Models of the Atom - Dalton’s model (1803) Greek model (400 B.C.)

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Presentation transcript:

Models of the Atom - Dalton’s model (1803) Greek model (400 B.C.)
+ + - Dalton’s model (1803) Greek model (400 B.C.) Thomson’s plum-pudding model (1897) Rutherford’s model (1909) Bohr’s model (1913) Charge-cloud model (present) 1803 John Dalton pictures atoms as tiny, indestructible particles, with no internal structure. 1897 J.J. Thomson, a British scientist, discovers the electron, leading to his "plum-pudding" model. He pictures electrons embedded in a sphere of positive electric charge. 1911 New Zealander Ernest Rutherford states that an atom has a dense, positively charged nucleus. Electrons move randomly in the space around the nucleus. 1926 Erwin Schrödinger develops mathematical equations to describe the motion of electrons in atoms. His work leads to the electron cloud model. 1913 In Niels Bohr's model, the electrons move in spherical orbits at fixed distances from the nucleus. “Models of the Atom” Description: This slide shows he evolution of the concept of the atom from John Dalton to the present. Basic Concepts ·         The model of the atom changed over time as more and more evidence about its structure became available. ·         A scientific model differs from a replica (physical model) because it represents a phenomenon that cannot be observed directly. Teaching Suggestions Use this slide as a review of the experiments that led up to the present-day view of the atom. Ask students to describe the characteristics of each atomic model and the discoveries that led to its modification. Make sure that students understand that the present-day model shows the most probable location of an electron at a single instant. Point out that most scientific models and theories go through an evolution similar to that of the atomic model. Modifications often must be made to account for new observations. Discuss why scientific models, such as the atomic models shown here, are useful in helping scientists interpret heir observations. Questions Describe the discovery that led scientists to question John Dalton’s model of the atom ad to favor J.J. Thomson’s model. What experimental findings are the basis for the 1909 model of the atom? What shortcomings in the atomic model of Ernest Rutherford led to the development of Niels Bohr’s model? A friend tells you that an electron travels around an atom’s nucleus in much the same way that a planet revolves around the sun. Is this a good model for the present-day view of the atom? Why or why not? Another friend tells you that the present-day view of an electron’s location in the atom can be likened to a well-used archery target. The target has many holes close to the bull’s-eye and fewer holes farther from the center. The probability that the next arrow will land at a certain distance from the center corresponds to the number of holes at that distance. Is this a good model for the present-day view of the atom? Why or why not? Suppose that, it the future, an apparatus were developed that could track and record the path of an electron in an atom without disturbing its movement. How might this affect the present-day model of the atom? Explain your answer. How does developing a model of an atom differ from making a model of an airplane? How are these two kinds of models the same? Drawing on what you know in various fields of science, write a general statement about the usefulness of scientific models. Timeline: Wysession, Frank, Yancopoulos Physical Science Concepts in Action, Prentice Hall/Pearson, 2004 pg 114 1924 Frenchman Louis de Broglie proposes that moving particles like electrons have some properties of waves. Within a few years evidence is collected to support his idea. 1932 James Chadwick, a British physicist, confirms the existence of neutrons, which have no charge. Atomic nuclei contain neutrons and positively charged protons. 1904 Hantaro Nagaoka, a Japanese physicist, suggests that an atom has a central nucleus. Electrons move in orbits like the rings around Saturn. 1

Dalton Model of the Atom
Late 1700’s - John Dalton- England Teacher- summarized results of his experiments and those of others Combined ideas of elements with that of atoms in Dalton’s Atomic Theory Objective: To describe the Dalton model of the atom. John Dalton ( ) established a continuing tradition of chemical atomism. 2

Foundations of Atomic Theory
Law of Conservation of Mass Mass is neither destroyed nor created during ordinary chemical reactions. Law of Definite Proportions The fact that a chemical compound contains the same elements in exactly the same proportions by mass regardless of the size of the sample or source of the compound. Lavoisier (credited with Law of Conservation of Mass). Proust (credited with Law of Definite Proportions). Dalton (credited with Law of Multiple Proportions). Law of Multiple Proportions If two or more different compounds are composed of the same two elements, then the ratio of the masses of the second element combined with a certain mass of the first elements is always a ratio of small whole numbers. 3

