Presentation on theme: "Chapter 7 “Ionic and Metallic Bonding”"— Presentation transcript:
1Chapter 7 “Ionic and Metallic Bonding” Pre-AP ChemistryCharles Page High SchoolStephen L. Cotton
2Section IonsOBJECTIVES:Determine the number of valence electrons in an atom of a representative element.
3Section IonsOBJECTIVES:Explain how the octet rule applies to atoms of metallic and nonmetallic elements.
4Describe how cations form. Section IonsOBJECTIVES:Describe how cations form.
5Explain how anions form. Section IonsOBJECTIVES:Explain how anions form.
6Valence Electrons are…? The electrons responsible for the chemical properties of atoms, and are those in the outer energy level.Valence electrons - The s and p electrons in the outer energy levelthe highest occupied energy levelCore electrons – are those in the energy levels below.
7Keeping Track of Electrons Atoms in the same column...Have the same outer electron configuration.Have the same valence electrons.The number of valence electrons are easily determined. It is the group number for a representative elementGroup 2A: Be, Mg, Ca, etc.have 2 valence electrons
8Electron Dot diagrams are… A way of showing & keeping track of valence electrons.How to write them?Write the symbol - it represents the nucleus and inner (core) electronsPut one dot for each valence electron (8 maximum)They don’t pair up until they have to (Hund’s rule)XPuzzlePieces
9The Electron Dot diagram for Nitrogen Nitrogen has 5 valence electrons to show.First we write the symbol.NThen add 1 electron at a time to each side.Now they are forced to pair up.We have now written the electron dot diagram for Nitrogen.
10The Octet RuleIn Chapter 6, we learned that noble gases are unreactive in chemical reactionsIn 1916, Gilbert Lewis used this fact to explain why atoms form certain kinds of ions and moleculesThe Octet Rule: in forming compounds, atoms tend to achieve a noble gas configuration; 8 in the outer level is stableEach noble gas (except He, which has 2) has 8 electrons in the outer level
11Formation of CationsMetals lose electrons to attain a noble gas configuration.They make positive ions (cations)If we look at the electron configuration, it makes sense to lose electrons:Na 1s22s22p63s1 1 valence electronNa1+ 1s22s22p6 This is a noble gas configuration with 8 electrons in the outer level.
12Electron Dots For Cations Metals will have few valence electrons (usually 3 or less); calcium has only 2 valence electronsCa
13Electron Dots For Cations Metals will have few valence electronsMetals will lose the valence electronsCa
14Electron Dots For Cations Metals will have few valence electronsMetals will lose the valence electronsForming positive ionsCa2+This is named the “calcium ion”.NO DOTS are now shown for the cation.
157.1Formation of CationsThe electron configuration of the sodium ion is the same as that of a neon atom.
16The sodium atoms in a sodium-vapor lamp ionize to form sodium cations. 7.1Formation of CationsThe sodium atoms in a sodium-vapor lamp ionize to form sodium cations.The sodium atoms in a sodium-vapor lamp ionize to form sodium cations (Na+). Applying Concepts How many electrons are in the highest occupied energy level of Na+?
177.1Formation of CationsWalnuts are a good dietary source of magnesium. Magnesium ions (Mg2+) aid in digestive processes.Walnuts are a good dietary source of magnesium. Magnesium ions (Mg2+) aid in digestive processes.
187.1Formation of CationsCations of Group 1A elements always have a charge of 1+. Cations of group 2A elements always have a charge of 2+.Cations of Group 1A elements have a charge of 1+. Cations of Group 2A elements have a charge of 2+.
197.1Formation of CationsA copper atom can ionize to form a 1+ cation (Cu+). By losing its lone 4s electron, copper attains a pseudo noble-gas electron configuration.
