Atomic Forces Cont.. Energy Levels  From this, Bohr determined electrons were at certain energy levels from the nucleus.  Excited e - ’s jump to higher.

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Presentation transcript:

Atomic Forces Cont.

Energy Levels  From this, Bohr determined electrons were at certain energy levels from the nucleus.  Excited e - ’s jump to higher energy levels, then fall back to ground.  Since the distance it “falls” back is always the same, energy always comes out of an atom in discrete amounts.  The energy level are the numbers on the left column

Orbits  Bohr calculated the necessary distance for an electron to fall to release the different amounts of energy, and drew perfect circles around the atom for the electrons to travel.  He was using classical physics, relativity, because he didn’t know of quantum mechanics yet.  Quantum mechanics was just being discovered

orbitals  As new information presented itself, Bohr quickly agreed that his orbit model was incorrect, however, the energy level portion of his theory was correct.  Bohr became one of the top researchers in quantum mechanics and the wave model of the atom.

What keeps electrons near?  electromagnetic force  like charges repel, opposite charges attract  The e - are attracted to the positive nucleus but repelled by every other e -.  This is why we have to fill all up arrows before pairing electrons up (they don’t want to be next to each other).  Pauli Exclusion Principle ~ You can not have more than two electrons in one orbital (on the same line) because of this repulsion.

Orbitals instead of orbits  With simple orbits electrons would be pulled into the nucleus.  An orbital is just the area with the highest probability of finding an electron.  The high energy of the electrons keeps them spinning around.  Heisenberg’s Uncertainty Principle ~ we can never know exactly where an electron is and where it is going.  Orbitals are represented by the lines you place the arrows on

Orbitals take on different shapes  The easiest (lowest energy level) shape an orbital can take is called s (sphere).  The first energy level can hold 1 s orbital only.  The second energy level can hold 1 s orbital and 3 p orbitals (p orbital is a higher energy shape than s)  The third can hold 1 s orbital 3 p orbitals and 5 d orbitals. 

More protons  The more positive the nucleus the closer the electrons can be pulled in.  This is why we have to skip d and f (only a larger nucleus can squeeze all those orbitals into one energy level).  Aufbau principle- electrons will occupy the lowest energy orbital available.  If electrons were forced to be in the same orbital, it is assumed they would spin in opposite directions (to avoid contact). This is represented by either an up or a down arrow.

What holds a nucleus together?  Strong Nuclear Force- holds the nucleus together  EM forces want to blow the nucleus apart  Neutrons lessen this effect  Without enough neutrons the atom will break apart.  This process is called radioactive decay  For some isotopes this happens very quickly (radioactive stuff) but for most it doesn’t.

Going from atoms (microscopic) to useable amounts (macroscopic) of substances  chemists do not talk about the number of atoms in a reaction because atoms are so small.  Instead they refer to moles of atoms.  1 mole = x10 23 particles  This is Avogadro’s number

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