1. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Chemistry FIFTH EDITION by Steven S. Zumdahl University of Illinois

2. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 2 Chemistry FIFTH EDITION Chapter 20 Transition Metals and Coordination Chemistry

3. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 3 Figure 20.1 The Position of the Transition Elements on the Periodic Table

4. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 4 Figure 20.2 Plots of the First (Red Dots) and Third (Blue Dots) Ionization Energies for the First-Row Transition Metals

5. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 5 Figure 20.3 Atomic Radii of the 3d, 4d, and 5d Transition Series

6. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 6 Figure 20.4 The Structures of the Chromium (VI) Anions

7. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 7 Figure 20.5 The Ligand Arrangements for Coordination Numbers 2, 4, and 6

8. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 8 Figure 20.8 Some Classes of Isomers

9. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 9 Figure 20.9 NO 2 -

10. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 10 Figure 20.10 Alloys Containing Copper

11. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 11 Figure 20.11 Typical Compounds of Copper

12. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 12 Figure 20.12 Unpolarized Light Consists of Waves Vibrating in Many Different Planes

13. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 13 Figure 20.13 The Rotation of the Plane of Polarized Light by an Optically Active Substance

14. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 14 Figure 20.15 A Human Hand Exhibits a Nonsuperimposable Mirror Image

15. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 15 Figure 20.16 Isomers of I and II of Co(en) 3 3+ are Mirror Images That Cannot Be Superimposed

16. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 16 Figure 20.17 The Optical Isomers of Co(en) 2 CI 2 +

17. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 17 Figure 20.18 Hybrid Orbitals on Co 3+

18. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 18 Figure 20.19 The Hybrid Orbitals Required for Tetrahedral, Square Planar, and Linear Complex Ions

19. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 19 Figure 20.20 An Octahedral Arrangement of Point-Charge Ligands and the Orientation of the 3d Orbitals

20. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 20 Figure 20.21 The Energies of the 3d Orbitals for a Metal Ion in an Octahedral Complex

21. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 21 Figure 20.23 The Visible Spectrum

22. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 22 Figure 20.24 Violet Light

23. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 23 Figure 20.26 The d Orbitals in a Tetrahedral Arrangement of Point Charges

24. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 24 Figure 20.27 The Crystal Field Diagrams for Octahedral and Tetrahedral Complexes

25. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 25 Figure 20.28 The d Energy Diagrams for Square, Planar, and Linear Complexes

26. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 26 Figure 20.29 The Heme Complex

27. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 27 Figure 20.30 Chlorophyll

28. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 28 Figure 20.31 Myoglobin

29. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 29 Figure 20.32 Hemoglobin

30. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 30 Figure 20.34 A Schematic Diagram of a Cyclone Separator

31. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 31 Figure 20.35 A Schematic Representation of Zone Refining

32. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 32 Figure 20.36 The Blast Furnace Used in the Production of Iron

33. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 33 Figure 20.37 A Schematic Diagram of the Open Hearth Process for Steel Making

34. Copyright©2000 by Houghton Mifflin Company. All rights reserved. 34 Figure 20.38 The Basic Oxygen Process for Steelmaking