Section 12.3 Ionic Solids Bill Vining SUNY Oneonta.

Slides:

Advertisements

Similar presentations

Objectives By the end of this section you should:

Advertisements

Lecture 4 (9/18/2006) Crystal Chemistry Part 3: Coordination of Ions Pauling’s Rules Crystal Structures.

Figure 16.9: Three cubic unit cells and the corresponding lattices.

Imperfection in Solids

Warm Up Give the formula that will result from reacting the following ions: 1.Na +, O 2- 2.Al 3+, Cl - 3.Mg 2+, N 3- 4.Al 3+, S 2- 5.Ca +, Br - 1.Na 2.

Unless otherwise stated, all images in this file have been reproduced from: Blackman, Bottle, Schmid, Mocerino and Wille, Chemistry, 2007 (John Wiley)

Unit Cell of Crystal Structure

Ionic Bond Chapter 5 Section 2.

1 Liquids Molecules at interfaces behave differently than those in the interior. Molecules at surface experience a net INWARD force of attraction. This.

2.2 Ionic Compounds Atomic Ions LO:I understand how ions are formed from neutral atoms.

Ionic Bonding. CA Standards  Students know atoms combine to form molecules by sharing electrons to form covalent or metallic bonds or by exchanging electrons.

Solids Ch.13. Solids Fixed, immobile (so to speak) Fixed, immobile (so to speak) Symmetry Symmetry Crystals Crystals So what’s the inner order? So what’s.

Previously in Chem 104: types of solids Unit Cell 3 types of cubic cells contents of unit cell Lecture 1 posted! TODAY Z quantify relationship between.

Sections 12.1 – 12.2 Types of Solids Metallic Solids Bill Vining SUNY Oneonta.

Metallic –Electropositive: give up electrons Ionic –Electronegative/Electropositive Colavent –Electronegative: want electrons –Shared electrons along bond.

Advanced Chemistry Notes. Solids Recall: according to the Kinetic Theory (KT), solids were a state of matter where the AF dominated the KE of particles.

L03C: Chapter 3 (Continued) Inorganic Compounds Reminder: Bonding ranges from ionic to covalent depending on relative electronegativity of constituents.

Metallic –Electropositive: give up electrons Ionic –Electronegative/Electropositive Colavent –Electronegative: want electrons –Shared electrons along bond.

Crystal Structure Solids are divided into 2 categories:

Ceramics Term ceramics comes from the greek word keramikos – “burnt stuff” Ceramics are typically formed during high temperature heat treating – “Firing”

Packing of more than one type of sphere into unit cells: -Packing of ions in salts -Which is usually larger, negative (anions) or positive (cations) ions?

2D Packing Examples hole Answer the following questions for both packing diagrams. 1.Find the smallest unit that, if repeated, would give you the entire.

Chapter 12: Solids. Types of Solids: Ionic Molecular Network: crystalline amorphous Metallic.

Crystalline Structures Edward A. Mottel Department of Chemistry Rose-Hulman Institute of Technology.

Previously in Chem 104: types of solids Unit Cell TODAY 3 types of cubic cells contents of unit cell, Z quantify relationship between cell and density.

Chapter 12: Solids. Types of Solids: Ionic Molecular Network: crystalline amorphous Metallic.

Crystalline Structures Edward A. Mottel Department of Chemistry Rose-Hulman Institute of Technology.

Crystalline Structures Edward A. Mottel Department of Chemistry Rose-Hulman Institute of Technology.

Structure of Solids Objectives

Chapter 3: Structures of Metals & Ceramics

Objectives Know atoms combine to form molecules by sharing electrons to form covalent or metallic bonds or by exchanging electrons to form ionic bonds.

Ionic Bonds and Ionic Compounds

Ionic – Bonding and Crystal Structure. Valence and Lewis Bond Theory metals and non-metals exchange electrons eg. Na 2 O O [He]    2s 2 2p 4 Na [Ne]

Instructor: Dr. Upali Siriwardane

Chapter Chapter 12: Structures & Properties of Ceramics ISSUES TO ADDRESS... How do the crystal structures of ceramic materials differ from those.

