Chapter 16: Ethers, Epoxides, and Sulfides

Slides:



Advertisements
Similar presentations
Aldehydes, ketones. Required background: Structure of alkenes Nucleophilic substitution S N 1, S N 2 Essential for: 1. Carboxylic aids and their derivatives,
Advertisements

Goals for the day: Grignard Reaction Ethers (Naming and reactions)
Chapter 8: Ethers and Epoxides Diethyl ether in starting fluid.
Chapter 18: Ethers and Epoxides; Thiols and Sulfides
Ethers and Epoxides; Thiols and Sulfides. 2 Symetrical Ethers Diethyl ether prepared industrially by sulfuric acid– catalyzed dehydration of ethanol –
EthersR-O-R or R-O-R´ Nomenclature: simple ethers are named: “alkyl alkyl ether” “dialkyl ether” if symmetric CH 3 CH 3 CH 3 CH 2 -O-CH 2 CH 3 CH 3 CH-O-CHCH.
11.1 Ethers, Sulfides and Epoxides - 11 Structure, nomenclature, properties Ether synthesis - Williamson synthesis ( S N 2 ) H + /ROH addition to olefins.
Chapter 14 Ethers, Epoxides, and Sulfides
Organic Chemistry Reviews Chapter 11 Cindy Boulton February 8, 2009.
CH 18: Ethers and Epoxides Renee Y. Becker Valencia Community College CHM
Ethers & Epoxides. Ether Nomenclature Compounds that contain two organic groups attached to an oxygen atom General formula is 1. Common Names – Name both.
1 Chapter 9 Alcohols, Ethers and Epoxides. 2 Alcohols contain a hydroxy group (OH) bonded to an sp 3 hybridized carbon. Introduction—Structure and Bonding.
Chapter 18 Ethers and Epoxides; Thiols and Sulfides.
Alcohols < < Nomenclature < < Properties < < Preparation < < Reactions < < Spectroscopy.
Ethers Nomenclatures, methods nof preparations, properties, reactions and uses.
Chapter 14 Ethers, Epoxides, and Sulfides
Chapter 12 Reactions of Alcohols, Ethers, Epoxides, and Sulfur-Containing Compounds Organometallic Compounds Irene Lee Case Western Reserve University.
ETHERS.
Ethers and Epoxides Chem. 108 Chapter 8 1. Ether is a class of organic compounds that contain an ether group R–O–R. For the simplest ether, Dimethyl ether.
Chapter 16 Ethers, Epoxides, and Sulfides
1 Figure 4.3 Examples of cycloalkane nomenclature Nomenclature.
Ethers and Epoxides Chem 145 Chapter
Chapter 11 Alcohols and Ethers
Alcohols Biological Activity Nomenclature Preparation Reactions.
11.1 Ethers, Sulfides and Epoxides Structure, nomenclature, properties Ether synthesis - Williamson synthesis ( S N 2 ) H + /ROH addition to olefins (chapt.
79 Chapter 16: Ethers, Epoxides, and Sulfides 16.1: Nomenclature of Ethers, Epoxides, and Sulfides (Please read) 16.2: Structure and Bonding in Ethers.
1. Learning Objectives Chapter seven discusses the following topics and by the end of this chapter the students will:  Know the structure of ethers 
CHE 242 Unit V Structure and Reactions of Alcohols, Ethers and Epoxides; Basic Principles of NMR Spectroscopy CHAPTER FOURTEEN Terrence P. Sherlock Burlington.
Ethers and Epoxides
The next 2 slides are part of one question.. Which of the following is not a step in the mechanism of the given reaction?
Organic Chemistry Chapter 8 Alcohols, Phenols, and Ethers.
Ethers and Epoxides.
Ethers and Epoxides.
Ethers and Epoxides Dr Nahed Elsayed.
Ethers and Epoxides; Thiols and Sulfides
Ethers and Epoxides
Ethers and Epoxides
Chapter 16: Ethers, Epoxides, and Sulfides
Chapter 18 Ethers and Epoxides; Thiols and Sulfides
Ethers and Epoxides
Chapter 15: Alcohols, Diols, and Ethers
Ethers Ethers are compounds with the general formula: R-O-R’
ETHERS AND EPOXIDES 108 Chem Dr. Shatha I Alaqeel 108 Chem.
18: Ethers and Epoxides; Thiols and Sulfides
Chapter 11: Alcohols and Ethers
Biological Activity Nomenclature Preparation Reactions
Ethers & Epoxides Unit 12.
Ethers & Epoxides Unit 12.
18: Ethers and Epoxides; Thiols and Sulfides
Ethers.
Chem. 108 Ethers and Epoxides Chapter 8.
Ethers.
Chapter 11: Alcohols and Ethers
Ethers.
Chapter 11 Alcohols and Ethers
Chapter 11: Alcohols and Ethers
Chapter 11: Alcohols, Ethers, Epoxides
Ethers and Epoxides 340 Chem 1st 1439.
Ethers and Epoxides
CH 11-4: Epoxide Synthesis and Reactions
Chapter 8 Ethers Adel M. Awadallah Islamic University of Gaza
Alcohols and ethers.
18: Ethers and Epoxides; Thiols and Sulfides
Chapter 18 Ethers and Epoxides; Thiols and Sulfides
Ethers and Epoxides Structure
Ethers.
Ethers The formula is R—O—R¢, where R and R¢ are alkyl or aryl.
TOPIC 10. ALCOHOLS AND ETHERS (chapter 11)
Nucleophilic Substitution: Alkylation of α Carbons
Chapter 8 Ethers Adel M. Awadallah Islamic University of Gaza
Presentation transcript:

Chapter 16: Ethers, Epoxides, and Sulfides

16.1 – Nomenclature of Ethers, Epoxides, and Sulfides

16.2 – Structure and Bonding on Ethers and Epoxides Oxirane (ethylene oxide)

Natural products containing ethers Brevetoxin B

16.3 – Physical Properties of Ethers

16.4 – Crown Ethers

16.4 – Crown Ethers

16.5 – Preparation of Ethers Earlier chapters:

16.6 – The Williamson Ether Synthesis Old lab experiment:

16.7-16.8 – Acid-catalyzed Cleavage of Ethers Symmetrical: nonsymmetrical:

16.9-16.10 – Preparation of Epoxides – Review Epoxidation: From bromohydrins:

16.11-16.12 – Reactions of Epoxides with Nucleophiles

16.13 – Acid-catalyzed Ring Opening of Epoxides

16.14 – Epoxides in Biological Processes

16.15 – Preparation of Sulfides Acid-base reaction followed by SN2

Not covering 16.16 and 16.17