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CH3Br, 101209 agust,heima,....Dec09/CH3BR-Overall (C)-081209km agust,www,...Dec09/PPT-101209ak.ppt agust,heima,...Dec09/XLS-101209ak.xls.

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Presentation on theme: "CH3Br, 101209 agust,heima,....Dec09/CH3BR-Overall (C)-081209km agust,www,...Dec09/PPT-101209ak.ppt agust,heima,...Dec09/XLS-101209ak.xls."— Presentation transcript:

1 CH3Br, 101209 agust,heima,....Dec09/CH3BR-Overall (C)-081209km agust,www,...Dec09/PPT-101209ak.ppt agust,heima,...Dec09/XLS-101209ak.xls

2 New 3 peaks new artifact ATH?

3 71343.2474 71349.2 71353.3

4 Configuration Term J Level (cm -1 ) 2s22p2 2s22p2 3 P 0 0 1 16.40 2 43.40 2s22p2 2s22p2 1 D 2 10 192.63 2s22p2 2s22p2 1 S 0 21 648.01 2s2p3 2s2p3 5 S° 2 33 735.20 2s 2 2p( 2 P°)3s 3 P° 0 60 333.43 1 60 352.63 2 60 393.14 2s 2 2p( 2 P°)3s 1 P° 1 61 981.82 2s2p3 2s2p3 3 D° 3 64 086.92 1 64 089.85 2 64 090.95 2s 2 2p( 2 P°)3p 1 P 1 68 856.33 2s 2 2p( 2 P°)3p 3 D 1 69 689.48 2 69 710.66 3 69 744.03 2s 2 2p( 2 P°)3p 3 S 1 70 743.95 2s 2 2p( 2 P°)3p 3 P 0 71 352.51 1 71 364.90 2 71 385.38 2s 2 2p( 2 P°)3p 1 D 2 72 610.72 2s 2 2p( 2 P°)3p 1 S 0 73 975.91 J GS0 0 3P116.4 243.4 2s22p(2Po)3p071352.5171336.1171309.11 3P171364.971348.571321.5 271385.3871368.9871341.98 agust,heima,...Dec09/XLS-101209ak.xls: http://physics.nist.gov/cgi-bin/ASD/energy1.plhttp://physics.nist.gov/cgi-bin/ASD/energy1.pl :

5 Check 69704.95668/ 69705.0 To be copaierd with lines in PPT-240809ak.ppt:

6 Configurati on Term J Level (cm -1 ) 2s22p2 2s22p2 3 P 0 0 1 16.40 2 43.40 2s22p2 2s22p2 1 D 2 10 192.63 2s22p2 2s22p2 1 S 0 21 648.01 2s2p3 2s2p3 5 S° 2 33 735.20 2s 2 2p( 2 P°)3 s 3 P° 0 60 333.43 1 60 352.63 2 60 393.14 2s 2 2p( 2 P°)3 s 1 P° 1 61 981.82 2s2p3 2s2p3 3 D° 3 64 086.92 1 64 089.85 2 64 090.95 2s 2 2p( 2 P°)3 p 1 P 1 68 856.33 2s 2 2p( 2 P°)3 p 3 D 1 69 689.48 2 69 710.66 3 69 744.03 2s 2 2p( 2 P°)3 p 3 S 1 70 743.95 2s 2 2p( 2 P°)3 p 3 P 0 71 352.51 1 71 364.90 2 71 385.38 C I69647.2 69668.9 69675.3 69697.7 69705.0 69715.4 69733.1 1D REMPI for C + Measurements seem to have got lost http://physics.nist.gov/cgi-bin/ASD/energy1.pl Exp. Values:

7 71343.2474~71341.98 J’’=2 ->-> J´=2 71349.2 ~71348.5; J’’= 1 ->-> J´= 1 71353.3 ~ 71352.51; J’’=0 ->-> J´=0 Ergo: The lines are: 2s22p2 (3P) ->-> 2s22p(2P°)3p(3P),  J =0:

8 77411.21 Does not seem to be C atomic line. (see: agust,heima,...Dec09/XLS-101209ak.xls ) Could this be Br atomic line?

9


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