1. P461 - Semiconductors1 Superconductivity Resistance goes to 0 below a critical temperature T c element T c resistivity (T=300) Ag ---.16 mOhms/m Cu --.17 mOhms/m Ga 1.1 K 1.7 mO/m Al 1.2.28 Sn 3.7 1.2 Pb 7.2 2.2 Nb 9.2 1.3 many compounds (Nb-Ti, Cu-O-Y mixtures) have T c up to 90 K. Some are ceramics at room temp Res. T

2. P461 - Semiconductors2 Superconductors observations Most superconductors are poor conductors at normal temperature. Many good conductors are never superconductors  superconductivity due to interactions with the lattice practical applications (making a magnet), often interleave S.C. with normal conductor like Cu if S.C. (suddenly) becomes non-superconducting (quenches), normal conductor able to carry current without melting or blowing up quenches occur at/near maximum B or E field and at maximum current for a given material. Magnets can be “trained” to obtain higher values

3. P461 - Semiconductors3 Superconductors observations For different isotopes, the critical temperature depends on mass. ISOTOPE EFFECT again shows superconductivity due to interactions with the lattice. If M  infinity, no vibrations, and T c  0 spike in specific heat at T c indicates phase transition; energy gap between conducting and superconducting phases. And what the energy difference is plasma  gas  liquid  solid  superconductor

4. P461 - Semiconductors4 What causes superconductivity? Bardeen-Cooper-Schrieffer (BCS) model paired electrons (cooper pairs) coupled via interactions with the lattice gives net attractive potential between two electrons if electrons interact with each other can move from the top of the Fermi sea (where there aren’t interactions between electrons) to a slightly lower energy level Cooper pairs are very far apart (~5,000 atoms) but can move coherently through lattice if electric field  resistivity = 0 (unless kT noise overwhelms  breaks lattice coupling) electron atoms

5. P461 - Semiconductors5 Conditions for superconductivity Temperature low enough so the number of random thermal phonons is small interactions between electrons and phonons large (  large resistivity at room T) number of electrons at E = Fermi energy or just below be large. Phonon energy is small (vibrations) and so only electrons near E F participate in making Cooper pairs (all “action” happens at Fermi energy) 2 electrons in Cooper pair have antiparallel spin  space wave function is symmetric and so electrons are a little closer together. Still 10,000 Angstroms apart and only some wavefunctions overlap (low E  large wavelength)

6. P461 - Semiconductors6 Conditions for superconductivity 2 2 electrons in pair have equal but opposite momentum. Maximizes the number of pairs as weak bonds constantly breaking and reforming. All pairs will then be in phase (other momentum are allowed but will be out of phase and also less probability to form) if electric field applied, as wave functions of pairs are in phase - maximizes probability -- allows collective motion unimpeded by lattice (which is much smaller than pair size) different times different pairs

7. P461 - Semiconductors7 Energy levels in S.C. electrons in Cooper pair have energy as part of the Fermi sea (E 1 and E 2 =E F  plus from their binding energy into a Cooper pair (V 12 ) E 1 and E 2 are just above E F (where the action is). If the condition is met then have transition to the lower energy superconducting state can only happen for T less than critical temperature. Lower T gives larger energy gap. At T=0 (from BCS theory) normal s.c. Temperature E gap

8. P461 - Semiconductors8 Magnetic Properties of Materials H = magnetic field strength from macroscopic currents M = field due to charge movement and spin in atoms - microscopic can have residual magnetism: M not equal 0 when H=0 diamagnetic   < 0. Currents are induced which counter applied field. Usually.00001. Superconducting  = -1 (“perfect” diamagnetic)

9. P461 - Semiconductors9 Magnetics - Practical in many applications one is given the magnetic properties of a material (essentially its  ) and go from there to calculate B field for given geometry D0 Iron Toroid beamline sweeping magnet spectrometer air- gap analysis magnet

10. P461 - Semiconductors10 Paramagnetism Atoms can have permanent magnetic moment which tend to line up with external fields if J=0 (Helium, filled shells, molecular solids with covalent S=0 bonds…)   = 0 assume unfilled levels and J>0 n = # unpaired magnetic moments/volume n+ = number parallel to B n- = number antiparallel to B n = n+ + n- moments want to be parallel as

11. P461 - Semiconductors11 Paramagnetism II Use Boltzman distribution to get number parallel and antiparallel where M = net magnetic dipole moment per unit volume can use this to calculate susceptibility(Curie Law)

12. P461 - Semiconductors12 Paramagnetism III if electrons are in a Fermi Gas (like in a metal) then need to use Fermi-Dirac statistics reduces number of electrons which can flip, reduces induced magnetism,  smaller antiparallel parallel EFEF turn on B field. shifts by  B antiparallel states drop to lower energy parallel

13. P461 - Semiconductors13 Certain materials have very large  (1000) and a non-zero B when H=0 (permanent magnet).  will go to 0 at critical temperature of about 1000 K (  non ferromagnetic) 4s2: Fe26 3d6 Co27 3d7 Ni28 3d8 6s2: Gd64 4f8 Dy66 4f10 All have unfilled “inner” (lower n) shells. BUT lots of elements have unfilled shells. Why are a few ferromagnetic? Single atoms. Fe,Co,Ni D subshell L=2. Use Hund’s rules  maximize S (symmetric spin)  spatial is antisymmetric and electrons further apart. So S=2 for the 4 unpaired electrons in Fe Solids. Overlap between electrons  bands but less overlap in “inner” shell overlapping changes spin coupling (same atom or to adjacent atom) and which S has lower energy. Adjacent atoms may prefer having spins parallel. depends on geometry  internuclear separation R Ferromagnetism

14. P461 - Semiconductors14 R small. lots of overlap  broad band, many possible energy states and magnetic effects diluted R large. not much overlap, energy difference small R medium. broadening of energy band similar to magnetic shift  almost all in state Ferromagnetism II P A R E(unmagnetized)- E(magnetized) Mn Fe Co Ni