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© Boardworks Ltd 2001 KS4: Useful Products from Organic Sources ORGANIC CHEMISTRY
© Boardworks Ltd 2001 Crude Oil Crude oil is a mixture; it contains hundreds of different compounds, some small and some extremely large. Nearly all these compounds contain carbon and hydrogen only and are called hydrocarbons. Hydrocarbons are molecules that contain carbon and hydrogen only. The compounds present in crude oil are separated, processed and purified in an oil refinery. These processes are covered in the following slides.
© Boardworks Ltd 2001 Composition of a typical crude oil Crude oils from different parts of the world have different composition
© Boardworks Ltd 2001 It is difficult to obtain pure compounds from crude oil so instead, crude oil is separated into groups of compounds called fractions. Each fraction contains compounds of similar boiling point. A description of each fraction is shown below:
© Boardworks Ltd 2001 Fractional distillation Crude oil is split into fractions using fractional distillation. Here crude oil is heated and pumped into the bottom of a tall tower containing trays. Compounds with low boiling points rise towards the top of the tower where they condense. Compounds with higher boiling point condense lower in the column. Thus each tray contains liquids (fractions) of different boiling point. The liquid on each tray is continuously pumped away. A fractional distillation tower works continuously, unlike distillation in the laboratory.
© Boardworks Ltd 2001 Crude oil preheater Medium ones condense Short ones condense Small ones condense Very small molecules do not condense and come out of the top Very large molecules do not vaporise and fall to the bottom How fractional distillation works 40°C 70°C 180°C 250°C 340°C Long ones condense Liquid out Getting cooler
© Boardworks Ltd 2001 preheater Crude oil Fuel gas Petrol Naphtha Kerosine Diesel fuel Fuel and lubricating oil Bitumen What fractional distillation produces Fractional distillation separates crude oil according to boiling point. Uses of each fraction on next slide Getting more volatile
© Boardworks Ltd 2001 Fuel gas Petrol / gasoline Naphtha Paraffin / Kerosine Diesel fuel Fuel and lubricating oil Bitumen Burned in the refinery to fuel the distillation process, sold as LPG, purified and sold as bottled camping gas Fuel for cars and motorcycles, also used to make chemicals. Used to make chemicals. Fuel for greenhouse heaters and jet engines, manufacture of chemicals. Fuel for lorries, trains. Fuel for the heating systems of large buildings, fuel for ships, lubricating oil. Roofing, and road surfaces. Uses of each fraction
© Boardworks Ltd 2001 Fuel gas Petrol / gasoline Naphtha Paraffin / Kerosine Diesel fuel Fuel and lubricating oil Bitumen 1-4, mostly 1. 5-10 8-12. 10-16 14-22 20-70 More than 65 Fraction Number of carbon atoms
© Boardworks Ltd 2001 Burning Hydrocarbons The apparatus below is used to test the products of combustion of a hydrocarbon. any hydrocarbon + oxygen water + carbon dioxide Suction pump Candle wax is the hydrocarbon here ice- water Cloudiness- indicates carbon dioxide Liquid collected can be tested with anhydrous cobalt chloride paper (blue pink).
© Boardworks Ltd 2001 Alkanes Carbon atoms are unusual in that they are able to form strong covalent bonds to each other. Therefore, carbon is able to form chains of atoms of different length and so make molecules of different size. There are many thousands of molecules containing C-C bonds. In this course you learn about two groups of these compounds, alkanes and alkenes. Alkanes are hydrocarbons (molecules containing carbon and hydrogen only) in which each carbon atom is covalently bonded to four other atoms via 4 single covalent bonds. The other atoms can be either carbon or hydrogen.
© Boardworks Ltd 2001 Alkanes: Methane, CH 4 C H H H H C H H H H ‘Dot and cross’ diagram Displayed formula or graphical formula It is common in organic chemistry to show covalent bonds as single lines. This makes it easier to show how the atoms are connected.
© Boardworks Ltd 2001 C H H C H H H C C H H H H H H H Alkanes: Ethane, C 2 H 6 Ethane is the simplest alkane containing a C-C bond.
© Boardworks Ltd 2001 C H H H C H H H C H H H H C H H H C H H C H H H methane, CH 4 ethane, C 2 H 6 propane, C 3 H 8 Alkanes
© Boardworks Ltd 2001 butane, C 4 H 10 pentane, C 5 H 12 C H H H C H H C H H C H H H C H H H C H H C H H C H H C H H H
© Boardworks Ltd 2001 C H H H C H H C H H C H H C H H C H H H hexane, C 6 H 14 and so on………… Notice the carbon chain is not straight
© Boardworks Ltd 2001 methane, CH 4 ethane, C 2 H 6 propane, C 3 H 8 butane, C 4 H 10 pentane, C 5 H 12 hexane, C 6 H 14........ Alkane series of molecules General Formula, C n H 2n+2 Since all these molecules contain only single covalent bonds, alkanes are called saturated. This is called a homologous series
© Boardworks Ltd 2001 Increasing melting and boiling point. Physical Properties of the Alkanes The alkanes show a gradual change in melting and boiling points.
