1. 1 Sodium Doped Lanthanum Manganites Thin Films: Synthesis, Substrate Effect and Thickness Dependence Paolo Ghigna Dipartimento di Chimica Fisica “M. Rolla”, Università di Pavia, V.le Taramelli 16, I-27100, Pavia, Italy

2. 1 Introduction One of the most exciting feature of manganites thin films is the close correlations between the electronic transport and the strain effect induced by the substrate used for thin films growth. In fact the physical properties of the films (T I-M, T C, MR) can be nicely tuned by controlling the film thickness and the substrate nature, i.e., the two most important variable in affecting the film strain and growth direction. Recently we focused on the sodium doped lanthanum manganites in order to deeply investigate this system which looks suitable for achieving better electronic and magnetic properties. This is mainly due to the fact that the tolerance factor (t) is practically unchanged by the sodium replacement of lanthanum; moreover, compared to the Ca-doped manganites, it is possible to achieve an equal amount of hole doping with a lower cation substitution since for the same amount of aliovalent dopant the hole density is twice with respect to the calcium doping. This should reflect in a lower cation disorder induced by the doping. Finally, for an optimal doping, these materials present a rhombohedral structure.

3. 1 Experimental La 0.88 Na 0.12 MnO 3+  thin films were deposited on SrTiO 3 (100), NdGaO 3 (100) and NdGaO 3 (110) single crystals. The depositions were performed by an off-axis Rf- magnetron sputtering system. X-ray reflectivity (XRR), as well as  - 2  X-ray diffraction (XRD) data were collected by using a Bruker “D8 Advance” diffractometer. Resistance measurements were carried out in a Quantum Design Magnetic Property Measurement System (MPMS) in a four points configuration. NC-AFM images were obtained with an Autoprobe CP microscope (Park Instruments- VEECO), operating in non-contact mode.

4. 1 Crystal Structure La 0.88 Na 0.12 MnO 3+  (LNMO) starting powders present a rhombohedral structure; cell parameters: a=5.494 Ǻ, c=13.302 Ǻ, V=57.96 Ǻ 3.

5. 1 Film growth and microstructure

6. 1 X-ray diffraction and reflectivity --154.2-3.88482 --188- 3.87933 --221.1-3.87711NGO (100) 240911142563.89282 2717071.62853.89833 --155-3.88911NGO (110) 259; 178 45; 37129260, 182 3.87670 25278.295.7603.87825 24077.994.22483.85113 STO (100) MR peak 5 T (K) MR (%) 5 T E a (meV) T I-M (K) Out-of- plane parameter (Å) Thick- ness (nm) Substrate

7. 1 Substrate induced strain The strain is defined as ((a substrate -a target )/a substrate )  100 For the STO (100) substrate is about +0.50% (tensile strain). For the NGO (110) substrate is about -0.54% (compressive strain) Finally, for the films grown on the NGO (100), the epitaxial growth should place the b-c lattice planes of the orthorhombic Pbnm structure in the plane of the substrate while the out-of-plane lattice constant will be one of the two short axes of the orthorhombic cell (a, in this case)

8. 1 Magnetoresistance: STO (100) deposited films

9. 1 Magnetoresistance: NGO (110) deposited films

10. 1 Magnetoresistance: NGO (100) deposited films

11. 1 Conclusions The first synthesis by means of Rf-sputtering of optimally doped La 1-x Na x MnO 3 thin films has been performed, With three different substrates, and for each of them, three different thicknesses. The synthetic procedure here applied showed to be suitable to produce well oriented epitaxial thin films. The structural data showed that film grown onto STO (100) are under tensile strain while the one growth on NGO (110) are under a compressive strain of the same magnitude. Films grown onto the NGO (110) substrate do not show magnetoresistance.