ROSINA, COSAC & PTOLEMY Reviewer: Heather Franz 2/15/16 – 2/17/16

Slides:



Advertisements
Similar presentations
12-1 Molecular Mass Spectroscopy Molecular structure Composition of mixtures Molecular mass spectra Ion Source Mass Spectrometers Applications.
Advertisements

Mass Spectrometry Courtesy Purpose of Mass Spectrometry  Produces spectra of masses from the molecules in a sample of material, and.
Mass Spectroscopy Mass Spectrometry ä Most useful tool for molecular structure determination if you can get it into gas phase ä Molecular weight of.
Lecture 8. GC/MS.
Chem. 133 – 4/28 Lecture. Announcements Lab Report 2.3 due Today Pass back graded materials (lab reports 2.2, Q5, and AP3.1) Today’s Lecture Mass Spectrometry.
Chapter 20 Molecular Mass Spectrometry. Introduction... Mass spectroscopy is perhaps one of the most widely applicable of all the analytical tools available.
Mass Analyzers Double Focusing Magnetic Sector Quadrupole Mass Filter Quadrupole Ion Trap Linear Time-of-Flight (TOF) Reflectron TOF Fourier Transform.
Mass Spectrometry 12-1 to 12-4
Molecular Mass Spectroscopy Chem Introduction In Mass Spectroscopy (MS), atomic and molecular weights are generally expressed in terms of atomic.
Molecular Mass Spectrometry
LC-MS Lecture 7.
Ptolemy: A report, and future plans D. Andrews, S. Barber, G. Morgan, A. Morse, S. Sheridan, I. Wright, C. Pillinger Ptolemy is the result of a collaboration.
Instant Notes Analytical Chemistry
6. Mass Spectrometry Adv. Inst. Techs. How does it work? a very small amount of sample is bombarded by a beam of high energy (usually electron beam) produces.
Russell Rouseff FOS 6355 Summer 2005 What is Mass Spectroscopy Analytical Chemistry Technique Used to identify and quantify unknown compounds Can also.
IMPRS June The principle of time-of-flight (TOF) instruments From the 3 independently measured quantities (E/q, τ, E total ) the 3 desired quantities.
Gas Chromatography And Mass Spectrometry
Types of Chromatography Liquid chromatography versus gas chromatography? Applications? Volatile  GC Non-volatile  LC.
Mass Spectrometry Mass spectrometry (MS) is not true “spectroscopy” because it does not involve the absorption of electromagnetic radiation to form an.
GCMS: gas chromatography and mass spectrometry
By, Blessy Babu. What is Gas Chromatography?  Gas spectroscopy is a technique used to separate volatile components in a mixture.  It is particularly.
Chemical Ideas 7.6 Chromatography. The general principle. Use – to separate and identify components of mixtures. Several different types - paper, thin.
Secondary ion mass spectrometry (SIMS)
Atomic Structure 2.2: The Mass Spectrometry. Operation of Mass Spec Describe and explain the operation of a mass spectrometer What’s it for? A mass spectrometer.
1 Chemical Analysis by Mass Spectrometry. 2 All chemical substances are combinations of atoms. Atoms of different elements have different masses (H =
Mass Spectroscopy 1 Mass Spectroscopy (Mass Spec) Applying Atomic Structure Knowledge to Chemical Analysis.
Chemistry Topic: Atomic theory Subtopic : Mass Spectrometer.
Mass spectrometry (Test) Mass spectrometry (MS) is an analytical technique that measures masses of particles and for determining the elemental composition.
F LORIDA I NTERNATIONAL U NIVERSITY Advanced Mass Spectrometry Piero R. Gardinali/Yong Cai/ Bruce McCord Revised on August 23, 2009.
Mass Spectroscopy Introduction.
Chemistry XXI Unit 1 How do we distinguish substances? M1. Searching for Differences Identifying differences that allow us to separate components. M2.
Mass Spectrometry Relative atomic masses and the mass of individual isotopes can be determined using a mass spectrometer. The principle behind mass spectrometry.
WELCOME STUDENTS Mobile : Skype: aamarpali.puri.
Chem. 133 – 4/26 Lecture. Announcements Return graded quiz and additional problem Lab – Lab report deadlines (2:4 – Thursday) Today’s Lecture – Mass Spectrometry.
Instrumental Analysis
CHROMATOGRAPHY Chromatography is used to separate and analyse small amounts of mixtures Methods involve a stationary phase and a mobile phase. There are.
Metabolomics Part 2 Mass Spectrometry
CHEM133 Mass Spectrometry: Lecture 1
Overview Determining Identity Quantitative Analysis
Chemical Ideas 7.6 Chromatography.
A guide for A level students KNOCKHARDY PUBLISHING
Components of Mass Spectrometer
Review of Basic Atomic Structure, Mass Spectrometry
Analytical Chemistry II ChEm 321
Continuous Flow Isotope Ratio Mass Spectrometry
Chem. 133 – 4/13 Lecture.
Mass Spectrometry Obaid M. Shaikh.
Starter Complete the quiz and hand in..
Mass Spectrometry Courtesy
Mass Spectroscopy. Mass Spectroscopy Mass Spectrometry Most useful tool for molecular structure determination if you can get it into gas phase Molecular.
Mass Spectrometry Courtesy
Instrumental Chemistry
Gas Chromatography.
Instrumental Chemistry
How do we get those numbers? Or What’s in the “Black Box”?
An Introduction to Chromatographic Separations
Mass Spectrometry Courtesy
Nat. Rev. Nephrol. doi: /nrneph
Molecular Mass Spectroscopy
Gas Chromatography.
ROSETTA simulations on SPIS for DFMS ion measurements
Mass Spectrometry THE MAIN USE OF MS IN ORG CHEM IS:
M.Prasad Naidu MSc Medical Biochemistry, Ph.D,.
High-Performance Liquid Chromatography
A guide for A level students KNOCKHARDY PUBLISHING
CHROMATOGRAPHY.
High-Performance Liquid Chromatography
Suppose we make a new compound containing of C,H, and N
Presentation transcript:

