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Published byAugustus Clarke Modified about 1 year ago

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Modeling slow sequential dissociation dynamics processes with wave packet methods: Application to Cl 2 -He 2 vibrational predissociation A. Garc í a-Vela Instituto de Física Fundamental, Consejo Superior de Investigaciones Científicas, C/ Serrano 123, 28006 Madrid, Spain The AVPD model The model redistributes the absorbed wave packet intensity by means of three assumptions based on the nature of vibrational predissociation in X 2 -Rg 2 and X 2 -Rg vdW complexes [7]. 1) Only the most likely dissociation channel is allowed for the intermediate X 2 -Rg complex absorbed, namely Δv’=0 or Δv’=-1. 2) More specifically, for the v’ and v’-1 manifolds the Δv’=-1 channel is considered, while for the manifolds v

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