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Atomic Modifications and Doping of Metal Oxides for Commercially Significant Partial Oxidation J. Gleaves and G. Yablonski Heterogeneous Kinetics and Particle.

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Presentation on theme: "Atomic Modifications and Doping of Metal Oxides for Commercially Significant Partial Oxidation J. Gleaves and G. Yablonski Heterogeneous Kinetics and Particle."— Presentation transcript:

1 Atomic Modifications and Doping of Metal Oxides for Commercially Significant Partial Oxidation J. Gleaves and G. Yablonski Heterogeneous Kinetics and Particle Chemistry Laboratory http://crelonweb.wustl.edu

2 Heterogeneous Selective Oxidation Programs Heterogeneous Kinetics and Particle Chemistry Laboratory (HKPCL) Chemical Reaction Engineering Laboratory (CREL) Chemical Engineering Dept., Washington University, St. Louis, MO CH 4 + 1/2O 2 CO + 2H 2 Fuels, Chemicals Supported metal CH 2 CHCOOH CH 3 CH 2 CH 3 + 2O 2 + 2H 2 O propaneacrylic acid Metal oxide CH 2 CHCN CH 3 CH 2 CH 3 + 2O 2 + NH 3 + 4H 2 O propaneacrylonitrile Metal oxide + 1/2 O 2 + H 2 O Metal oxide C2H5C2H5 CH CH 2 ethylbenzene styrene + 1/2 O 2 propenepropene oxide Metal oxide CH 2 CHCH 3 H 2 C CHCH 3 O

3 TAP-2 - Atomic Deposition System Deposition chamber Mass spectrometer TAP Reactor chamber Diffusion pump


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