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Atomic & Nuclear Chemistry

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Monday 10/29/12 Prep: 1.Find geiger counter & samples Class: 1.Coop Quiz – A Mole Conversion & An Avg Atomic Mass Problem 2.Isotopes (Quick Review) Radiation Demos 3.Alpha, Beta, Gamma Radiation 4.Fission vs Fusion 5.Nuclear Equations – Alpha, Beta Asmt: Write Nuclear Equations for the Uranium Decay Series

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Vocabulary 2B (Define in your notebook) Isotopenuclear reactor Radioisotopenuclear weapon Radioactivityhalf life Radiationnuclear equation Fissionpositron Fusionradiocarbon dating Radioactive decaycritical mass Alpha particlenuclear bombardment Beta particlecurie Gamma rayrem Nuclear chain reactionplasma Dosimetertransmutation

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Isotopes Atoms of a single element have the same number of protons but may differ in neutrons. Example 1: Carbon-12 vs Carbon-14 Example 2: Uranium-238 vs Uranium-235 Some isotopes are stable while others are unstable and radioactive. The STRONG NUCLEAR FORCE acts between protons & neutrons to hold them together. However protons will repel each other with their mutual positive charge.

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Carbon Isotopes IsotopeHalf – life Carbon – s Carbon – s Carbon – min Carbon – 12Stable Carbon – 13Stable Carbon – y Carbon – s Carbon – s How long does it take 400 g of each isotope to decay to less than 1 mg?

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Geiger Counter Demos SampleCounts per Minute Reason Humans NaCl vs KCl Smoke Detector Old Fashioned Lantern Mantle Old Glow in the Dark Clock Uranium Ore

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Becquerel/Curries Becquerel – First observed photographic evidence of radioactivity Curie – Discovered radioactive elements of radium and polonium Curie – made gift of 1 gram of Radium to President Truman to help fight cancer.

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Rutherfords Discovery of Alpha, Beta & Gamma Radiation

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Rutherford & Radiation Discovered alpha, beta & gamma radiation using a magnetic field.

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Radioactivity Blocked by 1ft of concrete or few inches of lead Sheet metal Blocked by paper Penetration High energy photon 1 electron2 protons, 2 neutrons Composition 0 (movie)(movie)+2Charge 0 amu1/1837 amu 4 amuMass Symbol GammaBetaAlphaTypes of Radiation

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Radioactivity Alpha – large Relatively slow Beta – much smaller Relative fast Gamma – no mass Pure energy Travels at the Speed of light

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Alpha Radiation The unstable nucleus simultaneously ejects two neutrons and two protons, which correspond to a helium nucleus. The emission of gamma photons is a secondary reaction that occurs a few thousandths of a second after the disintegration.

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Alpha Emission 263 Sg He Rf 104

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Beta Emission The unstable nucleus ejects an electron. The emission of gamma photons is a secondary reaction that occurs a few thousandths of a second after the disintegration

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Beta Emission 14 C 6 0 e + 14 N 7 + A neutron disintegrates, ejects an electron and another proton is left over. A gamma ray is also released.

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Gamma Radiation involves high energy waves that dont change the identity of the nucleus

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Nuclear Reactions Radioactivity results from changes in atomic nuclei. Fission – splitting of a large nucleus into smaller pieces releases energy. Fusion – small nuclei join to make a larger nucleus and release energy. Energy is released when a small amount of mass converts to energy as E = mc 2. The atomic masses of isotopes deviate from whole numbers due to loss of mass from energy released as they fused.

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Fusion of Hydrogen Isotopes At high temperatures and pressures, 2 nuclei may collide and form a bigger nucleus. This example produces helium and a stray neutron. Stars are fueled by the energy released by fusion which also builds atoms of increasing sizes in their cores.

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Fission of Uranium A neutron splits the nucleus. The fragments include: –2 different smaller atoms, –3 more neutrons. The 3 neutrons can split more atoms. If every fission splits 3 more atoms, the reaction will multiply out of control!

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Nuclear Chain Reaction

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Nuclear Equations Styrofoam Demos Alpha Decay – releases a helium nucleus. Beta Decay – a neutron converts to a proton and releases an electron. Assignment: Uranium Decay Series

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Nuclear Warheads

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Chernobyl Nuclear Disaster

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Nuclear Equations Alpha ( ) Decay – releases 2 protons & 2 neutrons - a helium nucleus. Beta ( ) Decay – a neutron converts to a proton and releases an electron. 4 He 2 0 e

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Uranium Decay Series

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U238 alpha - HL 4.468e9y Th234 beta – HL 24.10d Pa234 beta – HL 6.70h U234 alpha – HL 245,500y Th230 alpha – HL 75,380y Ra226 alpha – HL1600y Rn222 alpha – HL d Po218 alpha – HL 3.10m Pb214 beta – HL 26.8m Bi214 beta – HL 19.9m Po214 alpha – HL s Pb210 beta – HL 22.6y Bi210 beta – HL 138d Po210 alpha – HL 4.199m Pb206 Stable!

