5. The Harmonic Oscillator Consider a general problem in 1D Particles tend to be near their minimum Taylor expand V(x) near its minimum Recall V’(x 0 )

Slides:



Advertisements
Similar presentations
Non-degenerate Perturbation Theory
Advertisements

Mathematical Formulation of the Superposition Principle
Matrix Representation
Quantum One: Lecture 6. The Initial Value Problem for Free Particles, and the Emergence of Fourier Transforms.
Commutators and the Correspondence Principle Formal Connection Q.M.Classical Mechanics Correspondence between Classical Poisson bracket of And Q.M. Commutator.
Quantum One: Lecture 4. Schrödinger's Wave Mechanics for a Free Quantum Particle.
The Klein-Gordon Equation
P460 - angular momentum1 Orbital Angular Momentum In classical mechanics, conservation of angular momentum L is sometimes treated by an effective (repulsive)
P460 - angular momentum1 Orbital Angular Momentum In classical mechanics, conservation of angular momentum L is sometimes treated by an effective (repulsive)
Chapter 3 Determinants and Matrices
PHYS Quantum Mechanics PHYS Quantum Mechanics Dr Gavin Smith Nuclear Physics Group These slides at:
101 Outline I.The infinite square well II. A comment on wavefunctions at boundaries III.Parity IV.How to solve the Schroedinger Equation in momentum space.
2. Solving Schrödinger’s Equation Superposition Given a few solutions of Schrödinger’s equation, we can make more of them Let  1 and  2 be two solutions.
8. Spin and Adding Angular Momentum 8A. Rotations Revisited
4. The Postulates of Quantum Mechanics 4A. Revisiting Representations
Boyce/DiPrima 9th ed, Ch 11.2: Sturm-Liouville Boundary Value Problems Elementary Differential Equations and Boundary Value Problems, 9th edition, by.
Introduction to Quantum Theory of Angular Momentum
Orbital Angular Momentum
The Harmonic Oscillator
States, operators and matrices Starting with the most basic form of the Schrödinger equation, and the wave function (  ): The state of a quantum mechanical.
Physics 3 for Electrical Engineering Ben Gurion University of the Negev
8.1 Vector spaces A set of vector is said to form a linear vector space V Chapter 8 Matrices and vector spaces.
Physics 3 for Electrical Engineering
Chang-Kui Duan, Institute of Modern Physics, CUPT 1 Harmonic oscillator and coherent states Reading materials: 1.Chapter 7 of Shankar’s PQM.
Chap 3. Formalism Hilbert Space Observables
3. Hilbert Space and Vector Spaces
generates 3-dimensional rotations
Quantum One: Lecture Representation Independent Properties of Linear Operators 3.
Operators A function is something that turns numbers into numbers An operator is something that turns functions into functions Example: The derivative.
Physics 3 for Electrical Engineering Ben Gurion University of the Negev
Quantum theory of spin: algebraic approach in analogy with classical physics, we believe that a spinning mass carries intrinsic angular momentum, along.
1 MODELING MATTER AT NANOSCALES 4. Introduction to quantum treatments The variational method.
PHYS 773: Quantum Mechanics February 6th, 2012
7. Angular Momentum The order in which you rotate things makes a difference,  1  2   2  1 We can use this to work out commutation relations for the.
Angular Momentum Classical radius vector from origin linear momentum determinant form of cross product Copyright – Michael D. Fayer, 2007.
5. Quantum Theory 5.0. Wave Mechanics
Quantum Two 1. 2 Angular Momentum and Rotations 3.
2. Time Independent Schrodinger Equation
P460 - operators and H.O.1 Operator methods in Quantum Mechanics Section 6-1 outlines some formalism – don’t get lost; much you understand define ket and.
MODELING MATTER AT NANOSCALES 4. Introduction to quantum treatments Eigenvectors and eigenvalues of a matrix.
MODULE 13 Time-independent Perturbation Theory Let us suppose that we have a system of interest for which the Schrödinger equation is We know that we can.
Quantum Two 1. 2 Angular Momentum and Rotations 3.
Mathematical Formulation of the Superposition Principle
Q. M. Particle Superposition of Momentum Eigenstates Partially localized Wave Packet Photon – Electron Photon wave packet description of light same.
Matrices and vector spaces
17. Quantization of Electromagnetic Fields
Chapter 6 Angular Momentum.
Announcements Read 8E-8F, 7.10, 7.12 (me = 0), 7.13
Non-degenerate Perturbation Theory
Angular Momentum Classical radius vector from origin linear momentum
Quantum One.
3. Boundary Value Problems II 3A. The Spherical Harmonics
Spin and Magnetic Moments
Chapter 4 Quantum Mechanics in 3D.
Quantum One.
4. The Postulates of Quantum Mechanics 4A. Revisiting Representations
Quantum One.
The Harmonic Oscillator
2. Solving Schrödinger’s Equation
Quantum Two.
12. Approx. Methods for Time Ind. Systems
Orbital Angular Momentum
The Stale of a System Is Completely Specified by lts Wave Function
Quantum Mechanics Postulate 4 Describes expansion
Addition of Angular Momenta
Chapter 5 1D Harmonic Oscillator.
Solution of the differential equation Operator formalism
16. Angular Momentum Angular Momentum Operator
Linear Vector Space and Matrix Mechanics
Presentation transcript:

5. The Harmonic Oscillator Consider a general problem in 1D Particles tend to be near their minimum Taylor expand V(x) near its minimum Recall V’(x 0 ) = 0 Constant term is irrelevant We can arbitrarily choose the minimum to be x 0 = 0 We define the classical angular frequency  so that All Problems are the Harmonic Oscillator

Raising and Lowering Operators 5A. The 1D Harmonic Oscillator First note that V(  ) = , so only bound states Classically, easy to show that the combination m  x + ip has simple behavior With a bit of anticipation, we define We can write X and P in terms of these:

Commutators and the Hamiltonian We will need the commutator Now let’s work on the Hamiltonian

Raising and Lowering the Eigenstates Let’s label orthonormal eigenstates by their a † a eigenvalue If we act on an eigenstate with a or a †, it is still an eigenstate of a † a : Lowering Operator: Raising Operator: We can work out the proportionality constants:

It is easy to see that since ||a|n  || 2 = n, we must have n  0. This seems surprising, since we can lower the eigenvalue indefinitely This must fail eventually, since we can’t go below n = 0 –Flaw in our reasoning: we assumed implicitly that a|n   0 If we lower enough times, we must have a|n  = 0  ||a|n  || 2 = 0 Conclusion: if we lower n repeatedly, we must end at n = 0 –n is a non-negative integer If we have the state |0 , we can get other states by acting with a † –Note: |0   0 What are the possible eigenvalues

Sometimes – rarely – we want the wave functions Let’s see if we can find the ground state |0  : The Wave Functions (1) Normalize it:

The Wave Functions (2) Now that we have the ground state, we can get the rest Almost never use this! –If you’re doing it this way, you’re doing it wrong n = 3 n = 2 n = 1 n = 0

Working with the Harmonic Oscillator 5B. Working with the H.O. & Coherent States It is common that we need to work out things like  n|X|m  or  n|P|m  The wrong way to do this: The right way to do this: Abandon all hope all ye who enter here

Sample Problem At t = 0, a 1D harmonic oscillator system is in the state (a) Find the quantum state at arbitrary time (b) Find  P  at arbitrary time

Sample Problem (2) (b) Find  P  at arbitrary time

Coherent States Can we find eigenstates of a and a † ? Yes for a and no for a † Because a is not Hermitian, they can have complex eigenvalues z –Note that the state |z = 1  is different from |n = 1  Let’s find these states: Act on both sides with  m|: Normalize it

Comments on Coherent States They have a simple time evolution Suppose at t = 0, the state is Then at t it will be When working with this state, avoid using the explicit form Instead use: And its Hermitian conjugate equation: Recall: these states are eigenstates of a non-Hermitian operator –Their eigenvalues are complex and they are not orthogonal These states roughly resemble classical behavior for large z –They can have large values of  X  and  P  –While having small uncertainties  X and  P

Sample Problem Find  X for the coherent state |z 

All Problems are the Harmonic Oscillator 5C. Multiple Particles and Harmonic Oscillator Consider N particles with identical mass m in one dimension This could actually be one particle in N dimensions instead These momenta & position operators have commutation relations: Taylor expand about the minimum X 0. Recall derivative vanishes at minimum A constant term in the Hamiltonian never matters We can always change origin to X 0 = 0. Now define: We now have:

Solving if it’s Diagonal To simplify, assume k ij has only diagonal elements: We define  i 2 = k i /m: Next define Find the commutators: Write the Hamiltonian in terms of these: Eigenstates and Eigenenergies:

Note that the matrix made of k ij ’s is a real symmetric matrix (Hermitian) Classically, we would solve this problem by finding the normal modes First find eigenvectors of K: –Since K is real, these are real eigenvectors Put them together into a real orthogonal matrix –Same thing as unitary, but for real matrices Then you can change coordinates: Written in terms of the new coordinates, the behavior is much simpler. The matrix V diagaonalizes K Will this approach work quantum mechanically? What if it’s Not Diagonal?

Define new position and momentum operators as Because V is orthogonal, these relations are easy to reverse The commutation relations for these are: We now convert this Hamiltonian to the new basis: Does this Work Quantum Mechanically?

The procedure: Find the eigenvectors |v  and eigenvalues k i of the K matrix Use these to construct V matrix Define new operators X i ’ and P i ’ The eigenstates and energies are then: Comments: To name states and find energies, all you need is eigenvalues k i Don’t forget to write K in a symmetric way! The Hamiltonian Rewritten:

Sample Problem Name the eigenstates and find the corresponding energies of the Hamiltonian Find the coefficients k ij that make up the K matrix NO! Remember, k ij must be symmetric! So k 12 = k 21 Now find the eigenvalues: The states and energies are:

It Isn’t Really That Complex 5C. The Complex Harmonic Oscillator A classical complex harmonic oscillator is a system with energy given by Where z is a complex position Just think of z as a combination of two real variables: Substituting this in, we have: We already know everything about quantizing this: More usefully, write them in terms of raising and lowering operators: The Hamiltonian is now:

Working with complex operators Writing z in terms of a and a † Let’s define for this purpose Commutation relations: All other commutators vanish In terms of these, And the Hamiltonian:

The Bottom Line If we have a classical equation for the energy: Introduce raising/lowering operators with commutation relations The Hamiltonian in terms of these is: Eigenstates look like: For z and z* and their derivatives, we substitute: This is exactly what we will need when we quantize EM fields later