Conservation of Atoms 2 H2 + O2 2 H2O O H2 H2O O2 + 4 atoms hydrogen
John Dalton 2 H2O H O H2 O2 H2O + “Conservation of Atoms” Description: This slide illustrates conservation of atoms in a chemical reaction. Basic Concepts Atoms are conserved in chemical reactions, but molecules are not. Atoms are neither created nor destroyed in chemical reactions. They are only rearranged. Equation coefficients can be interpreted as the relative numbers of molecules, formula units, or moles of reactants and products. Teaching Suggestions This slide shows that atoms are neither created nor destroyed in a chemical reaction but are merely rearranged. Use this slide and worksheet to help students understand formula equations. You may need to review how gram formula mass is determined. Questions State the law that explains why the number of oxygen and hydrogen atoms is the same on both sides of the equation shown in the diagram. In what ways are the atoms rearranged by the reaction? Write a word equation for the reaction taking place in the diagram. In the balanced equation shown in the diagram, what is the coefficient of H2? Of O2? Give two ways in which the coefficients in the balanced equation can be interpreted. Use the balanced equation to determine how many moles of H2O would be produced by the reaction of 4 moles of H2 with 2 moles of O2. The gram formula mass of a substance is the number of grams of the substance containing a mole of formula units. Write the equation for the reaction in question 5 showing the number of moles of the reactants and the product. Calculate the gram formula mass of H2, O2, and H2O. How many grams of H2 and O2 react in the reaction in part a? How many grams of H2O are produced? Rewrite the equation, giving the masses of reactants and products. How do you know that mass is conserved in this reaction? Do the masses of the reactants in the equation in part d have the same ratio as the coefficients of the equation in part a? Why or why not? Which do you think is most useful to a chemist: the balanced formula equation (at the top of the diagram), the molecular sketch, the word equation, or an equation that gives the masses of reactants and products? Which would be the least useful? Explain your reasoning. 4 atoms hydrogen 2 atoms oxygen 4 atoms hydrogen 2 atoms oxygen Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 204 4

Legos are Similar to Atoms
H O H2 O2 H2O + Lego's can be taken apart and built into many different things. Atoms can be rearranged into different substances. 5

Conservation of Mass + + High voltage electrodes Before reaction glass
chamber High voltage After reaction 0 g H2 40 g O2 300 g (mass of chamber) + 385 g total O2 H2O H2 5.0 g H2 “Conservation of Mass” (Lavoisier) Description: This slide illustrates a reaction between hydrogen and oxygen in a nonstoichiometric mixture of these gases. Basic Concepts ·         Mass and atoms are conserved in chemical reactions. ·         When non-stoichiometric quantities of substances are mixed, they react in stoichiometric proportions. Any reactants in excess remain unreacted. Teaching Suggestions Explain that the first diagram shows the amount of oxygen and hydrogen in a closed chamber. A spark passes between the electrodes, causing the O2 and H2 to react rapidly. The second diagram shows what is in the chamber after the reaction. Use this slide to illustrate that reactants combine in the stoichiometric proportions. Stress that is is not sufficient to know the amounts of starting materials present. One must also know the amounts of reactants that will take part in the reaction. Questions What is the ratio of the mass of O2 to H2 before the reaction? What is the ratio of the number of moles of O2 to H2 before the reaction? How do you account for the fact that the mass of the chamber and its contents is the same before and after the reaction. Why is some oxygen left in the chamber after the reaction? What are the masses of H2 and O2 that take part in the reaction? What is the ratio of the mass of O2 to H2 taking part in this reaction? What is the ratio of the number of moles of O2 to H2 taking part in the reaction? Why is this mole ratio different from the mass ratio? If there were twice as much H2 in the chamber (10 g) but the same amount of O2 (80g), what would you expect to find in the chamber after the reaction? Explain your answer. O2 80 g O2 45 g H2O ? g H2O 300 g (mass of chamber) + 385 g total Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 204 6

