1. Ch 19 Reactions of Benzene 1. Give the products of the following electrophilic aromatic substitution reactions. Also show how the electrophile is generated in each case. a. b.

2. Ch 19 Reactions of Benzene c. d. e.

3. Ch 19 Reactions of Benzene f. g.

4. Ch 19 Reactions of Benzene 2. Design a synthesis for the following, starting with benzene: a. d. b. e. c.

5. Ch 19 Reactions of Benzene 3. Name the following: a. b. c. d.

6. Ch 19 Reactions of Benzene 4. Put the following in order of acidity:

7. Ch 19 Reactions of Benzene 5. Give the products of the following reactions. If no reaction occurs, so state. a. b.

8. Ch 19 Reactions of Benzene c. d. e.

9. Ch 19 Reactions of Benzene f. (show the mechanism for the above reaction)

10. Ch 19 Reactions of Benzene 6. Fill in the missing reagents and products for the following arenediazonium reactions:

11. Ch 19 Reactions of Benzene 7. Give the product and mechanism of the following nucleophilic aromatic substitution:

12. Ch 19 Reactions of Benzene 8. Show how the following could be synthesized from benzene. a. b. c. d. e. f.