© Boardworks Ltd 2001 Cracking The demand for some hydrocarbons is high and cannot be supplied from fractional distillation alone. To boost the amount of some smaller hydrocarbons produced some of the high boiling point fractions are converted to more useful hydrocarbons. This process is called cracking. Cracking involves breaking C-C bonds. catalyst smaller alkane ethene Heat to vaporise Long alkane Distillation tower pressure
© Boardworks Ltd 2001 Cracking On the surface of the catalyst, long chain molecules are split apart or ‘cracked’. The reaction is: + C 8 H 18 C 6 H 14 + C 2 H 4 ethene Octane hexane Ethene is used to make plastics Heat pressure catalyst
© Boardworks Ltd 2001 CHEMICAL REACTIONS OF ALKANES Alkanes are generally unreactive. This is because they only contain C-H and C-C bonds. However, the lower members of the series readily combust in air. With plenty of air, the products are water and carbon dioxide only. Methane + oxygen water + carbon dioxide CH 4 + 2O 2 2H 2 O + CO 2 Combustion with limited amounts of air, however, produces carbon monoxide and water. Carbon monoxide is a poisonous gas.
© Boardworks Ltd 2001 Isomerism Alkanes of the same molecular formula can have different arrangements of atoms Extension These molecules are isomers of butane
© Boardworks Ltd 2001 Alkenes C H H C H H Ethene is the simplest alkene. C H H C H H C2H4C2H4 Carbon atoms can also form double covalent bonds to each other. Molecules with a double bond are called alkenes. or
© Boardworks Ltd 2001 Alkenes Alkenes have the general formula C n H 2n Alkenes are unsaturated because they contain a double C=C bond. In all alkenes at least two carbon atoms are joined to only 3 atoms.
© Boardworks Ltd 2001 Other alkenes Propene, C 3 H 6 Butene, C 4 H 8
© Boardworks Ltd 2001 CHEMICAL REACTIONS OF ALKENES The double bond allows alkenes to undergo reactions where atoms are added to the molecule. Thus, alkenes are more reactive than alkanes. + Br 2 An addition reaction: If ethene is bubbled through bromine water the solution becomes colourless - this is used as the test for an alkene. Explanation: bromine colours the solution orange, however, this is used up in the reaction and the product is colourless.
© Boardworks Ltd 2001 Pressure high temperature catalyst Polymerisation Alkenes can undergo addition reactions to other alkene molecules. The result is very long chains of carbon atoms called polymers. This is written as: And lots more.. Pressure high temperature catalyst n n This is called addition polymerisation ethene poly(ethene)
© Boardworks Ltd 2001 Examples of addition polymers Poly(propene) n n propene n tetrafluoroethane Poly(tetrafluoroethane) or PTFE n
© Boardworks Ltd 2001 Three very useful plastics
© Boardworks Ltd 2001 Poly(ethene) Bottles (HDPE) Poly(propene) boxes (PP)
© Boardworks Ltd 2001 REVIEW QUESTIONS
© Boardworks Ltd 2001 1. i) How is crude oil split into fractions ii) Name the seven fractions produced by fractional distillation of crude oil. iii) Give three differences between fractions. 2. i) What is meant by cracking? ii) Complete the formula below: C 8 H 18 + C 2 H 4 iii) The starting hydrocarbon is octane, name the two products of this reaction. iv) Describe how you could test for the presence of ethene.
© Boardworks Ltd 2001 3. i) Draw the bonding diagram for methane (show only outer shell electrons, carbon has an atomic number of 6). ii) Draw the graphical formula for methane. iii) Methane is saturated, explain what this means. iv) Draw the graphical formula for another alkane containing five carbon atoms. 4. Propane is used as ‘Calor Gas’. Complete the word and equation for its combustion in the plenty of air Propane + Oxygen _________ + _________ C 3 H 8 + O 2 _____ + ___ Why is it necessary to combust hydrocarbons in plenty of air?