Law of Definite Proportions
11.56 g of lead sulfide 1.56 g of sulfur + 10.00 g of lead 3.00 g of sulfur 11.56 g of lead sulfide + 10.00 g of lead + 1.44 g of sulfur (leftovers) An early illustration of the law of definite proportions is found in the work of a Swedish chemist, J.J. Berzelius ( ). In a typical experiment he heated g of lead with varying amounts of sulfur to form lead sulfide. Because lead is a soft, grayish metal, sulfur is a pale yellow solid, and lead sulfide is a shiny black solid, it was easy to tell when all the lead had reacted. Excess sulfur could be washed away by carbon disulfide, a liquid that dissolves sulfur but not lead sulfide. As long as he used at least 1.56 g of sulfur, he got exactly g of lead sulfide. Any sulfur in excess of 1.56 g was left over, unreacted. If he used more than g of lead with 1.56 g of sulfur, he got g of lead sulfide with lead left over. These findings are consistent with Dalton’s atomic theory. 18 g of lead 11.56 g of lead sulfide 1.56 g of sulfur + + 8.00 g of lead (leftovers) Ralph A. Burns, Fundamentals of Chemistry 1999, page 91 7

Daltons’ Models of Atoms
Carbon dioxide, CO2 Water, H2O Dalton would have shown water with a single hydrogen and a single oxygen. Dalton did not know that hydrogen was diatomic and had a mass of 1 amu. Methane, CH4 8

Dalton’s Atomic Theory
1. All matter is made of tiny indivisible particles called atoms. 2. Atoms of the same element are identical, those of different atoms are different. 3. Atoms of different elements combine in whole number ratios to form compounds 4. Chemical reactions involve the rearrangement of atoms. No new atoms are created or destroyed. Dalton's theory had four main concepts: All matter is composed of indivisible particles called atoms. Bernoulli, Dalton, and others pictured atoms as tiny billiard-ball-like particles in various states of motion. While this concept is useful to help us understand atoms, it is not correct as we will see in later modules on atomic theory linked to at the bottom of this module. All atoms of a given element are identical; atoms of different elements have different properties. Dalton’s theory suggested that every single atom of an element such as oxygen is identical to every other oxygen atom; furthermore, atoms of different elements, such as oxygen and mercury, are different from each other. Dalton characterized elements according to their atomic weight; however, when isotopes of elements were discovered in the late 1800s this concept changed. Chemical reactions involve the combination of atoms, not the destruction of atoms. Atoms are indestructible and unchangeable, so compounds, such as water and mercury calx, are formed when one atom chemically combines with other atoms. This was an extremely advanced concept for its time; while Dalton’s theory implied that atoms bonded together, it would be more than 100 years before scientists began to explain the concept of chemical bonding. When elements react to form compounds, they react in defined, whole-number ratios. The experiments that Dalton and others performed showed that reactions are not random events; they proceed according to precise and well-defined formulas. This important concept in chemistry is discussed in more detail below. California WEB 9

