Chapter 13 Unsaturated Hydrocarbons CHEM 2124 – General Chemistry II Alfred State College Professor Bensley
Chapter 13 Objectives Identify the three major types of unsaturated hydrocarbons – alkenes, alkynes, and aromatic compounds. Name alkanes, alkynes, and substituted benzenes. Recognize the difference between constitutional isomers and stereoisomers, as well as identify cis and trans isomers. Draw the products of addition reactions of alkenes.
Chapter 13 Objectives Draw the products of reactions that follow Markovnikov’s Rule. Draw the structure of polymers that are formed from alkene monomers. Draw the products of substitution reactions of benzene.
Chapter 13 – Unsaturated Hydrocarbons I. Alkenes and Alkynes A.Alkenes B.Alkynes
Chapter 13 – Unsaturated Hydrocarbons What are unsaturated hydrocarbons? Drawing Condensed Structures C.Alkene and Alkyne Properties
Nomenclature of Alkenes and Alkynes HOW TO Name an Alkene or Alkyne Step [1] Find the longest chain that contains both C atoms of the double or triple bond. 4 C’s in longest chain butane ----> butene 6 C’s in longest chain hexane ----> hexyne
Nomenclature of Alkenes and Alkynes HOW TO Name an Alkene or Alkyne Step [2] Number the carbon chain from the end that gives the multiple bond the lower number. 1-butene 2-hexyne
Nomenclature of Alkenes and Alkynes HOW TO Name an Alkene or Alkyne Step [3] Number and name the substituents, and write the name. What is a diene?
Chapter 13 – Unsaturated Hydrocarbons CH methylcyclopentene CH ,6-dimethylcyclohexene D. Cycloalkenes
Chapter 13 – Unsaturated Hydrocarbons 2-butene II. Stereoisomers A. Cis/trans isomers
Chapter 13 – Unsaturated Hydrocarbons B. Stereoisomers vs. Constitutional Isomers
Interesting Alkenes in Food and Medicine
Chapter 13 – Unsaturated Hydrocarbons A.Addition Reactions III. Reactions of Alkenes 1. Hydrogenation
Chapter 13 – Unsaturated Hydrocarbons 2. Halogenation 3. Hydrohalogenation
Chapter 13 – Unsaturated Hydrocarbons 4. Markovnikov’s Rule C1 has more H’s, so it will bond to the H from HCl. 2-Chloropropane is the only product formed. C2 is bonded to 1 H C1 is bonded to 2 H’s
Chapter 13 – Unsaturated Hydrocarbons 5. Hydration CH 3 H +HOH this C has no H’s this C has 1 H OH H CH 3 H H 2 SO 4 only product
Figure 13.4
Chapter 13 – Unsaturated Hydrocarbons IV. Aromatic Compounds What is a resonance hybrid?
1. One substituent Chapter 13 – Unsaturated Hydrocarbons A. Nomenclature of Aromatic Compounds
Chapter 13 – Unsaturated Hydrocarbons 2. Disubstituted Benzenes
ortho-xylene o-xylene 1,2-dimethylbenzene meta-xylene m-xylene 1,3-dimethylbenzene para-xylene p-xylene 1,4-dimethylbenzene 3. Polysubstituted Benzenes 4-chloro-1-ethyl-2-propylbenzene
2,5-dichloroaniline Some common drugs that contain benzene rings are:
B. Reactions of Aromatic Hydrocarbons Chapter 13 – Unsaturated Hydrocarbons Addition NO Substitution YES
Chapter 13 – Unsaturated Hydrocarbons