Bomb Calorimeter Used to measure enthalpy changes of combustion reactions at a constant volume Occurs inside a tiny inner metal chamber called a bomb The.

Slides:



Advertisements
Similar presentations
Chapter 6 Thermochemistry -study of heat changes that occur during chemical reactions, study of relationships between chemistry and energy energy- ability.
Advertisements

Chapter 5 Thermochemistry
Calorimetry: :Measuring Heat
Enthalpy Changes Measuring and Expressing ∆H Calorimetry.
Chemistry/Biology 12 (Nova Scotia Curriculum)
Calorimetry Definition: Calorimetry is the accurate and precise measurement of heat flow for chemical and physical processes. It operates under the law.
Laboratory 12 CALORIMETRY. Objectives 1.Construct and utilize a coffee cup calorimeter to measure heat changes 2.Determine the heat capacity of a calorimeter.
Thermodynamics Thermodynamics is the study of systems involving energy in the form of heat and work.
Calorimetry Heat of combustion Heat capacity Solution calorimetry Calibration factor Bomb calorimetry.
Enthalpy and Calorimetry Chapter 5 part 2 Enthalpy H is heat under constant pressure or H=q P H=E+PV And therefore ΔH= ΔE+P ΔV ΔH=H final -H initial.
Calorimetry Mr. Dvorsky SCH 4U1. A calorimeter is an object used for measuring the heat of a chemical reaction or physical change. Can be as simple as.
17.1 Calorimetry Calorimetry is the experimental science of measuring (metry) heat (calor) transfer under controlled conditions. Almost all thermodynamic.
Causes of Change Changes in Enthalpy During Chemical Reactions.
Calorimetry Chapter 5. Calorimetry Since we cannot know the exact enthalpy of the reactants and products, we measure  H through calorimetry, the measurement.
Energy Transformations Thermochemistry is the study of energy changes that occur during chemical reactions and changes in state. The energy stored in the.
CALCULATION OF ENTHALPY CHANGES. Molar Enthalpy  the enthalpy change for 1 mole of a substance associated with a chemical, physical or nuclear change.
Chapter 17 Thermochemistry
1 Chapter 6 EnergyThermodynamics. 2 Energy is... n The ability to do work. n Conserved. n made of heat and work. n a state function. n independent of.
Thermochemistry Powerpoint #2.
Chapter 11 Thermochemistry Principles of Reactivity: Energy and Chemical Reactions.
1 Chapter 8 Thermochemistry. 2 Energy is... n The ability to do work. n Conserved. n made of heat and work. n a state function. n independent of the path,
Calorimetry “heat measuring” Energy changes can be calculated by measuring temperature changes in a calorimetre.
Heat & Enthalpy Changes
T HE U NIVERSITY O F Q UEENSLAND Foundation Year THERMOCHEMISTRY I.
Enthalpy Changes Measuring and Expressing ∆H ☾ Calorimetry ☽
General reaction: Enthalpy change Consider the reaction a A + b B c C + d D = c (C) + d (D) - a (A) - b (B) 61.
Energy as Heat A sample can transfer energy to another sample. One of the simplest ways energy is transferred is as heat. Heat is the energy transferred.
Measuring Heat reaction
Thermochemistry Chapter 17.
Thermal Energy from Chemical Reactions. Thermochemical Equations An equation with the amount of energy produced or absorbed –C 8 H 18(l) + 12½O 2(g) 
Calorimetry. Since we cannot know the exact enthalpy of the reactants and products, we measure  H through calorimetry, the measurement of heat flow.
Measuring heat changes
Calorimetry Thermochemistry. Calorimeter  Instrument used to measure amount of energy involved in a chemical reaction.  It is equivalent to an isolated.
Thermochemistry © 2009, Prentice-Hall, Inc. Chapter 11 Thermochemistry.
Ch. 15: Energy and Chemical Change
Ch. 11 Thermochemistry: Heat and Chemical Change
Chapter 17: Measuring and Expressing Enthalpy Changes
Calorimetry is the technological process of measuring energy changes of an isolated system called a calorimeter Calorimetry is the technological process.