Structure of Atoms Scientist began to wonder what an atom was like.
Was it solid throughout with no internal structure or was it made up of smaller, subatomic particles? It was not until the late 1800’s that evidence became available that atoms were composed of smaller parts. Some of the details of Dalton’s atomic theory require more explanation. Elements: As early as 1660, Robert Boyle recognized that the Greek definition of element (earth, fire, air, and water) was not correct. Boyle proposed a new definition of an element as a fundamental substance, and we now define elements as fundamental substances that cannot be broken down further by chemical means. Elements are the building blocks of the universe. They are pure substances that form the basis of all of the materials around us. Some elements can be seen in pure form, such as mercury in a thermometer; some we see mainly in chemical combination with others, such as oxygen and hydrogen in water. We now know of approximately 116 different elements. Each of the elements is given a name and a one- or two-letter abbreviation. Often this abbreviation is simply the first letter of the element; for example, hydrogen is abbreviated as H, and oxygen as O. Sometimes an element is given a two-letter abbreviation; for example, helium is He. When writing the abbreviation for an element, the first letter is always capitalized and the second letter (if there is one) is always lowercase. Atoms: A single unit of an element is called an atom. The atom is the most basic unit of the matter that makes up everything in the world around us. Each atom retains all of the chemical and physical properties of its parent element. At the end of the nineteenth century, scientists would show that atoms were actually made up of smaller, "subatomic" pieces, which smashed the billiard-ball concept of the atom. Compounds: Most of the materials we come into contact with are compounds, substances formed by the chemical combination of two or more atoms of the elements. A single “particle” of a compound is called a molecule. Dalton incorrectly imagined that atoms “hooked” together to form molecules. However, Dalton correctly realized that compounds have precise formulas. Water, for example, is always made up of two parts hydrogen and one part oxygen. The chemical formula of a compound is written by listing the symbols of the elements together, without any spaces between them. If a molecule contains more than one atom of an element, a number is subscripted after the symbol to show the number of atoms of that element in the molecule. Thus the formula for water is H2O, never HO or H2O2. The idea that compounds have defined chemical formulas was first proposed in the late 1700s by the French chemist Joseph Proust. Proust performed a number of experiments and observed that no matter how he caused different elements to react with oxygen, they always reacted in defined proportions. For example, two parts of hydrogen always reacts with one part oxygen when forming water; one part mercury always reacts with one part oxygen when forming mercury calx. Dalton used Proust’s Law of Definite Proportions in developing his atomic theory. The law also applies to multiples of the fundamental proportion, for example: In both of these examples, the ratio of hydrogen to oxygen to water is 2 to 1 to 1. When reactants are present in excess of the fundamental proportions, some reactants will remain unchanged after the chemical reaction has occurred. The story of the development of modern atomic theory is one in which scientists built upon the work of others to produce a more accurate explanation of the world around them. This process is common in science, and even incorrect theories can contribute to important scientific discoveries. Dalton, Priestley, and others laid the foundation of atomic theory, and many of their hypotheses are still useful. However, in the decades after their work, other scientists would show that atoms are not solid billiard balls, but complex systems of particles. Thus they would smash apart a bit of Dalton’s atomic theory in an effort to build a more complete view of the world around us. Source: 10

Antoine-Henri Becquerel
Radioactivity (1896) 1. rays or particles produced by unstable nuclei a. Alpha Rays – helium nucleus b. Beta Part. – high speed electron c. Gamma ray – high energy x-ray 2. Discovered by Becquerel – exposed photographic film 3. Further work by Curies Antoine-Henri Becquerel ( ) Their research led to the isolation of polonium, and radium. Together they were awarded half of the Nobel Prize for Physics in 1903, for their study into the spontaneous radiation discovered by Becquerel, who was awarded the other half of the Prize. In 1911 Marie Curie received a second Nobel Prize, this time in Chemistry, in recognition of her work in radioactivity. 11

Thomson Model of the Atom
J. J. Thomson - English physicist. 1897 Made a piece of equipment called a cathode ray tube. It is a vacuum tube - all the air has been pumped out. Objectives: To describe the Thomson plum-pudding model of the atom. To state the relative charge on an electron and a proton. The electron was discovered as a constituent of all mater by J. J. Thomson following his experiments with cathode ray tubes. By passing an electric discharge through a gas at low pressure, a beam of rays is generated at the cathode. These rays consist of high energy electrons. The negative charge of the electron is demonstrated by the fact that they are deflected away from a negative plate. Thomson was able to determine the charge/mass ratio for the electron (e/m = x 1011 C/kg). R A Millikan was later to determine the mass of the electron as 1/1836 amu. You can find descriptions of Thomson's and Millikan's work in most standard texts. Mass of the electron = x kg Charge of the electron = x C 12

Background Information
Cathode Rays Form when high voltage is applied across electrodes in a partially evacuated tube. Originate at the cathode (negative electrode) and move to the anode (positive electrode) Carry energy and can do work Travel in straight lines in the absence of an external field 13

Cathode Ray Experiment
1897 Experimentation Using a cathode ray tube, Thomson was able to deflect cathode rays with an electrical field. The rays bent towards the positive pole, indicating that they are negatively charged. 14

A Cathode Ray Tube Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 58 15

- Thomson’s Experiment + voltage source + -
OFF + + - By adding an electric field… he found that the moving pieces were negative. 16

