1. Geology, Mining, and Water Quality by Matthew A. Sares

4. Acid Mine Drainage Water Water - from rain and snowmelt+ Oxygen Oxygen - from the air+ Pyrite Pyrite - from the mine Reaction = Sulfuric Acid

5. Sources of Acid Mine Drainage (AMD) Mine Effluent Burbank Mine, San Juan Co.

6. Lewis Mine and Mill, San Miguel Co. Mill Tailings Mine Dump Mine Dump

7. THE CHEMISTRY of ACID MINE DRAINAGE Reaction 1: FeS 2(s) + H 2 O + 7/2O 2 2H + Fe 2+ + 2SO 4 + 2H + H + Reaction 2:* Fe 2+ + 1/4O 2 + H + Fe 3+ + 1/2H 2 O Reaction 3: FeS 2(s) + 8H 2 O + 14Fe 3+ 16H + 15Fe 2+ + 2SO 4 + 16H + Reaction 4: Fe 3+ + 3H 2 O 3H + Fe(OH) 3(s) + 3H + pyrite water sulfate acid * catalyzed by bacteria

8. Lewis Mine and Mill, San Miguel Co. Background Water Quality

9. THE CHEMISTRY of ACID MINE ROCK DRAINAGE Reaction 1: FeS 2(s) + H 2 O + 7/2O 2 2H + Fe 2+ + 2SO 4 + 2H + H + Reaction 2:* Fe 2+ + 1/4O 2 + H + Fe 3+ + 1/2H 2 O Reaction 3: FeS 2(s) + 8H 2 O + 14Fe 3+ 16H + 15Fe 2+ + 2SO 4 + 16H + Reaction 4: Fe 3+ + 3H 2 O 3H + Fe(OH) 3(s) + 3H + pyrite water sulfate acid * catalyzed by bacteria

10. Acid Rock Drainage (ARD) sources: Natural springs and drainages in Abandoned mines hydrothermally altered areas

11. Hydrothermal alteration is a process whereby hot water circulating within the earth changes the composition of rocks. Intensely altered rocks have yellow, orange, and red colors from the oxidation of iron in pyrite. East Mancos River headwaters, Montezuma Co.

12. (mod. from Guilbert and Park, 1986) Hydrothermal Alteration Feldspars >> Clays Iron and Sulfur >> Pyrite

13. naturally upstreamof any significant human impacts. A number of streams in eleven different headwater areas of Colorado have naturally high concentrations of metals and/or acidity, upstream of any significant human impacts. Rocks in these areas have been affected by intense “hydrothermal alteration” in the geologic past.

14. Red Cone, Park Co.

15. Red Mountain, Chaffee and Pitkin Co. Springs

16. Natural acid rock drainage dissolves metals present in the rock, affecting downstream water quality. 110100100010000 Above Factor Above Aquatic Life Standard Constituent PEEKABOO GULCH SPRING pH=2.17, conductance=2470 µS, Q=25 gpm 1,724 x 42 x 164 x 100 x 6 x 21 x 6 x Al Cd Cu Fe Mn Pb Ag Zn SO4

18. Lookout Mountain, Conejos Co.

19. Iron Creek Lower Spring, Conejos Co. Ferrosinter deposits are characteristic of springs in hydrothermally altered areas.

20. Some hydrothermally altered areas have high rates of erosion, and are prone to debris flows and landslides because bedrock has been weakened. Slide Headwall Red Mountain #2, Ouray Co. Alum Creek, Conejos Co.

21. Slumgullion landslide is in an area of hydrothermally altered rock. Movement and erosion continually expose acid-producing minerals. Drainage from the slide area is very acidic (pH  3.4). Slumgullion Landslide near Lake City, Mineral Co. Headwall

22. Conclusions AMD degradation can be acute because: 1) Mines act as collectors of groundwater 2) Water is in contact with high grade ore minerals 3) Mine dumps and tailings provide dramatically increased surface areas for the interaction of water, oxygen, and sulfide minerals. Acid rock drainage is generated at mines and naturally where sulfide minerals are present and the buffering capacity of the water is exceeded.

23. Both ARD sources must be characterized to determine realistic remediation goals. Conclusions Natural ARD is important in areas of intense hydrothermal alteration because: 1) Rocks contain disseminated sulfide minerals. 2) Rocks are depleted of buffering minerals. 3) Large volumes of rock are affected.