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Detonation Parameters as Inferred from Shock Adiabats of Reaction Products V.S. Trofimov, V.A. Veretennikov Institute of Structural Macrokinetics and Materials.

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Presentation on theme: "Detonation Parameters as Inferred from Shock Adiabats of Reaction Products V.S. Trofimov, V.A. Veretennikov Institute of Structural Macrokinetics and Materials."— Presentation transcript:

1 Detonation Parameters as Inferred from Shock Adiabats of Reaction Products V.S. Trofimov, V.A. Veretennikov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences Chernogolovka, Moscow, 142432 Russia e-mail: veret@ism.ac.ru XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland

2 A B P V This is the well known representation of a detonation wave in terms of the fluid- dynamic theory developed by Zel’dovich XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland

3 E(P,V) specific internal energy E s (V), P s (V ) specific internal energy and pressure on the shock adiabat of products, respectively Grüneisen coefficient XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland

4 V 00 specific volume of HE in its initial state V 0 specific volume of detonation products in their condensed state at normal conditions Q P reaction heat at P = P 0 = const.  i mass fraction of the i -th product V i (P) specific volume on the shock adiabat of the i -th product XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland

5 1. Anisichkin V.F., Generalized shock adiabats and zeroth isotherms of the elements, Fiz. Goreniya Vzryva, 1979, vol. 15, no. 2, pp. 152-157. 2. Trofimov V.S., Trofimov O.V., Caloric equation of state for condensed matter as inferred from generalized shock adiabats, Khim. Fiz., 2009, vol. 28, no. 2, pp. 56-64.  0 = 1/V 0 initial density a initial volumetric speed of sound [1] and [2] XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland

6 HE  00, kg/m 3  00 /  0 D, m/s (meas) D, m/s (cltd) P, GPa (meas) P, GPa (cltd) Amatol 50/50,  0 = 1111 kg/m 3 16501.077987779–24.8 14850.971137152–19.1 13200.864286583–15.3 11550.757436151–13.1 9900.650595926–12.0 RDX,  0 = 1063 kg/m 3 17201.08460793330.927.6 15480.97933730624.120.7 13760.87304667918.215.8 12040.76629614214.412.8 10320.66008578910.911.2 8600.5538657117.810.6 TNT,  0 = 1295 kg/m 3 16201.06980684118.318.7 14580.96523634314.415.6 12960.85987597111.213.6 11340.7544757648.712.6 9720.6490857716.212.3 XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland

7 Спасибо за внимание! Thank you for your attention! Dziękuję za uwagę! XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland

8 XII International Symposium on Explosive Production of New Materials: Science, Technology, Business, and Innovations (EPNM-2014) May 25-30, 2014 Cracow, Poland


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