Integrated rate laws Rate laws Mechanisms

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Presentation transcript:

Integrated rate laws Rate laws Mechanisms Lecture 31/36 Integrated rate laws Rate laws Mechanisms

Zero-Order

First Order

Second Order

From data The reaction is first order

Second Order

Zero-Order Rate Law Typical of catalytic processes

First Order Rate Law Mechanism

Complex Rate Law Order is not necessary an integer

Second Order Rate Law This is not a simple bimolecular process 8/20/2019 Second Order Rate Law This is not a simple bimolecular process

Complex Rate Law Mechanism

Complex Rate Law From the B-Z reaction

Elementary Processes First Order Process Second Order Process Third Order Process

Mechanism Overall reaction Mechanism

Mechanism Overall reaction Mechanism

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