20Electron Dots For Cations Let’s do Scandium, #21The electron configuration is: 1s22s22p63s23p64s23d1Thus, it can lose 2e- (making it 2+), or lose 3e- (making 3+)Sc = Sc2+Sc= Sc3+Scandium (II) ionScandium (III) ion
21Electron Dots For Cations Let’s do Silver, element #47Predicted configuration is: 1s22s22p63s23p64s23d104p65s24d9Actual configuration is: 1s22s22p63s23p64s23d104p65s14d10Ag = Ag1+ (can’t lose any more, charges of 3+ or greater are uncommon)
22Electron Dots For Cations Silver did the best job it could, but it did not achieve a true Noble Gas configurationInstead, it is called a “pseudo-noble gas configuration”
23Electron Configurations: Anions Nonmetals gain electrons to attain noble gas configuration.They make negative ions (anions)S = 1s22s22p63s23p4 = 6 valence electronsS2- = 1s22s22p63s23p6 = noble gas configuration.Halide ions are ions from chlorine or other halogens that gain electrons
24Electron Dots For Anions Nonmetals will have many valence electrons (usually 5 or more)They will gain electrons to fill outer shell.3-P(This is called the “phosphide ion”, and should show dots)
257.1Formation of AnionsThe figure shows the symbols of anions formed by some elements in Groups 5A, 6A, and 7A.Atoms of nonmetals and metalloids form anions by gaining enough valence electrons to attain the electron configuration of the nearest noble gas. Interpreting Diagrams In which group of the periodic table do the elements bromine and iodine belong?
267.1Formation of AnionsBoth a chloride ion and the argon atom have an octet of electrons in their highest occupied energy levels.
277.1Formation of AnionsThe negatively charged ions in seawater—the anions—are mostly chloride ions.The six most abundant ions in seawater are chloride (Cl– ), sulfate (SO42–), sodium (Na+), magnesium (Mg2+), calcium (Ca2+), and potassium (K+).
29Stable Electron Configurations All atoms react to try and achieve a noble gas configuration.Noble gases have 2 s and 6 p electrons.8 valence electrons = already stable!This is the octet rule (8 in the outer level is particularly stable).Ar
31Section 7.2 Ionic Bonds and Ionic Compounds OBJECTIVES:Explain the electrical charge of an ionic compound.
32Section 7.2 Ionic Bonds and Ionic Compounds OBJECTIVES:Describe three properties of ionic compounds.
33Ionic BondingAnions and cations are held together by opposite charges (+ and -)Ionic compounds are called salts.Simplest ratio of elements in an ionic compound is called the formula unit.The bond is formed through the transfer of electrons (lose and gain)Electrons are transferred to achieve noble gas configuration.
34Ionic CompoundsAlso called SALTSMade from: a CATION with an ANION (or literally from a metal combining with a nonmetal)
35Ionic BondingNaClThe metal (sodium) tends to lose its one electron from the outer level.The nonmetal (chlorine) needs to gain one more to fill its outer level, and will accept the one electron that sodium is going to lose.
36Ionic BondingNa+Cl -Note: Remember that NO DOTS are now shown for the cation!
48= Ca3P2 Ionic Bonding Formula Unit This is a chemical formula, which shows the kinds and numbers of atoms in the smallest representative particle of the substance.For an ionic compound, the smallest representative particle is called a: Formula Unit
49Properties of Ionic Compounds Crystalline solids - a regular repeating arrangement of ions in the solid: Fig. 7.9, page 197Ions are strongly bonded together.Structure is rigid.High melting pointsCoordination number- number of ions of opposite charge surrounding it
50NaCl CsCl TiO2 - Page 198 Coordination Numbers: Coordination number- number of ions of opposite charge surrounding itCoordination Numbers:Both the sodium and chlorine have 6NaClBoth the cesium and chlorine have 8CsClEach titanium has 6, and each oxygen has 3TiO2
51Formation of Ionic Compounds 7.2Formation of Ionic CompoundsNaCl is the chemical formula for sodium chloride.Sodium cations and chloride anions form a repeating three-dimensional array in sodium chloride (NaCl). Inferring How does the arrangement of ions in a sodium chloride crystal help explain why the compound is so stable?
