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**pv v r w A pv+v r w B Figure S4**

S4A-sugars, O2PLS-DA scatter loading plot; 4 classes- Model: 3+0; P=0,003 pv+v r w B S4B, flavanones, O2PLS-DA scatter loading plot; 3 classes- Model: 2+0; P= 0,0001

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**pv v+r+w C D pv+v r+w pv+v r+w E**

S4C, aromatic organic acids, O2PLS-DA histogram loading plot; 2 classes- Model: 1+0, P=4.2x10-7 D pv+v r+w S4D, flavones, O2PLS-DA histogram loading plot; 2 classes-Model: 1+3, P=7,2x10-5 pv+v r+w E S4E, non acylated anthocyanins, O2PLS-DA histogram loading plot; 2 classes-Model: 1+0, P=2,8x10-7

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pv+v r+w F S4F, flavan-3-ols and procyanidins, O2PLS-DA histogram loading plot; 2 classes-Model: 1+1, P=0,016 S4G, stilbenes and viniferins, O2PLS-DA histogram loading plot; 2 classes- Model: 1+1, P= 0,008 pv+v+r w G

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