1. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 1 INGAS 24 months meeting Brussels - Belgium 27 - 28 October 2010 InGas 24 months meeting: SPA1/Ecocat

2. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 2 WPA1.4 (after treatment system development) –Planned objectives & starting point The activity will lead to the definition of a dedicated solution for the aftertreatment system, taking into account fuel characteristics and engine specificities (lay out and operating modes). This will be supported in a first step both by the catalyst modelling and by laboratory tests, which will be followed by screening activities at the engine test bed. Starting from the engine characteristics and emission targets, new catalyst formulations will be evaluated at laboratory scale and proposed within different lay out solutions. Progress of work 12-24 months –Sample preparation for engine tests at IFP –Ageing of the samples –Further lab. and own engine tests for washcoat development InGas 24 months meeting: SPA1/Ecocat

3. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 3 Sample preparation –According to the task A1.4.3 (catalyst samples manufacturing) the first full size samples have been prepared for the further evaluation in IFP and CRF. –Metallic substrate: Ø = 125 mm, L = 120 mm V = 1,473 dm 3 500 cpsi –Washcoat matrix with stoichiometric CNG coating : 120 g/cft 0:11:19255 proto n:o 23208 120 g/cft 0:23:19256 proto n:o 23207 200 g/cft 0:19:19257 proto n:o 23209 200 g/cft 0:39:19258 proto n:o 23210 250 g/cft Pd-only9259 proto n:o 23211 InGas 24 months meeting: SPA1/Ecocat

4. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 4 InGas 24 months meeting: SPA1/Ecocat Catalyst layout

5. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 5 Sample preparation: fresh samples InGas 24 months meeting: SPA1/Ecocat

6. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 6 Gasoline groove height 20% of the channel height Diesel groove height 50% of the channel height Sample preparation: metallic substrate EcoCat® substrates Features groove system for substrate locking and improved flow dynamics (turbulent areas). 100 % stainless steel (1.4767/1.4725 substrate, FeCrAl). Easy to integrate into the exhaust system. Improved heat and mass transfer rate, low thermal inertia. High resistance against thermal and mechanical shocks. InGas 24 months meeting: SPA1/Ecocat

7. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 7 Sample preparation: washcoat –Advanced coating High surface area – two layer washcoat Oxygen Storage Rear Earth Stabilizers Active metals – Pt/Pd/Rh InGas 24 months meeting: SPA1/Ecocat

8. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 8 InGas 24 months meeting: SPA1/Ecocat Sample preparation: ageing 40 h

9. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 9 InGas 24 months meeting: SPA1/Ecocat Sample preparation: ageing 40 h

10. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 10 Evaluation of tri-metallic catalyst (Pt-Pd-Rh) against Pd-Rh standard CNG washcoat (λ=1) –200 g/cft: Pd-Rh 39:1 vs. Pt-Pd-Rh 1:38:1 (based on the 2 nd quarter 2010 PGM prices latter being about 5 % more expensive) –Laboratory light off tests as fresh and LS-1030°C/20h aged (LS= lean 10 min + stoichiometric 50 min); test mixture in light off (25-600°C): O 2 0,8 %, NO 600 ppm, H 2 O 10 %, CO 2 9 %, CO 8000 ppm, H 2 3800, CH 4 1800 ppm, C 2 H 6 100 ppm, N 2 bal –Engine tests in 1,2 litre bi-power E4 vehicle over the NEDC as fresh and 40 h RAH aged (catalyst size: 100x150 mm, 500 cpsi, 1.18 litre) InGas 24 months meeting: SPA1/Ecocat

11. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 11 Light off tests in laboratory InGas 24 months meeting: SPA1/Ecocat → Minor improvements found in lab. tests

12. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 12 Engine test results for fresh and aged Pd-Rh vs. Pt-Pd-Rh samples –1,2 liter E4 bi-power vehicle with CNG over NEDC (ageing 40/80 h) InGas 24 months meeting: SPA1/Ecocat → Tri-metallic catalyst showed better durability against thermal ageing

13. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 13 Cumulative THC results in the engine after 40 h ageing InGas 24 months meeting: SPA1/Ecocat → Better light off behavior was found after the 3 rd urban cycle for tri-metallic

14. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 14 Conclusion –Five proto samples were prepared for the engine bench evaluation at IFP in Fiat engine –Tri metallic catalyst was evaluated against standard Pd-Rh CNG catalyst: In the laboratory tests minor improvements were found in the light off (T 50 ) temperatures In engine tests fresh samples are performing equally but tri metallic sample showed better durability against thermal ageing –DA1.19 Catalyst samples availability (Task A1.4.3 Catalyst samples manufacturing) Deliverable report was prepared and delivered on 15 th August 2010 InGas 24 months meeting: SPA1/Ecocat

15. INGAS “24 Months Meeting ”, “Brussels, Belgium”, “27-28 October 2010” INGAS INtegrated GAS Powertrain 15 WPA1.5 (global assessment on the validator vehicle) –Samples for the validator vehicle tests will be designed and prepared based on the first results in engine bench tests at IFP InGas 24 months meeting: SPA1/Ecocat