Electrochemistry Lesson 6 Balancing Redox Reactions.

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Presentation transcript:

Electrochemistry Lesson 6 Balancing Redox Reactions

Balancing Redox Full Reactions in Acid Solution

MnO C 2 O 4 2- →MnO 2 + CO 3 2-

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO Separate into half reactions.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO 4 - →MnO 2 C 2 O 4 2- →CO Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO 4 - →MnO 2 C 2 O 4 2- →2CO Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO 4 - →MnO 2 + 2H 2 O C 2 O 4 2- →2CO Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO 4 - →MnO 2 + 2H 2 O C 2 O H 2 O →2CO Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO H + →MnO 2 + 2H 2 O C 2 O H 2 O →2CO Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO H + →MnO 2 + 2H 2 O C 2 O H 2 O →2CO H + 1.Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO H + + 3e - →MnO 2 + 2H 2 O C 2 O H 2 O →2CO H + 1.Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO H + + 3e - →MnO 2 + 2H 2 O C 2 O H 2 O →2CO H + + 2e - 1.Separate into half reactions. 2.Balance each half reaction.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO 3 2- MnO H + + 3e - →MnO 2 + 2H 2 O C 2 O H 2 O →2CO H + + 2e - 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO (MnO H + + 3e - →MnO 2 + 2H 2 O) 3(C 2 O H 2 O →2CO H + + 2e - ) 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO (MnO H + + 3e - →MnO 2 + 2H 2 O) 3(C 2 O H 2 O →2CO H + + 2e - ) 2MnO H + + 3C 2 O H 2 O→ 2MnO 2 + 4H 2 O + 6CO H + 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions.

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO (MnO H + + 3e - →MnO 2 + 2H 2 O) 3(C 2 O H 2 O →2CO H + + 2e - ) 2MnO H + + 3C 2 O H 2 O→ 2MnO 2 + 4H 2 O + 6CO H + 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions. 4.Simplify

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO (MnO H + + 3e - →MnO 2 + 2H 2 O) 3(C 2 O H 2 O →2CO H + + 2e - ) 24 2MnO H + + 3C 2 O H 2 O→ 2MnO 2 + 4H 2 O + 6CO H + 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions. 4.Simplify

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO (MnO H + + 3e - →MnO 2 + 2H 2 O) 3(C 2 O H 2 O →2CO H + + 2e - ) 2MnO C 2 O H 2 O→ 2MnO 2 + 6CO H + 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions. 4.Simplify

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO (MnO H + + 3e - →MnO 2 + 2H 2 O) 3(C 2 O H 2 O →2CO H + + 2e - ) 2MnO C 2 O H 2 O→ 2MnO 2 + 6CO H + 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions. 4.Simplify 5.Check

Balancing Redox Full Reactions in Acid Solution MnO C 2 O 4 2- →MnO 2 + CO (MnO H + + 3e - →MnO 2 + 2H 2 O) 3(C 2 O H 2 O →2CO H + + 2e - ) MnO C 2 O H 2 O→ 2MnO 2 + 6CO H + 1.Separate into half reactions. 2.Balance each half reaction. 3.Add the two half reactions. 4.Simplify 5.Check

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O H 2 O→ 2MnO 2 + 6CO H +

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O H 2 O→ 2MnO 2 + 6CO H + 1.Balance in acid solution

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O H 2 O→ 2MnO 2 + 6CO H + 1.Balance in acid solution 2.Add OH - to neutralize the H +

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O H 2 O→ 2MnO 2 + 6CO H + 4OH - 4OH - 1.Balance in acid solution 2.Add OH - to neutralize the H + 3.Simplify

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O H 2 O→ 2MnO 2 + 6CO H + 4OH - 4OH - 4H 2 O 1.Balance in acid solution 2.Add OH - to neutralize the H + 3.Simplify

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O OH - → 2MnO 2 + 6CO H 2 O 1.Balance in acid solution 2.Add OH - to neutralize the H + 3.Simplify

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O OH - → 2MnO 2 + 6CO H 2 O 1.Balance in acid solution 2.Add OH - to neutralize the H + 3.Simplify 4.Check

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O OH - → 2MnO 2 + 6CO H 2 O 1.Balance in acid solution 2.Add OH - to neutralize the H + 3.Simplify 4.Check

Balancing Redox Full Reactions in Basic Solution 2MnO C 2 O OH - → 2MnO 2 + 6CO H 2 O-12 1.Balance in acid solution 2.Add OH - to neutralize the H + 3.Simplify 4.Check

Balancing Redox Full Reactions in Basic Solution Fe+O 2 → H 2 O+Fe(OH) 2

Balancing Redox Full Reactions in Basic Solution Fe→Fe(OH) 2 O 2 → H 2 O

Balancing Redox Full Reactions in Basic Solution Fe +2H 2 O→Fe(OH) 2 O 2 → H 2 O + H 2 O

Balancing Redox Full Reactions in Basic Solution Fe +2H 2 O→2H + +Fe(OH) 2 O 2 +4H + → H 2 O + H 2 O

Balancing Redox Full Reactions in Basic Solution Fe +2H 2 O→2H + +Fe(OH) 2 + 2e - 4e - + O 2 +4H + → H 2 O + H 2 O

Balancing Redox Full Reactions in Basic Solution 2(Fe +2H 2 O→2H + +Fe(OH) 2 + 2e - ) 4e - + O 2 +4H + → H 2 O + H 2 O

Balancing Redox Full Reactions in Basic Solution 2(Fe +2H 2 O→2H + +Fe(OH) 2 + 2e - ) 4e - + O 2 +4H + → H 2 O + H 2 O 2Fe + 4H 2 O + O 2 +4H + → 4H + + 2Fe(OH) 2 + 2H 2 O

Balancing Redox Full Reactions in Basic Solution 2(Fe +2H 2 O→2H + +Fe(OH) 2 + 2e - ) 4e - + O 2 +4H + → H 2 O + H 2 O 2 2Fe + 4H 2 O + O 2 +4H + → 4H + + 2Fe(OH) 2 + 2H 2 O

Balancing Redox Full Reactions in Basic Solution 2(Fe +2H 2 O→2H + +Fe(OH) 2 + 2e - ) 4e - + O 2 +4H + → H 2 O + H 2 O 2 2Fe + 4H 2 O + O 2 + 4H + → 4H + + 2Fe(OH) 2 + 2H 2 O 2Fe + 2H 2 O + O 2 → 2Fe(OH) 2

Balancing Redox Full Reactions in Basic Solution 2(Fe +2H 2 O→2H + +Fe(OH) 2 + 2e - ) 4e - + O 2 +4H + → H 2 O + H 2 O 2Fe + 2H 2 O + O 2 → 2Fe(OH) 2 No need to add OH -

As→H 2 AsO 4 - +AsH 3 (alkaline) 3(As+ 4H 2 O→H 2 AsO H + + 5e - ) 5(3H + +As+ 3e - →AsH 3 ) 3As + 12H 2 O + 15H + + 5As → 3H 2 AsO H + + 5AsH 3 8As + 12H 2 O → 3H 2 AsO H + + 5AsH 3 3OH - 3OH - + 8As + 9H 2 O → 3H 2 AsO AsH 3-3