Fibers 11/22/2017 Chem-195

Fibers Fiber: is the smallest unit of a textile material woven or twisted together to form a thread or yarn. Fibers (like hair) are among the most common items left at a crime scene. Class evidence- mass produced by textile difficult to trace back Probative value- can create connection btwn a victim and suspect. (evidence which is sufficiently useful to prove something important in a trial) 11/22/2017 Chem-195

Types of Fabric Weave In a weave, the lengthwise yarn is called the warp. The crosswise yarn is called the weft or woof. Types include: Plain Twill Satin 11/22/2017 Chem-195

Woven Fabric PLAIN Simplest and most common weave Warp and weft pass under each other alternately Design resembles a checkerboard 11/22/2017 Chem-195

Woven Fabric TWILL Create by passing the warp yearn over one to three weft yearns before going under one Makes a diagonal weave Design resembles a stair steps Denim is the most obvious example 11/22/2017 Chem-195

Woven Fabric SATIN The yarn interlacing is not uniform Creates long floats Interlacing weave passes over four or more yarns Satin is the most obvious example 11/22/2017 Chem-195

Knitted Fabric Knitted fabrics are made by interlocking loops into a specific arrangement. It may be one continuous thread or a combination. Diagram: 11/22/2017 Chem-195

Blends use of different fabrics & colors to create the warp and weft patterns. 11/22/2017 Chem-195

Fibers All fibers are made of polymers which are long chains of repeating units. The word polymer means many (poly) units (mer). The repeating units of a polymer are called monomers. 11/22/2017 Chem-195

Fiber Morphology Investigators use: 1. fiber cross section 2. chemical structure 3. synthetic polymers for forensic analysis 11/22/2017 Chem-195

Fiber Cross Section The cross section of a man-made fiber can be manufacturer-specific Unusual cross sections increase fiber association. Cross-sectional views of nylon carpet fibers as seen with a scanning electron microscope (SEM) 11/22/2017 Chem-195

Types of Fibers Natural Synthetic Silk Polyester Cotton Rayon Wool Mohair Cashmere Synthetic Polyester Rayon Nylon Acetate Acrylic Spandex 11/22/2017 Chem-195

Natural Fibers Many different natural fibers that come from plants and animals are used in the production of fabric. Cotton fibers are the plant fibers most commonly used in textile materials The animal fiber most frequently used in the production of textile materials is wool, and the most common wool fibers originate from sheep. 11/22/2017 Chem-195 http://www.fireflydiapers.com/articles/diaperarticle_naturalfibersabsorb.htm

Natural Fibers Wool--animal fiber from sheep, may also be goat (mohair), rabbit (angora), camel, mink, beaver wool: composed of polypeptide keratin chains of amino acid. main bond is sulfur which accounts for the smell of wool when burned Wool Fibers (400X) 11/22/2017 Chem-195

Chemical structure: Natural fibers Silk: composed of proteins, only 2 amino acids Silk--animal fiber produced by silkworms (cocoon) 11/22/2017 Chem-195

# smell like burning leaves # 40% of all fabric is cotton #polymers is glucose # smell like burning leaves # 40% of all fabric is cotton # 60% of all clothes and furniture # low probative value because its too common 11/22/2017 Chem-195

# Contains cellulose (fibers are longer than cotton) Linen: made from flax plant (genus (Linum of the family Linaceae, the flax family) # Contains cellulose (fibers are longer than cotton) # often blended with other fibers because it is brittle. 11/22/2017 Chem-195

Synthetic Fibers More than half of all fibers used in the production of textile materials are synthetic or man-made. Nylon, rayon, and polyester are all examples of synthetic fibers. *nylon and polyester are the most common Fibers under a microscope Cross-section of a man-made fiber Images: http://www.trashforteaching.org/phpstore/product_images/YarnWS.JPG http://www.fbi.gov/hq/lab/fsc/backissu/july2000/deedric3.htm#Fiber%20Evidence http://www.jivepuppi.com/images/fiber_evidence.jpg 11/22/2017 Chem-195

Synthetic Fibers Made from cellulose Rayon--first man-made fiber; Acetate:– made from a reaction with acetic acid. 11/22/2017 Chem-195

Synthetic Fibers (Made from derivatives of petroleum, coal and natural gas) Acrylic- used in carpets Spandex(a type of material that stretches and is used especially for making clothes fit tightly) elastic properties 11/22/2017 Chem-195

Forensics of Fiber Analysis Cross transfers of fiber often occur in cases in which there is person-to-person contact More contact= more fiber transferred 11/22/2017 Chem-195

