Measurements and modeling of water vapor from solar spectral irradiance during ATTREX Bruce Kindel, Peter Pilewskie, Sebastian Schmidt, Troy Thornberry,

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Measurements and modeling of water vapor from solar spectral irradiance during ATTREX Bruce Kindel, Peter Pilewskie, Sebastian Schmidt, Troy Thornberry, Drew Rollins, Samuel LeBlanc, and Paul Bui.

Solar Spectral Flux Radiometer (SSFR) Zeiss Monolithic Spectrometer VIS-NIR: 256 element silicon diode array nm, 3.0 nm sampling, 8 nm FWHM NIR: 256 element InGaAs array nm, 5.0 nm sampling, 16 nm FWHM 16-bit system NIST traceable calibration Integrating sphere for cosine response

SSFR Irradiance (Zenith & Nadir 18km) Water vapor transmittance (0-100 km) Wavelength (nm) Irradiance m -2 nm -1 / Transmittance

SSFR Irradiance (Zenith & Nadir 18km) Water vapor transmittance (14, km) Wavelength (nm) Irradiance W m -2 nm -1 / Transmittance

SSFR transmittance spectra SF1 Transmittance = zenith (low alt) / zenith (high alt)

Radiative Transfer Modeling MODTRAN5.3.2 updated to HITRAN cm -1 sampling 2 cm -2 resolution convolved with the SSFR slit function User defined atmosphere, vertical profile of water vapor from NOAA, pressure and temperature from MMS. Default tropical values for other species. Model vertical resolution of 250 meters, ~14 levels over the profile

ZH Z = Vertical distance between profile altitudes H = Solar slant path

SSFR-SSFR

MODTRAN-SSFR Mean & Stdev 11 cases Wavelength (nm) Transmittance Difference (MODTRAN-SSFR)

SSFR MODTRAN Water Vapor Transmittance SSFR MODTRAN

Irradiance (W m -2 nm -1 ) Transmittance Wavelength (nm) TOA Solar Spectrum 20 km 18 km TOA-20 km TOA-18 km

Summary First results of measuring UTLS water vapor in the strong water vapor bands at 1400 and 1900 nm from solar irradiance are encouraging. SSFR transmittances (absorptances) correlate well with integrated values from NOAA in situ water vapor profiles. Comparisons with atmospheric radiative transfer modeling (MODTRAN) using atmospheric profiles of water vapor, pressure, and temperature display a consistent bias in the computed transmittances as compared to measurements. This technique may provide a near real time measure of column integrated water vapor from aircraft altitude to the top of the atmosphere along the solar slant path.