Fiber Analysis Hair and Fiber 3

Fiber Evidence Fiber –The smallest unit of a textile material that has a length many times greater than its diameter –Can be spun with other fibers to form a yarn (rope) that can be woven or knitted to form a fabric Can be natural (plant or animal) or man- made –Man-made fibers now account for over ½ of all textile production

Forensic Value Are considered class evidence Are common trace evidence at a crime scene Can be characterized based on comparison of both physical and chemical properties

Fiber Classification Natural fibers are classified according to their origin –Vegetable or cellulose –Animal or protein –Mineral Some natural fibers can be altered into artificial ones –Cotton and rayon –Rayon is chemically-altered cellulose

Chemical Alteration Note the differences between the cotton fiber (left) and rayon (right). Can you detect what happens in the chemical transformation process?

Fiber Evidence Important characteristics –Type and length of fiber –Spinning method –Fabric construction Above characteristics can greatly affect transfer of fibers and significance as evidence Can originate from more than clothing –Furniture, upholstery, etc.

Fiber Evidence Significance –Based upon clear relationships between objects associated with crime –Relative value of evidence can be based upon several factors Type of fiber Number of fibers Color or variation of color Location of fibers Number of different fibers Likelihood of transfer based on fiber construction

Fiber Evidence Useful in similar crimes to hairs Since DNA is not found, often limited to class characteristics due to mass production Transfer usually found through physical contact Routinely found in vehicle accidents or on glass/screens

Animal Fibers Silk –Technically a protein secretion –Among the most expensive fibers –Fibers are altered by changing diet of silkworm –Does not resemble typical non-human hair

Mineral Fibers Fiberglass –Artificially produced fiber Asbestos –Natural fiber from the mineral serpentine

Plant Fibers Cotton –Most common plant fiber –Virtually worthless as evidence if white If dyed, the dye is more valuable than the cotton –Distinctive twisted, ribbon-like shape

Plant Fibers Ramie fiber, common in SE Asia Hemp fiber, the strongest natural fiber Jute fiber, also common in Asia Plant fibers are based on the polymer cellulose, the chemical that forms the cell wall of plant cells

Synthetic Fiber Chemistry Polymers –Well known natural polymers Starch Cellulose - nature of polymer provided structure to plants Proteins - form animal hairs –Well known man-made polymers Nylon Teflon Silicone

Synthetic Fiber Chemistry Man-made polymers –Basic chemical substance of all artificial fibers –Also include most paints, plastics, adhesives, rubbers Polymers are routinely formed from thousands of individual atoms Composed of repeating units called monomers that link like chains

Synthetic Fiber Chemistry “Classic” polymer structure of the synthetic fiber nylon. Note the long chain of repeating atoms.

Synthetic Fibers In spite of common names, practically no two of the same type of fiber are manufactured the same way all the way through the production process Positive ID almost always involves microscopy and chemical analysis Three different scanning electron microscope images of nylon carpet fibers. Note clear structural differences at this magnification.

Synthetic Fiber Analysis Identification and Comparison Color –Based on introduced combinations of dyes –Different dyes may identify manufacturer Diameter –Typically very little variation due to precise machinery –Cross section usually helpful as well Typical cross section of synthetic carpet fibers.

Synthetic Fiber Analysis Production method can be single largest identifier Cross sections are exceptionally important –Synthetic fibers are forced out of a nozzle when they are hot –Holes of the nozzle are not always round

Synthetic Fiber Analysis Burning Chemistry of fibers can cause fiber to burn in different ways Odor, color of flame, smoke and the appearance of the residue can also be an indicator Thermal decomposition Gently heating can break down polymers to basic monomers Chemical testing Solubility and decomposition

Questions The most common type of plant fiber is… a)cotton b) woolc) mohair d) hemp

What is the definition of a polymer?

In plant-based fibers, the polymer _____________ is the major component of the fiber. This polymer is composed of the monomer ____________.