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Atomic Structure. Electromagnetic Radiation Energy traveling through space c = λ* ν Wavelength – (λ) distance between 2 peaks or troughs on a wave – Units:

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Presentation on theme: "Atomic Structure. Electromagnetic Radiation Energy traveling through space c = λ* ν Wavelength – (λ) distance between 2 peaks or troughs on a wave – Units:"— Presentation transcript:

1 Atomic Structure

2 Electromagnetic Radiation Energy traveling through space c = λ* ν Wavelength – (λ) distance between 2 peaks or troughs on a wave – Units: m, cm, nm Frequency – (ν) # waves that pass a point in time – Units: Hertz (Hz) or /s Speed of light – (c) = 3.0*10 8 m/s

3 Energy of photons

4 Spectrums See light patterns Electromagnetic Spectrum – shows all types of electromagnetic radiation Diffraction – light is separated (see colors of rainbow from white light) – See dark and light spots Continuous spectrum – see ranges or bands of color Line spectrum – see only specific wavelengths (looks like lines of color) – Changes in energy emit certain colors

5 Bohr Model of Atom Primarily dealt with Hydrogen atom Also called Planetary Model electrons orbit the nucleus like the planets orbit the sun Electrons reside in specific energy levels – Lowest possible state = ground state (level 1) – Higher states = excited states – Absorb energy to go to excited state; emits light/energy when comes back down

6 Quantum Mechanical Model of Atom Quantum Mechanics – deBroglie, Schrodinger, Heisenberg Electrons not just particles – also act as waves Find electrons in orbitals – know probable location of electron but not exact at any given time (Heisenberg Uncertainty Principle) Schrodinger assigned quantum numbers to describe properties of electrons – Principal quantum number (n) = main energy level/shell (n=1,2,3,….) – Angular momentum quantum number (l) = shape = block/subshell (s=0; p=1; d=2; f=3) – Magnetic quantum number (m l ) = orientation (-l to +l) – Spin quantum number (m s ) = +1/2 or -1/2

7 Orbital Shapes s orbital = sphere - only 1 orientation (s) have nodes – areas of high probability and 0 probability p orbital = dumbbell shape – 3 possible 2 lobes oriented about x,y,z axes (p x, p y, p z ) d orbital = double dumbbell – 5 possible 4 lobes oriented about x,y,z axes (d xy, d yz, d xz, d x2y2, d z2 ) f orbital = 3 dumbells – 7 possible 6 lobes oriented about x,y,z axes (f xyz, etc)

8 Pauli Exclusion Principle = no 2 electrons can have the same set of quantum numbers Example: Sulfur Identify Group, Period, block, total # e- Write orbital notation/orbital diagrams to see specific quantum numbers for atoms/electrons lines/boxes with arrows (2 opposite arrows on each line) (Aufbau Principle = building up)

9 Electron configuration – Show all electrons in the atom Noble Gas notation – Short hand – bracket off number electrons equal to previous Noble gas Remember d orbitals – 1 less than the period they are in (3d in period 4); and f orbitals – 2 less than the period they are in (4f in period 6)

10 Periodic Table Arranged according to increasing atomic number Grouped according to similar properties or characteristics Periodic Trends: – Ionization energy – Electron affinity – Atomic radius – Metallic character


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