Forensic Analysis What can be used to identify and compare fibers as forensic evidence? 1. fiber cross section View through microscope Burn test Thermal decomposition Refractive index Chemical test 11/22/2017 Chem-195

Microscopic Examination A compound microscope: uses light The comparison microscope (two compound microscopes joined by an optical bridge) is used for more precise identification.  phase-contrast microscope, reveals fiber structure Scanning electron microscope converts the emitted electrons into a photographic image for display.  This affords high resolution and depth of focus. 11/22/2017 Chem-195

Fiber Comparison Can you tell the difference(s) between the cotton on the left and the rayon on the right? 11/22/2017 Chem-195

Spectrometer The spectrometer, which separates light into component wavelengths.  By passing light through something to produce a spectrum, the analyst can read the resulting lines, called "absorption lines."  specific wavelengths are specific to molecules of the substance.  11/22/2017 Chem-195

Fiber Evidence Collection Fibers are gathered at a crime scene with tweezers, tape, or a vacuum.  They generally come from clothing, drapery, wigs, carpeting, furniture, and blankets.  For analysis, they are first determined to be natural, manufactured, or a mix of both. 11/22/2017 Chem-195

Steps of Fiber Analysis The first step in fiber analysis is to compare color and diameter.  Dyes can also be further analyzed with chromatography, which uses solvents to separate the dye's chemical constituents.  11/22/2017 Chem-195

Fiber Color Color influences the value given to a particular fiber identification. Often several dyes are used How color is applied and absorbed along the length of the fiber are important comparison characteristics. Color-fading and discoloration can also lend increased value to a fiber association. 11/22/2017 Chem-195

Fiber Analysis 11/22/2017 Chem-195

Testing Fibers Burn Test: look @ how a fiber burns, its odor, and appearance of ash. Thermal decomposition: how a fiber breaks down when heated. *it returns to its monomer (initial building block) * ex: Acetate acetic acid litmus test will turn paper blue to red 11/22/2017 Chem-195

Thermal Decomposition of fiber activity 11/22/2017 Chem-195

3) Chemical test: test the solubility and decomposition of a fabric using a strong acids (Hydrochloric acid or sulfuric acid) or strong bases (NaOCl, acetone, NaOH) – this determines the fabrics polymers. 4) Density: m/v (pg. 148). Density of water is 1.00 g/ml. Olefin is the only fabric that will float in water. 11/22/2017 Chem-195

5) Refractive index: bending of light as it passes from air into a solid or liquid -- investigators measure the refractive index of an unknown sample with liquids of a known refractive index. --place sample in different liquids until Becke line is no longer visible liquid same index as fabric liquid w/ w/ high index low refractive index A B C 11/22/2017 Chem-195

6) Fluorescence: some fibers will fluoresce when exposed to UV light --- laundry soap and some bleach has whiting agents that cause blue light to be reflected making it appear whiter. 7)Dyes: investigators use a fabric to see if it accepts a particular dye to identify and compare it to an unknown sample 11/22/2017 Chem-195

Rf value = distance of pigment 8) Chromatography: separation of dyes by thin layer chromatography (TLC) Rf value = distance of pigment distance of solvent front 11/22/2017 Chem-195

Other test used in Fiber Analysis 9) FTIR: Fourier Transform Infrared based on the absorption and wavelength of light in a fabrics polymer. can be used on a single fiber Non-destructive 10) PGS-MS: Pyrolysis Gas Chamber-Mass Spectrometry Burns and separates each combustion product of sample Match results of chromatogram & products to known Can be used in short length fibers but is destructive. 11/22/2017 Chem-195

Fiber Forensics FYI analyst gets only a limited number of fibers to work with—sometimes only one. Fibers are sent to the lab for analysis. Fibers from scene are compared to victim 11/22/2017 Chem-195

Fiber Transfer and Persistence Fibers can be used as trace evidence due to fiber transfer. How easy the fiber is transferred is affected by: Area of contact the amount of pressure used Any friction due to side to side contact Number of passes or contacts Kind of clothing donor/recipient was wearing Fiber type, length and texture History of the garment. 11/22/2017 Chem-195

How long transfer fibers remain on victim is fiber persistence. Time of wear and movement What is covering the fabric Type of activity Weather condition ** fiber persistence decreases exponentially (with reference to an increase) more and more rapidly. with time of wear. 11/22/2017 Chem-195

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A B C D E F Types of Fibers - Key Acrylic Yarn Cotton Yarn Nylon Rope Polyester Yarn Rayon Rope Wool Yarn 11/22/2017 Chem-195