J.J. Thomson He proved that atoms of any element can be made to emit tiny negative particles. From this he concluded that ALL atoms must contain these negative particles. He knew that atoms did not have a net negative charge and so there must be balancing the negative charge. J.J. Thomson ( ) proposed a model of the atom with subatomic particles (1903). This model was called the plum-pudding or raisin pudding model of the atom. (Sir Joseph John) J. J. Thompson was born in Manchester in His father was a bookseller and publisher. Thompson was Cavendish Professor of experimental physics, Cambridge University from He was described as humble, devout, generous, a good conversationalist and had an uncanny memory. He valued and inspired enthusiasm in his students. Thompson was awarded the Nobel Prize for physics for his investigations of the passage of electricity through gases. In 1897, he discovered the electron through his work on cathode rays. Thomson´s son, Sir George Paget, shared the Nobel Prize for physics with C.J. Davisson in Seven of Thomson´s trainees were also awarded Nobel Prizes. J.J. Thompson is buried in Westminster Abbey close to some of the World’s greatest  scientists, Newton, Kelvin, Darwin, Hershel and Rutherford. Thomson won the Nobel Prize in 1906 for characterizing the electron. J.J. Thomson 17

William Thomson (Lord Kelvin)
In 1910 proposed the Plum Pudding model Negative electrons were embedded into a positively charged spherical cloud. Spherical cloud of Positive charge Electrons Named after a dessert, the plum pudding model portrays the atom as a big ball of positive charge containing small particles with negative charge. Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 56 18

Thomson Model of the Atom
J.J. Thomson discovered the electron and knew that electrons could be emitted from matter (1897). William Thomson proposed that atoms consist of small, negative electrons embedded in a massive, positive sphere. The electrons were like currants in a plum pudding. This is called the ‘plum pudding’ model of the atom. Found the electron Couldn’t find (proton) positive (for a while) Said the atom was like plum pudding …. bunch of positive stuff, with the electrons able to be removed. - electrons - - - - - - - 19

Other pieces Proton - positively charged pieces
1840 times heavier than the electron Neutron - no charge but the same mass as a proton. How were these pieces discovered? Where are the pieces? 20

Ernest Rutherford (1871-1937) Learned physics in J.J. Thomson’ lab.
PAPER Learned physics in J.J. Thomson’ lab. Noticed that ‘alpha’ particles were sometime deflected by something in the air. Gold-foil experiment Ernest Rutherford received the Nobel Prize in chemistry (1908) for his work with radioactivity. Ernest Rutherford ( ) was born in Nelson, New Zealand in He began work in J.J. Thompson’s laboratory in He later moved to McGill University in Montreal where he became one of the leading figures in the field of radioactivity. From 1907 on he was professor at the University of Manchester where he worked with Geiger and Marsden. He was awarded the Nobel Prize for Chemistry in 1908 for his work on radioactivity. In 1910, with co-workers Geiger and Marsden he discovered that alpha-particles could be deflected by thin metal foil. This work enabled him to propose a structure for the atom. Later on he proposed the existence of the proton and predicted the existence of the neutron. He died in 1937 and like J.J. Thompson is buried in Westminster Abbey. He was one of the most distinguished scientists of his century. Is the Nucleus Fundamental? Because it appeared small, solid, and dense, scientists originally thought that the nucleus was fundamental. Later, they discovered that it was made of protons (p+), which are positively charged, and neutrons (n), which have no charge. Animation by Raymond Chang – All rights reserved. 21

Rutherford ‘Scattering’
In 1909 Rutherford undertook a series of experiments He fired a (alpha) particles at a very thin sample of gold foil According to the Thomson model the a particles would only be slightly deflected Rutherford discovered that they were deflected through large angles and could even be reflected straight back to the source particle source Lead collimator Gold foil a q Rutherford’s results strongly suggested that both the mass and positive charge are concentrated in a tiny fraction of the volume of the atom, called the nucleus. Rutherford established that the nucleus of the hydrogen atom was a positively charged particle, which he called a proton. Also suggested that the nuclei of elements other than hydrogen must contain electrically neutral particles with the same mass as the proton. The neutron was discovered in 1932 by Rutherford’s student Chadwick. Because of Rutherford’s work, it became clear that an α particle contains two protons and neutrons—the nucleus of a helium atom. 22

