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Lecture 122/13/06 Seminar cancelled. Bronsted-Lowry Acids Proton donor (H + or H 3 O + ) Acidic vs. non-acidic protons Bronsted-Lowry Bases Proton acceptor.

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Presentation on theme: "Lecture 122/13/06 Seminar cancelled. Bronsted-Lowry Acids Proton donor (H + or H 3 O + ) Acidic vs. non-acidic protons Bronsted-Lowry Bases Proton acceptor."— Presentation transcript:

1 Lecture 122/13/06 Seminar cancelled

2 Bronsted-Lowry Acids Proton donor (H + or H 3 O + ) Acidic vs. non-acidic protons Bronsted-Lowry Bases Proton acceptor

3 Acids Strong HCl HBr HI HClO 3 HClO 4 HNO 3 H 2 SO 4 Weak All other acids R-COOH HCl → H + + Cl - Concentration of H + if you add 0.5 M HCl? HF ⇄ H + + F - Concentration of H + if you add 0.5 M HF?

4 Bases Strong LiOH NaOH KOH RbOH CsOH Ba(OH) 2 Sr(OH) 2 O 2- H - N 3- Weak Conjugate bases NH 3 R-NH 2

5 Oxide (O 2- : CaO, Na 2 O) O 2- (aq) + H 2 O → 2 OH - (aq) Hydride (H - : NaH) H - (aq) + H 2 O → H 2 (aq) + OH - (aq) Nitride (N 3- : Na 3 Na) N 3- (aq) + 3H 2 O → NH 3 (aq) + 3OH - (aq)

6 Amphoteric (Amphiprotic)

7 pH What is it? How do you measure it?

8 pH of some common substances pH Bleach12.5 Baking soda8.4 Egg White7.7 Milk6.8 Unpolluted rain5.6 Coffee4.9 Coke2.9 Stomach acid1.2

9 Autoionization of Water What is it? What is the definition of: Neutral solutions? Acidic solutions? Basic solutions?

10 T (°C)KwKw 100.29 x 10 -14 150.45 x 10 -14 200.68 x 10 -14 251.01 x 10 -14 301.47 x 10 -14 505.48 x 10 -14

11 pH vs. pOH

12 Degree of ionization


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