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Nuclear Equations Uranium 238 does alpha decay: –Mass numbers balance on both sides. –Atomic numbers balance on both sides Thorium 234 then does beta decay: 4 He U Th Th 90 0 e 234 Pa 91 +

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Nuclear Equations Problems 1.U–238 does alpha decay in nuclear reactors. 2.Am-241 does alpha decay in smoke alarms. 3.Tc-98 does beta decay in medical exams. 4.C–14 does beta decay in carbon dating. 5.The Curies used Ra-226 which does alpha decay. 6.Co–60 does beta decay in food irradiation. 7.Th-232 does alpha decay in camp lanterns. 8.P-35 does beta decay in DNA studies (Place isotopes activity in Outbox)

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Nuclear Equations Quiz 1.Write the nuclear equation for the alpha decay of Iodine Write the nuclear equation for the beta decay of cobalt 60.

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½ Lives Activity Obtain a set of radioactive blocks. Notice that each one has a mark on one side – either a, b or g. Roll the collection of blocks onto your table. Each time you roll, remove any blocks that come up, or. Count and record the remaining blocks. Roll the remaining blocks repeatedly 20 times and complete the chart below. Enter your group data into the excel file.excel file Make graphs of Time(minutes) Remaining Atoms for both individual & class averages. **Use exponential rather than linear trendlines. Roll (minutes) Remaining Atoms Class Average

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½ Lives Activity Questions 1.How do your lab pair results compare with the class average results? 2.Use the class average results and compute the 1 st ½ life, 2 nd ½ life, average ½ life. 3.What importance do ½ lives have to society? (dating, medical uses, wastes)

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½ Lives Each radio-isotope decays at a characteristic rate. The decay rate is determined by the time that it takes for ½ of the radio-isotope nuclei to break down by fission. Each ½ life reduces the remaining number of radioactive atoms by ½. The number remaining approaches but never reaches zero. Example: Iodine 131 has a ½ life of 8 days. How much of 1.00 gram sample would remain after 24 days?

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½ Lives of Isotopes IsotopeHalf – lifeRadiation emitted Carbon – yBeta Potassium – 401.3e9 yBeta, gamma Radon – dAlpha, gamma Radium – yAlpha, gamma Iodine – dBeta, gamma Thorium – dBeta, gamma Uranium – e8 yAlpha, gamma Uranium – e9 yAlpha, gamma

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Solving ½ Life Problems Masses: STARTING MASS Divided in ½ the # of half lives. ending mass Times: Time for 1 half life (HL) Total time elapsed (T) T = HL*(#) HL = T/# # = T/HL # of half lives

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½ Life Example 1 – Iodine 131 has a ½ life of 8 days. How much of 1.00 gram sample would remain after 24 days? Times: ½ life = 8 days Total = 24 days 24days / 8days = 3 half lives Masses: Start = 1.00 g End = ?unknown If 3 half lives occur, divide start by 2 3-times 1.00 g / 2 / 2 / 2 =.125 g

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½ Life Example 2: A 8.8mg sample of chromium-55 is analyzed after 15 min and found to contain 1.1mg remaining. What is the ½ life of Cr55? Masses: Start = 8.8 mg End = 1.1mg Divide 4.4 by 2 until reaching /2 = /2 = /2 = – ½ lives occurred Times: Total = 15 min ½ life = ? Unknown Divide 15 min by 3 – ½ lives 15min/3 HL = 5 min/1HL 5 min = 1 – ½ life

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½ Life Problems 1.If you have $1 million dollars and every 2 seconds it decreases by 1/2, how long will it take until you are penniless? 2.If a sample of a fossil mammoth has 1/8 th the amount of carbon 14 as it would today, how old must the fossil be? (1/2L C14 = 5715 years. 3.If a rock contained 1.2 g of potassium 40 when it formed, how many grams remain after 4 billion years. (1/2L K40 = 1.3e9 y) Asmt: P780 #1&2, P803 #24&25

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More ½ Life Problems 4. If a sample of radioactive isotope has a half-life of 1 year, how much of the original sample will be left at the end of the second year? The third year? The fourth year? 5. The isotope cesium-137, which has a half-life of 30 years, is a product of nuclear power plants. How long will it take for this isotope to decay to about one-sixteenth its original amount? 6.Iodine-131 has a half-life of 8 days. What fraction of the original sample would remain at the end of 32 days? 7.The half-life of chromium-51 is 28 days. If the sample contained 510 grams, how much chromium would remain after 56 days? How much would remain after 1 year?

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½ Lives Quiz 1. A sample of a radioactive isotope with an original mass of 8.00g is observed for 30 days. After that time, 0.25g of the isotope remains. What is its half-life? 2. The starting mass of a radioactive isotope is 20.0g. The half-life period of this isotope is 2 days. The sample is observed for 14 days. What PERCENTAGE of the original amount remains after 14 days?

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Health Physics Society Q:What are some health effects of the element uranium? A:The toxicity of uranium has been under study for over 50 years, including life-span studies in small animals. Depleted uranium and natural uranium both consist primarily of the uranium isotope 238U. They are only very weakly radioactive and are not hazardous radioactive toxicants, but uranium is a weak chemical poison that can seriously damage the kidneys at high blood concentrations. Virtually all of the observed or expected effects are from nephrotoxicity associated with deposition in the kidney tubules and glomeruli damage at high blood concentrations of uranium. The ionizing radiation doses from depleted and natural uranium are very small compared to potential toxic effects from uranium ions in the body (primarily damage to kidney tubules).

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