1) Bell Ringer: What are valence electrons? What is the difference between an ionic and molecular compound? 2) Worksheet #13 3) QUIZ #6.

Positively charged ions and negatively charged ions are attracted to each other and this attraction is the basis of ionic bonding.

Structure of Solids Objectives By the end of this section you should be able to: Understand typical ionic crystal structure Be able to define the primitive.

Chapter 7: Ionic and Metallic Bonding Section 2: Ionic Bonds and Ionic Compounds.

Topic #2: The Chemical Alphabet Fall 2008 Dr. Susan Lait

5. Formation of Ionic Compound s Compounds composed of cations and anions are called ionic compounds. Although they are composed of ions, ionic compounds.

Ionic Bonding & Ionic Compounds. Objectives Explain how ionic compounds are formed Explain the electrical charge of an ionic compound Describe three properties.

Metallic and Ionic Solids Sections

Sections 12.1 – 12.2 Types of Solids Metallic Solids.

Prentice Hall © 2003Chapter 11 Types of Solids Molecular Solidsex. CO 2, H 2 O, Ar Covalent-Network Solidsex. Diamond, quartz, SiO 2 Metallic Solidsex.

UNIT CELL – The smallest repeating unit of a crystalline solid EXP11-1 (of 11) UNIT CELLS.

Bonding, GPS 8 Additional Notes. Types of Solids Ionic solids – Ions arranged in a lattice Metallic solids – Cations of metals share a “sea” of valence.

Ionic Compounds CHEMISTRY 11 MS. MCGRATH. Ionic Compounds Ionic compounds do not form molecules. Why not? Think about NaCl…there is are the exact number.

Radius Ratio Rule.

Ionic Bonds and Ionic Compounds

Next time: Diffraction

Chemistry 481(01) Spring 2017 Instructor: Dr. Upali Siriwardane

Chapter 3: Solid State Chemistry Week 7

Chapter 3: Solid State Chemistry

CRYSTAL LATTICE & UNIT CELL

Solid State Lattices.

Chapter 12 – Solids and Modern Materials

Ionic Bond Chapter 5 Section 2.

Ionic Bond Chapter 5 Section 2.

IONIC SOLIDS IONIC SOLIDS T.Y. B.Sc. Dr. R. K. Jadhav

Solid Crystal Structures. (based on Chap

Solid Crystal Structures. (based on Chap

Ionic Compounds.

Solid Crystal Structures. (based on Chap

The Solid-State Structure of Metals and Ionic Compounds

Presentation transcript:

Section 12.3 Ionic Solids Bill Vining SUNY Oneonta

Types of Solids and Metallic Solids In these sections… a.Ionic solid unit cells and formulas b.Holes in unit cells of anions c.Cesium chloride, sodium chloride and zinc blend d.What controls which shape a solid takes? e.Calculations related to unit cell dimensions

Ionic Solids and Formulas cesium oxide (Cs on cornder, O on edges)

Ionic Compound Anion Unit Cells with Cations Occupying Holes

Cubic Holes in Simple Cubic Unit Cells

Octahedral and Tetrahedral Holes in FCC Unit Cells

Octahedral and Tetrahedral Holes in FCC Unit Cells

Three Important Ionic Unit Cells: cesium chloride

Three Important Ionic Unit Cells: sodium chloride

Three Important Ionic Unit Cells: zinc blend

Review of Anion Lattices and Holes in NaCl and zinc blend Unit Cells

Comparison of ZnS and SrCl 2 Unit Cells

Why do different solids of the same formula type adopt different unit cell structures? Stable arrangement has the greatest coordination number without leaving gaps between the cation and the surrounding ions As r - /r + increases, coordination # decreases

Determine an ionic radius from unit cell dimensions Magnesium oxide crystallizes with the sodium chloride structure. If the edge length of the unit cell is determined to be 420 pm and the O 2- ion is assigned a radius of 126 pm, what is the radius of the Mg 2+ ion?

CdF 2 crystallizes with the CaF 2 structure which is represented in the following model, with the anions in green. If the edge length of the unit cell is 540 pm, what is the density of crystalline CdF 2 in g/cm 3 ?