By : Ana Alina & Firdiana Sanjaya. Each time a photon bounces off the electron, momentum is transferred to the electron. The more photons you use, the.

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Presentation transcript:

By : Ana Alina & Firdiana Sanjaya

Each time a photon bounces off the electron, momentum is transferred to the electron. The more photons you use, the more momentum is transferred, and because you can't measure that momentum transferred to infinite precision the more uncertainty you're introducing in the measurement of the momentum of the electron

Heisenberg showed that there is a limit to the accuracy you can measure things:  x  p  h / 2  The uncertainty can also be stated in terms of the energy of a particle in a particular state, and the time in which the particle is in that state:  E  t  h / 2 

The Bohr model of the atom involves a single quantum number, the integer n that appears in the expression for the energy of an electron in an orbit. This picture of electrons orbiting a nucleus in well-defined orbits, the way planets orbit the Sun, is not our modern view of the atom.

The energy E n = - (13.6 eV) Z 2 / n 2, (n = 1, 2, 3, … ) The angular momentum of the electron L = [ ( +1)] 1/2 h / 2 , (n = 1, 2, 3, … )

The magnetic quantum number ( ) is related to one particular component of the angular momentum. By convention, we call this the z-component. The z-component of the electron's angular momentum is given by:

A very important difference between the Bohr model and the full quantum mechanical treatment of the atom is that Bohr proposed that the electrons were found in very well-defined circular orbits around the nucleus, while the quantum mechanical picture of the atom has the electron essentially spread out into a cloud. We call this a probability density cloud, because the density of the cloud tells us what the probability is of finding the electron at a particular distance from the nucleus.

In quantum mechanics, something called a wave function is associated with each electron state in an atom. The probability of finding an electron at a particular distance from the nucleus is related to the square of the wave function, so these electron probability density clouds are basically three-dimensional pictures of the square of the wave function.

If you've got a hydrogen atom, with only a single electron, it's very easy to determine the possible states that electron can occupy. A particular state means one particular combination of the 4 quantum numbers; there are an infinite number of states available, but the electron is more likely to occupy a low- energy state (i.e., a low n state) than a higher-energy (higher n) state.

What happens for other elements, when there is more than one electron to worry about? Can all the electrons be found in one state, the ground state, for example?  The Pauli exclusion principle states that no two electrons can occupy the same state. In other words, no two electrons can have the same set of 4 quantum numbers.

A shell consists of all those states with the same value of n, the principal quantum number. A subshell groups all the states within one shell with the same value of, the orbital quantum number.

The subshells are usually referred to by letters, rather than by the corresponding value of the orbital quantum number. The letters s, p, d, f, g, and h stand for values of 0, 1, 2, 3, 4, and 5, respectively. Using these letters allows us to use a shorthand to denote how many electrons are in a subshell; this is useful for specifying the ground state (lowest energy state) of a particular atom.

When Mendeleyev organized the elements into the periodic table, he knew nothing about quantum numbers and subshells. The way the elements are organized in the periodic table, however, is directly related to how the electrons fill the levels in the different shells

Different columns of the periodic table group elements with similar properties; they have similar properties because of the similarities between their ground state electron configurations. The noble gases (He, Ne, Ar, etc.) are all in the right-most column of the periodic table. Their ground state configurations have no partially filled subshells; having a complete subshell is favorable from the standpoint of minimizing energy so these elements do not react readily

On the other hand, the column next to the noble gases is the halogens; these are one electron short of having completely-filled subshells, so if they can share an electron from another element they're happy to do so. They react readily with elements whose ground state configurations have a single electron in one subshell like the alkali metals (Li, Na, K, etc.)