 In general, as we go across a period from left to right, the first ionization energy increases.  Why?  Electrons added in the same principal quantum.

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Presentation transcript:

 In general, as we go across a period from left to right, the first ionization energy increases.  Why?  Electrons added in the same principal quantum level do not completely shield the increasing nuclear charge caused by the added protons.  Electrons in the same principal quantum level are generally more strongly bound from left to right on the periodic table. Copyright © Cengage Learning. All rights reserved 1

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 In general, as we go down a group from top to bottom, the first ionization energy decreases.  Why?  The electrons being removed are, on average, farther from the nucleus. Copyright © Cengage Learning. All rights reserved 3

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Which atom would require more energy to remove an electron? Why? Na Cl Copyright © Cengage Learning. All rights reserved 5

Which atom would require more energy to remove an electron? Why? Li Cs Copyright © Cengage Learning. All rights reserved 6

 In general as we go across a period from left to right, the atomic radius decreases.  Effective nuclear charge increases, therefore the valence electrons are drawn closer to the nucleus, decreasing the size of the atom.  In general atomic radius increases in going down a group.  Orbital sizes increase in successive principal quantum levels. Copyright © Cengage Learning. All rights reserved 7

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Which should be the larger atom? Why? Na Cl Copyright © Cengage Learning. All rights reserved 9

Which should be the larger atom? Why? Li Cs Copyright © Cengage Learning. All rights reserved 10

Which is larger?  The hydrogen 1s orbital  The lithium 1s orbital Which is lower in energy?  The hydrogen 1s orbital  The lithium 1s orbital Copyright © Cengage Learning. All rights reserved 11

Arrange the elements oxygen, fluorine, and sulfur according to increasing:  Ionization energy  Atomic size Copyright © Cengage Learning. All rights reserved 12

Handout booklet #1-7, 10, 15, 16 Copyright © Cengage Learning. All rights reserved 13