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Topics ACOPhys “Opening Week” Get-together by examples 1.) Organic Optoelectronics 2.) Electronic Structure of Organic Materials 3.) Plastic Solar Cell.

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Presentation on theme: "Topics ACOPhys “Opening Week” Get-together by examples 1.) Organic Optoelectronics 2.) Electronic Structure of Organic Materials 3.) Plastic Solar Cell."— Presentation transcript:

1 Topics ACOPhys “Opening Week” Get-together by examples 1.) Organic Optoelectronics 2.) Electronic Structure of Organic Materials 3.) Plastic Solar Cell 4.) Random Matrix Theory and Excitons in Disordered Quantum Wells Planning next steps

2 Get-together by means of examples: Discussing Quantum Wells and Wires Prof. Gerhard Gobsch, “Applied Physics” Prof. Erich Runge, “Computational Physics” Technical University of Ilmenau, Institute of Physics

3 Semiconductors : An energy gap separates states of mobile electrons from states of mobile holes in the so-called valence band, which is otherwise occupied by electrons. What happens if electrons and holes meet ? What happens at the interface of two semiconductors ? Energy Position

4 Light Emitting Diodes (LED) + Semiconductor quantum well lasers... and the hairy details as presented by the world‘s best-known expert The simple view of a theoretical physicist... Energy Position Nobel prize 2000: Kroemer und Alferov

5 http://britneyspears.ac/physics/fplasers/images/dhlaser.jpg Light Emitting Diodes (LED) + Semiconductor quantum well lasers... and the hairy details as presented by the world‘s best-known expert

6 The Gallium Nitride Revolution: LEDs and lasers based on InGaN / GaN quantum wells Does the revolution eat its children? ‘‘Long reign the OLED’’

7 Band gaps of hexagonal nitride compounds

8 What about Quantum Mechanics ?

9 http://www.almaden.ibm.com/ almaden/media/image_mirage.html Electrons show wave-like properties,...... some of them are easily explained...... and some are a bit harder to get used to... Energy Position What about Quantum Mechanics ?

10 0 1 eV 2 eV 3 eV 4 eV Infra redUltraviolet CdSe nano spheres covered with ZnSe act as quantum dots http://www.evidenttech.com/products/core_shell_evidots/overview.php 2 nm: Lake Placid Blue5 nm: Maple-Red Orange conf h  2m L E 2 ~ ~ 2 2 Confinement energy... some of them are easily explained...

11 Excitons Enhanced particle-particle interaction: e-h bound state... some of them are easily explained... 100 meV 2-20 nm 1.5 eV E B = 5 meV

12 Computation of quantum wire excitons

13 Disorder-free structures, exciton parameters Dispersion of multi-subband QWR excitons low-energy states of 10 7 X 10 7 matrix electron-hole correlation decomposition into valence-band orbitals dispersion relation and exciton mass M X spin-splitting, polarization anisotropy A. Siarkos, E. Runge, PRB 61, 16854 (2000)

14 Spatially resolved spectroscopy K. Matsuda et al., PRL 91, 177401 (2003): 30 nm resolution, wavefunction mapping but: Ch. Lienau, E. Runge, Physik Journal, Jan. 2004 and to be published


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