Lecture 21 Tuesday 3/25/08 CSTR With Heat Effects Multiple Steady States. Ignition and Extiction Temperatures
CSTR with Heat Effects Energy Balance for CSTRs Equation (8-9) (page 476)
Energy Balance for CSTRs Equation (8-9) (page 476) Using We obtain after some manipulation (page 593)
At Steady State Solving for X Solving for T
In general
Mole Balance Rate Law Stoichiometry Combine
Generating G(T) and R(T) Need to solve for X after combining mole balance rate law and stoichiometry. For a first order irreversible reaction Parameters Then plot G and R as a function of T
CSTR Heat Effects F io T a2 T a1 FiFi mcmc V Neglect stirring
TCTC T R(T) T0T0 T C =T a T R(T) k k=0 (adiabatic) k=∞
G T T R,G Steady state, G(T)=R(T) T 0 T C T S T 01 T C1 T S1 T 02 T C2 T S2,T S3 T TSTS T0T0 Ignition temp Extinction temp stable unstable T T S3 T S1 T S2