Rutherford’s Apparatus
Rutherford received the 1908 Nobel Prize in Chemistry for his pioneering work in nuclear chemistry. beam of alpha particles radioactive substance MODERN ALCHEMY “Ernest Rutherford ( ) was the first person to bombard atoms artificially to produce transmutated elements. The physicist from New Zealand described atoms as having a central nucleus with electrons revolving around it. He showed that radium atoms emitted “rays” and were transformed into radon atoms. Nuclear reactions like this can be regarded as transmutations – one element changing into another, the process alchemists sought in vain to achieve by chemical means.” Eyewitness Science “Chemistry” , Dr. Ann Newmark, DK Publishing, Inc., 1993, pg 35 When Rutherford shot alpha particles at a thin piece of gold foil, he found that while most of them traveled straight through, some of them were deflected by huge angles. circular ZnS - coated fluorescent screen gold foil Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120 23

Rutherford’s Apparatus
beam of alpha particles radioactive substance MODERN ALCHEMY Ernest Rutherford ( ) was the first person to bombard atoms artificially to produce transmutated elements. The physicist from New Zealand described atoms as having a central nucleus with electrons revolving around it. He showed that radium atoms emitted “rays” and were transformed into radon atoms. Nuclear reactions like this can be regarded as transmutations – one element changing into another, the process alchemists sought in vain to achieve by chemical means. Eyewitness Science “Chemistry” , Dr. Ann Newmark, DK Publishing, Inc., 1993, pg 35 Ernest Rutherford English physicist. (1910) Wanted to see how big atoms are. Used radioactivity, alpha particles - positively charged pieces given off by polonium atoms. Shot them at a thin gold foil (~0.5 um thick) which can be made a few atoms thick. When the alpha particles hit a florescent screen, it glows. Approximately 1/20,000 bounced back at the alpha emitter source. Rutherford said this was like shooting a 15" shell at tissue paper and the shell came back and hit you. It was clearly, NOT what he thought should happen if Thomson's model of the atom was correct. Ernest Rutherford received the 1908 Nobel prize in chemistry for his work at McGill University with radioactive substances. fluorescent screen circular - ZnS coated gold foil Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120 24

Florescent Screen Lead block Polonium Gold Foil
Ernest Rutherford English physicist. (1910) Wanted to see how big atoms are. Used radioactivity, alpha particles - positively charged pieces given off by polonium. Shot them at gold foil which can be made a few atoms thick. When the alpha particles hit a florescent screen, it glows. California WEB 25

What He Expected The alpha particles to pass through without changing direction (very much) Because The positive charges were spread out evenly. Alone they were not enough to stop the alpha particles California WEB 26

What he expected… 27

Because, he thought the mass was evenly distributed in the atom
- 28

What he got… richocheting alpha particles 29

The Predicted Result: expected path expected marks on screen
Observed Result: mark on screen likely alpha particle path 30

Interpreting the Observed Deflections
. gold foil . beam of alpha particles undeflected particles . . The observations: (1) Most of the alpha particles pass through the foil un-deflected. (2) Some alpha particles are deflected slightly as the penetrate the foil. (3) A few (about 1 in 20,000) are greatly deflected. (4) A similar small number do not penetrate the foil at all, but are reflected back toward the source. Rutherford believed that when positively charged alpha particles passed near the positively charged nucleus, the resulting strong repulsion caused them to be deflected at extreme angles. Rutherford's interpretation: If atoms of the foil have a massive, positively charged nucleus and light electrons outside the nucleus, one can explain how: (1) an alpha particle passes through the atom un-deflected (a fate share by most of the alpha particles); (2) an alpha particle is deflected slightly as it passes near an electron; (3) an alpha particle is strongly deflected by passing close to the atomic nucleus; and (4) an alpha particle bounces back as it approaches the nucleus head-on. deflected particle Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120 31

Density and the Atom Since most of the particles went through, the atom was mostly empty. Because the alpha rays were deflected so much, the positive pieces it was striking were heavy. Small volume and big mass = big density This small dense positive area is the nucleus California WEB 32