© Boardworks Ltd 2001 5. i) In a homologous series the physical properties change gradually in the same direction. Plot a graph of boiling point against number of carbons for the alkanes. Use this graph to predict the boiling point of decane, C 10 H 22. 6. i) Write down the graphical formula for propene. ii) Write down the equation for the reaction of propene with bromine. iii) Predict the reaction of propene with hydrogen and write down the equation. Iv) What type of reaction is this?
© Boardworks Ltd 2001 7. Using the polymerisation of ethene as an example, explain the term addition polymerisation.
© Boardworks Ltd 2001 Harder Questions 8. Draw graphical formula for the three isomers of pentane. 9. Draw graphical formula for three isomers of butene. 10. Write down the equation for the combustion of propene in plenty of air and with a restricted amount of air.
© Boardworks Ltd 2001 ANSWERS TO REVIEW QUESTIONS
© Boardworks Ltd 2001 1. i) Crude oil is split into ‘fractions’ of different boiling point by fractional distillation. Here crude oil is vaporised and passed into a fractionating tower. Towards the top of the tower, where it is cooler, compounds of low boiling point condense and are collected on trays from which they are removed. Lower in the tower, higher boiling point fractions are collected. ii) Refinery gas / Petrol or gasoline / Naphtha / Kerosine or paraffin / Diesel / Oil / Bitumen iii) boiling point / viscosity / colour / size of hydrocarbon molecule
© Boardworks Ltd 2001 2. i) Cracking is the process used to convert long hydrocarbon molecules into smaller ones. The hydrocarbon liquid is vaporised and passed over a catalyst. On the surface of the catalyst the carbon chain is split to produce ethene and a smaller alkane. ii) C 8 H 18 C 6 H 14 + C 2 H 4 iii) C 6 H 14 is hexane, C 2 H 4 is ethene iv) You could pass the gas through bromine water. The bromine water, which is orange, will become colourless.
© Boardworks Ltd 2001 C H H H H C H H H H 3 i) ii) iii) Methane is saturated because it contains no double bonds. iv) C H H H C H H C H H C H H C H H H Pentane, C 5 H 12
© Boardworks Ltd 2001 Propane + Oxygen carbon dioxide + water C 3 H 8 + 5O 2 3CO 2 + 4H 2 O 4. In insufficient air/oxygen, carbon monoxide and water are produced. Carbon monoxide is a poisonous gas.
© Boardworks Ltd 2001 174°C 5.
© Boardworks Ltd 2001 C 3 H 6 + Br 2 C 3 H 6 Br 2 + Br 2 6. propene + H 2 propane i and ii) iii) iv) Addition reaction
© Boardworks Ltd 2001 Pressure high temperature catalyst n n This is called addition polymerisation because the molecules of ethene add together without producing any other products. ethene poly(ethene) 7.
© Boardworks Ltd 2001 8. Isomers of pentane
© Boardworks Ltd 2001 9. Isomers of butene
© Boardworks Ltd 2001 10. (i) 2C 3 H 6 + 9O 2 6CO 2 + 6H 2 O (ii) C 3 H 6 + 3O 2 3CO + 3H 2 O
© Boardworks Ltd of 45 KS4 Chemistry Alkanes and Alkenes.
Alkanes and Alkenes. Alkenes Alkanes Summary activities Combustion of alkanes Contents Cracking and polymerization.
© Boardworks Ltd of 30 KS4 Chemistry Useful Oil.
© Boardworks Ltd 2003 KS4 Useful Products from Organic Sources ORGANIC CHEMISTRY.
Organic Chemistry Revision Grade 10. What is crude oil? It is a mixture of hydrocarbons.
© Boardworks Ltd 2003 Organic Chemistry Alkanes and Alkenes.
© Boardworks Ltd of 37. © Boardworks Ltd of 37.
© Boardworks Ltd 2003 Section 3 Organic Chemistry Alkanes and Alkenes.
Objectives: To revise fractional distillation. To explain why large hydrocarbons are cracked. Outcomes: All of you will be able to explain what is meant.
© Boardworks Ltd 2003 Unit 2 Fuels ORGANIC CHEMISTRY.
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1.Alkanes are hydrocarbons in which all carbon atoms are bonded by single covalent bonds 2.Alkanes are said to be saturated because all the bonds are.
© Boardworks Ltd 2003 Industrial manufacture and uses of Alkenes.
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1 of 37© Boardworks Ltd of 37© Boardworks Ltd 2009.
Crude oil is a mixture of liquid hydrocarbons, often found together with natural gas. The lighter hydrocarbons- methane, ethane, propane a butane occur.
Useful Products from Organic Sources ORGANIC CHEMISTRY.
© Boardworks Ltd of 37. © Boardworks Ltd of 37 Supply and demand The amount of each type of fraction obtained by fractional distillation does.
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