Chapter 15.4 & 15.5 ENTHALPY AND CALORIMETRY.  Thermochemistry = heat changes that accompany chemical reactions and phase changes  Energy released 
Measuring and Using Energy Changes Calorimetry. To measure the heat flow in a process, you need an isolated system You also need a known amount of a substance,
Calor-imetry (heat/energy) – (measuring) This is all about keeping track of where the energy goes! Physical changes are often accompanied by a transfer.
Chapter 5 Thermochemistry. Energy of objects Objects can possess 2 kinds of energy. KE= energy of motion E k = ½ mv 2 PE= stored energy (energy of position)
Thermochemistry Section 2: Enthalpy and Calorimetry.
Enthalpy (H) is used to quantify the heat flow into or out of a system in a process that occurs at constant pressure. Enthalpy is defined as H = E + PV.
1. Definition Heat flow in a system SymbolH Like internal energy, the change in enthalpy is important State function – measure of its current conditions.
Section 5.5 Calorimetry. Objectives  Examine calorimetry in order to quantify heat changes in chemical processes.
U3 S3 L1 Calorimetry Textbook Readings MHR pages : The Technology of Heat Measurement pages : Using a Calorimeter to Determine the Enthalpy.
Energy change that occurs during a chemical reaction and/or changes in state.
HW 5.4 a. 200 KJ b. by 4 c. Heat up brakes and road a.  E = q + w b. No energy is not gained or lost. c. System loses heat or does work on the surroundings.
Energy change that occurs during a chemical reaction and/or changes in state.
Back Chapter 16 Reaction Energy West Valley High School General Chemistry Mr. Mata.
Measuring Heat. Calorimeter Measuring Heat A device for measuring amount of heat absorbed or released. Calorimeter.
Do Now: Check Homework #1-8 (omit 2 & 6), 11a, 12 (p. 483) 1a) coal 8.2% crude oil 35.2% natural gas 43.5% natural gas liquids 4.0% primary electricity,
17.2 Measuring and Expressing Enthalpy Changes 1 > Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Chapter 17 Thermochemistry.
ENERGY n The ability to do work n remains constant in amount during a chemical or physical change n energy changes occur between the system and the surrounding.
Combustion reactions are exothermic. They release energy, and heat up the surroundings.
Thermochemistry 3 Calorimetry & Heat of Formation.
Heat capacity and Calorimetry
© 2012 Pearson Education, Inc.
Energy Thermodynamics
5/2 Opener What is the difference between a dissolution and a chemical reaction?
Chapter 17 Thermochemistry 17.2 Measuring and Expressing
Enthalpy and Calorimetry
Energy Thermodynamics
Calorimetry Calorimetry is the measurement of the heat flow into or out of a system for chemical and physical processes. Copyright © Pearson Education,
Energy Thermodynamics
Thermochemistry Thermochemistry the study of the energy changes that accompany physical or chemical changes in matter. Changes may be classified.
ENTHALPY OF COMBUSTION ΔHc
Presentation transcript:

Bomb Calorimeter Used to measure enthalpy changes of combustion reactions at a constant volume Occurs inside a tiny inner metal chamber called a bomb The bomb contains pure oxygen, the reactants are ignited using an electric coil A known quantity of water surrounds the bomb and absorbs energy that is released by the reaction

Bomb Calorimetry To obtain precise heat measurements, you must know or find out the heat capacity of the bomb calorimeter Heat capacity takes into account all the parts of the calorimeter that can lose or gain. c total = c water + c thermometer + c stirrer + c container

Bomb Calorimetry Since mass of the other parts are constant, there is no need for the mass units in the heat capacity value. Manufacturers include the heat capacity (C) of a calorimeter when it is purchased. Therefore, q cal = CΔT C= heat capacity of the calorimeter