Rutherford Scattering (cont.)
Rutherford interpreted this result by suggesting that the a particles interacted with very small and heavy particles Particle bounces off of atom? Case A Case B Particle goes through atom? In the first case, one would assume the alpha particle (positively charged) struck another positively charged particle. Perhaps William Thomson (Lord Kelvin) was correct and the atom is like plum-pudding and is a positive ball with electrons embedded. In the middle example, where the alpha particles pass straight through and are not deflected, it implies the atom is mostly empty space or the alpha particle is too penetrating to give any useful information about the composition of an atom. The third example is NOT what is observed. For this to occur, the atom would have to be negatively charged and absorb all the positively charged alpha particles. At some point the atom would be “full” of alpha particles and then the atom would begin to bounce off of its surface alpha particles. The last example also occurs. In the gold foil experiment, Rutherford observed case A and D (rarely) and mostly case B. This was explained by saying the atom was mostly empty space where electrons spin rapidly around a positively charged, massive (most of the mass of the atom) but tiny nucleus. Particle attracts to atom? Case C . Particle path is altered as it passes through atom? Case D 33

Table: hypothetical description of alpha particles
(based on properties of alpha radiation) observation hypothesis alpha rays don’t diffract ... alpha radiation is a stream of particles alpha rays deflect towards a negatively charged plate and away from a positively charged plate ... alpha particles have a positive charge alpha rays are deflected only slightly by an electric field; a cathode ray passing through the same field is deflected strongly ... alpha particles either have much lower charge or much greater mass than electrons Copyright © by Fred Senese 34

Explanation of Alpha-Scattering Results
+ - Alpha particles Nuclear atom Nucleus Plum-pudding atom Thomson’s model Rutherford’s model 35

Interpreting the Observed Deflections
deflected particle . gold foil . beam of alpha particles undeflected particles . . Atom is mostly empty Small dense, positive piece at center (the nucleus). Alpha particles are deflected by it… if they get close enough to nucleus. Conclusion: From Rutherford’s results he proposed a nuclear atom model where there is a dense center of positive charge called the nucleus around which electrons move in space that is otherwise empty. Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120 36

Rutherford’s Gold-Leaf Experiment Conclusions: Atom is mostly empty space Nucleus has (+) charge Electrons float around nucleus “Rutherford’s Gold-Leaf Experiment” Description This slide illustrates Ernest Rutherford’s experiment with alpha particles and gold foil and his interpretation of the results. Basic Concepts When charged particles are directed at high speed toward a metal foil target, most pass through with little or no deflection, but some particles are deflected at large angles. Solids are composed of atoms that are closely packed. The atoms themselves are mostly empty space. All atoms contain a relatively small, massive, positively charged nucleus. The nucleus is surrounded by negatively charged electrons of low mass that occupy a relatively large volume. Teaching Suggestions Use this slide to describe and explain Rutherford’s experiment. Rutherford designed the apparatus shown in figure (A) to study the scattering of alpha particles by gold. Students may have difficult with the concepts in this experiment because they lack the necessary physics background. To help students understand how it was determined that the nucleus is relatively massive, use questions 3 and 4 to explain the concept of inertia. Explain that the electrostatic force is directly proportional to the quantity of electric charge involved. A greater charge exerts a greater force. (Try comparing the electrostatic force to the foce of gravity, which is greater near a massive object like the sun, but smaller near an object of lesser mass, such as the moon.) The force exerted on an alpha particle by a concentrated nucleus would be much greater that the force exerted on an alpha particle by a single proton. Hence, larger deflections will result from a dense nucleus than from an atom with diffuse positive charges. Point out that Rutherford used physics to calculate how small the nucleus would have to be produce the large-angle deflections observed. He calculated that the maximum possible size of the nucleus is about 1/10,000 the diameter of the atom. Rutherford concluded that the atom is mostly space. Questions If gold atoms were solid spheres stacked together with no space between them, what would you expect would happen to particles shot at them? Explain your reasoning. When Ernest Rutherford performed the experiment shown in diagram (A) he observed that most of the alpha particles passed straight through the gold foil. He also noted that the gold foil did not appear to be affected. How can these two observations be explained? Can you explain why Rutherford concluded that the mass of the f\gold nucleus must be much greater than the mass of an alpha particle? (Hint: Imagine one marble striking another marble at high speed. Compare this with a marble striking a bowling ball.) Do you think that, in Rutherford’s experiment, the electrons in the gold atoms would deflect the alpha particles significantly? Why or why not? (Hint: The mass of an electron is extremely small.) Rutherford experimented with many kinds of metal foil as the target. The results were always similar. Why was it important to do this? A friend tries to convince you that gold atoms are solid because gold feels solid. Your friend also argues that, because the negatively charged electrons are attracted to the positively charged nucleus, the electrons should collapse into the nucleus. How would you respond? As you know, like charges repel each other. Yet, Rutherford determined that the nucleus contains all of an atom’s positive charges. Invent a theory to explain how all the positive charges can be contained in such a small area without repelling each other. Be creative! Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 120 37