ROSINA, COSAC & PTOLEMY Reviewer: Heather Franz 2/15/16 – 2/17/16 Rosetta PDS Review ROSINA, COSAC & PTOLEMY Reviewer: Heather Franz 2/15/16 – 2/17/16

ROSINA

ROSINA Overview ROSINA = Rosetta Orbiter Spectrometer for Ion and Neutral Analysis Two mass spectrometers for neutrals and primary ions Complementary capabilities as pressure sensor Two types of data Mass spectra Pressure records

ROSINA science objectives ROSINA primary objectives To determine elemental, isotopic and molecular composition of the comet atmosphere and ionosphere To measure temperature and bulk velocity of gas To determine homogeneous and inhomogeneous reactions of gas and ions in dusty atmosphere and ionosphere

ROSINA sensors (1) DFMS (double focusing mass spectrometer) High resolution mass spectrometer with magnetic sector analyzer Two basic operating modes - Gas mode & ion mode Three detectors – multichannel plate (MCP), channel electron multiplier (CEM), Faraday cup (FC) In-flight calibration – small gas tube introduces calibrated amounts of noble gas mixture into source

ROSINA sensors (2) RTOF (Reflectron Time-of-Flight) mass spectrometer Two almost independent mass spectrometers Storage channel – for cometary neutral particles Ortho channel – orthogonal extraction source for cometary ions Micro-channel plates (MCPs) of imaging quality for detector Gas Calibration Unit (GCU) – injects defined quantity of known gas mixture (He, CO2 & Kr) into either the storage source or orthogonal source

ROSINA sensors (3) COPS Two sensors Nude gauge – measures total pressure (total neutral particle density) of cometary gas Ram gauge – measures ram pressure, equivalent to cometary gas flux Generated ion currents are measured by high-sensitivity electrometers

ROSINA RIDs See Excel spreadsheet

ptolemy

Ptolemy overview Ptolemy is a miniature gas-processing laboratory Uses chemical processing, GC, in situ calibration and mass spectrometry Determines nature, abundance and stable isotope compositions of volatile species Primary science goal – isotope ratios To determine 13C/12C, 15N/14N, 18O/16O, 17O/16O and D/H ratios of major constituents of a comet.

Ptolemy subsystems Sample Collection (SC) Primarily Sample Drilling and Distribution unit (SD2) Lander oven/carousel for solid samples (ice/organics/silicates) extracted from nucleus by drilling Coma samples are cryogenically trapped on adsorbent in a high-T oven (CASE oven), then heated to release volatiles Gas Distribution and Processing System (GDPS) Heaters, valves, T & P sensors Ovens can heat to 800C (high-T ovens) or 180C (med-T ovens) Med-T ovens are shared by Ptolemy, COSAC and CIVA-ROLIS Gas Chromatography (GC) 3 GC columns with He carrier gas Mass Spectrometer (MS) Ion trap MS with mass range of 15-150 amu and mass resolution better than unity

Ptolemy measurements GC measures retention times of molecular species in separation columns MS measures m/z ratio of ionized fragments of molecular species T and P of various components are monitored

Ptolemy RIDs See spreadsheet

cosac

COSAC overview COSAC = Cometary Sampling and Composition experiment Science objective Identify volatile molecular species in cometary nucleus, especially high-MW organic compounds and chiral analysis Observe variations in volatile compounds evolved from nucleus as function of solar distance

COSAC instruments Gas chromatograph (GC) GC with 8 columns and TCDs – Measures retention times of molecular species Time-of-flight mass spectrometer (TOF) Multi-sphere plate secondary electron multiplier detector Measures time-of-flight of ionized fragments of molecular species Can achieve higher resolution by reflectors for multi-turn mode

COSAC measurements Atmosphere or solid samples Pyrolysis ovens Sample collection (SD2 unit) shared with Ptolemy Pyrolysis ovens Med-T ovens – heat to 180C, shared with Ptolemy High-T ovens – heat to 600C Stepwise heating for 64 levels between -100C and +600C Calibration Includes onboard calibration gas with He, Ne, Kr, and Ar Used to fine-tune voltages, calibrate TOF-MS and check GC performance

COSAC RIDs See spreadsheet