52Properties of Ionic Compounds 7.2Properties of Ionic CompoundsThe orderly arrangement of component ions produces the beauty of crystalline solids.The beauty of crystalline solids, such as these, comes from the orderly arrangement of their component ions.
53Do they Conduct?Conducting electricity means allowing charges to move.In a solid, the ions are locked in place.Ionic solids are insulators.When melted, the ions can move around.Melted ionic compounds conduct.NaCl: must get to about 800 ºC.Dissolved in water, they also conduct (free to move in aqueous solutions)
54- Page 198The ions are free to move when they are molten (or in aqueous solution), and thus they are able to conduct the electric current.
55Section 7.3 Bonding in Metals OBJECTIVES:Model the valence electrons of metal atoms.
56Section 7.3 Bonding in Metals OBJECTIVES:Describe the arrangement of atoms in a metal.
57Section 7.3 Bonding in Metals OBJECTIVES:Explain the importance of alloys.
58Metallic Bonds are… How metal atoms are held together in the solid. Metals hold on to their valence electrons very weakly.Think of them as positive ions (cations) floating in a sea of electrons: Fig. 7.12, p.201
59Sea of Electrons + Electrons are free to move through the solid. Metals conduct electricity.+
60Metals are MalleableHammered into shape (bend).Also ductile - drawn into wires.Both malleability and ductility explained in terms of the mobility of the valence electrons
61Due to the mobility of the valence electrons, metals have: - Page 201Due to the mobility of the valence electrons, metals have:Notice that the ionic crystal breaks due to ion repulsion!1) Ductility2) Malleabilityand
65Ionic solids are brittle Strong Repulsion breaks a crystal apart, due to similar ions being next to each other.+-Force+-+-+-
66Crystalline Structure of Metals 7.3Crystalline Structure of MetalsMetal atoms are arranged in very compact and orderly patterns.Metal atoms crystallize in characteristic patterns. a) Chromium atoms have a body-centered cubic arrangement. b) Gold atoms have a face-centered cubic arrangement. c) Zinc atoms have a hexagonal close-packed arrangement. Inferring Which of these arrangements is the most closely packed?
67Crystalline structure of metal If made of one kind of atom, metals are among the simplest crystals; very compact & orderlyNote Fig. 7.14, p.202 for types:1. Body-centered cubic:every atom (except those on the surface) has 8 neighborsNa, K, Fe, Cr, W
68Crystalline structure of metal 2. Face-centered cubic:every atom has 12 neighborsCu, Ag, Au, Al, Pb3. Hexagonal close-packedevery atom also has 12 neighborsdifferent pattern due to hexagonalMg, Zn, Cd
69Alloys We use lots of metals every day, but few are pure metals Alloys are mixtures of 2 or more elements, at least 1 is a metalmade by melting a mixture of the ingredients, then coolingBrass: an alloy of Cu and ZnBronze: Cu and Sn
70Why use alloys? Properties are often superior to the pure element Sterling silver (92.5% Ag, 7.5% Cu) is harder and more durable than pure Ag, but still soft enough to make jewelry and tablewareSteels are very important alloyscorrosion resistant, ductility, hardness, toughness, cost
717.3AlloysBicycle frames are often made of titanium alloys that contain aluminum and vanadium.Bicycle frames are often made of titanium alloys that contain aluminum and vanadium.
727.3AlloysThe most important alloys today are steels. Steels have a wide range of useful properties, such as corrosion resistance, ductility, hardness, and toughness.
73More about Alloys… Table 7.3, p.203 – lists a few alloys Types? a) substitutional alloy- the atoms in the components are about the same sizeb) interstitial alloy- the atomic sizes quite different; smaller atoms fit into the spaces between larger“Amalgam”- dental use, contains Hg