Bohr’s Model Nucleus Electron Orbit Energy Levels 38

Bohr Model of Atom e- e- e-
Increasing energy of orbits n = 3 e- n = 2 n = 1 e- e- In 1913, Niels Bohr proposed a theoretical model for the hydrogen atom that explained its emission spectrum. – His model required only one assumption: The electron moves around the nucleus in circular orbits that can have only certain allowed radii. – Bohr proposed that the electron could occupy only certain regions of space – Bohr showed that the energy of an electron in a particular orbit is En = – hc n2 where  is the Rydberg constant, h is the Planck’s constant, c is the speed of light, and n is a positive integer corresponding to the number assigned to the orbit. n = 1 corresponds to the orbit closest to the nucleus and is the lowest in energy. A hydrogen atom in this orbit is called the ground state, the most stable arrangement for a hydrogen atom. As n increases, the radii of the orbit increases and the energy of that orbit becomes less negative. A hydrogen atom with an electron in an orbit with n >1 is in an excited state — energy is higher than the energy of the ground state. Decay is when an atom in an excited state undergoes a transition to the ground state — loses energy by emitting a photon whose energy corresponds to the difference in energy between the two states. A photon is emitted with energy E = hf The Bohr model of the atom, like many ideas in the history of science, was at first prompted by and later partially disproved by experimentation. 39

An unsatisfactory model for the hydrogen atom
According to classical physics, light should be emitted as the electron circles the nucleus. A loss of energy would cause the electron to be drawn closer to the nucleus and eventually spiral into it. Hill, Petrucci, General Chemistry An Integrated Approach 2nd Edition, page 294 40

Niels Bohr In the Bohr Model (1913) the neutrons and protons occupy a dense central region called the nucleus, and the electrons orbit the nucleus much like planets orbiting the Sun. They are not confined to a planar orbit like the planets are. Niels Bohr ( ) received the Nobel Prize, for his theory of the hydrogen atom, in 1922. Niels Bohr was born in Copenhagen. He is best known for his ground breaking work in atomic theory, which earned him the Nobel Prize in Physics in 1922. He was forced to flee Denmark in Bohr spent the remaining war years in the United States, where he participated in the Manhattan Project. In 1955 he organized the first Atoms for Peace Conference. He died on November 18, 1962 in Copenhagen. Worked on the atomic bomb project in WW II, but after the war, became a strong proponent of peaceful uses of atomic energy.    Niels Bohr was born in Copenhagen in Denmark in His father was a professor of physiology at the University of Copenhagen. Niels attended the same university and was a distinguished soccer player as well as a brilliant student.    Bohr studied at J. J. Thomson´s Cavendish Laboratory and at Rutherford´s laboratory. At the young age of 28, while working with Rutherford, he invented the first effective model and theory of the structure of the atom. His work ranks as one of the truly great examples of an imaginative mind at work. He was awarded the 1922 Nobel Prize for physics for his study of the structure of atoms.    During World War 2, Bohr and his family escaped from occupied Denmark to the United States. He and his son, Aage, acted as advisers at the Los Alomos Atomic Laboratories, where the atom bomb was developed. Thereafter, Bohr concerned himself with developing peaceful uses of nuclear energy. Aage Bohr, Neil´s son was awarded the Nobel Prize for physics in 1975. 41

Bohr’s contributions to the understanding of atomic structure:
1. Electrons can occupy only certain regions of space, called orbits. 2. Orbits closer to the nucleus are more stable — they are at lower energy levels. 3. Electrons can move from one orbit to another by absorbing or emitting energy, giving rise to characteristic spectra. • Bohr’s model could not explain the spectra of atoms heavier than hydrogen. Copyright © 2007 Pearson Benjamin Cummings. All rights reserved. 42