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S COPUS 資料庫檢索之經驗分享 使用者經驗分享 徐崇益博士 國立成功大學化學系所 國立成功大學化學系所.

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Presentation on theme: "S COPUS 資料庫檢索之經驗分享 使用者經驗分享 徐崇益博士 國立成功大學化學系所 國立成功大學化學系所."— Presentation transcript:

1 S COPUS 資料庫檢索之經驗分享 使用者經驗分享 徐崇益博士 國立成功大學化學系所 國立成功大學化學系所

2 靜宜大學蓋夏圖書館 433 台中市沙鹿區中棲路 200 號 逢甲大學 407 台中市西屯區文華路 100 號 ‎ ‎ 國立成功大學 701 台灣台南市東區大學路 1 號 ‎ ‎ 義守大學 840 高雄市大樹區學城路一段 1 號 ‎ ‎ 國立台灣科技大學 106 台灣台北市大安區基隆路四段 43 號 ‎ ‎ 長庚大學 333 桃園縣龜山鄉文化一路 259 號 S COPUS

3

4 OLED/F ENG C HIA U NIVERSITY

5 OLED/N ATIONAL C HENG K UNG U NIVERSITY

6 OLED/ I-S HOU U NIVERSITY

7 OLED/N ATIONAL T AIWAN U NIVERSITY OF S CIENCE AND T ECHNOLOGY

8 OLED/ C HANG G UNG U NIVERSITY

9 S TUDIED T HEME ( 研究主題 ) Studies on the Selectivity of Molecular Imprinted Polymer for Optical Modulated Biosensing System/Development and Application of Organic Blue Emitter Materials. ( 光學生化感測器之分子模版 選擇性探討與藍光有機材料開發應用 ) Keywords ; MIP 「分子模版」、 OLED 「有機發光二 極體」 2

10 B LUE E MITTER M ATERIAL 3

11 C ONCEPTION - OLED Synthesize material Blue emitter material focus preparation Vertical quartz-tube evaporation device purification Excited device Single-crystal XRD 4

12 1 H-NMR (300MHz, CDCl 3, ppm) 13 C-NMR (75MHz, CDCl 3, ppm) 2D-COSY PR650 spectra scan photometer HP4156 programmable voltage– current source meter JEOL JMS-700, FAB +, m/z Elementar vario EL Ⅲ Spectrum RX1 FTIR spectrometer NTEGRA Spectra - AFM / Confocal Raman Imaging spectrometer Differential scanning calorimetry (PerkinElmer DSC−7) (DSC, Perkin-Elmer Pyris Diamond) Thermo-gravimetric analysis (TGA, Perkin-Elmer Pyris 1) (PYRIS Diamond TG/DTA-10) Photoelectron spectroscopy (UPS, Riken Keiki AC-2) Cyclic voltammetry measurements CV-CH Instruments-627C Density functional theory (DFT) calculations at the B3LYP/6- 31G* using Gaussian03) Spontaneous emission transition probability formula N i (t) = N i0 exp(-A i t) X-ray powder diffraction (XRD, Shimadzu XRD-700) Single-crystal X-ray Bruker APEXII CCD diffractometer UV–Visible spectrophotometer (Hitachi−U3010) Luminescence spectrophotometer (Hitachi−F4500) Organic Light- Emitting Device NMR Mass/ Element OpticalLifetimePhysicalOrbitalCrystalSurface OLED Analyzer Map 5

13 S UMMARIZE OLED (1) (2) Update ︰ 11,324 on 0613/ ,533 on 0902/ ,638 on (3) 6

14 A NALYZE RESULTS - OLED 學校名稱 國家別名 來源期刊 作者貢獻 國別指引 領域趨勢 7

15 A UTHOR NAME : KEY WORD - OLED / TAIWAN 8

16 S UB - KEYWORDS FOR OLED ElectrodeHole transfer layerElectron transfer layer Emitter layerPhosphorescencePurity 9

17 Kim, Y Park, Y. H Samal, G. S Kim, K. S Shin, M. G Hsu, C. Y Rajeswaran, M Lee, M. T Jeon, S. O Kim, K. S Jeon, Y. M Blue (802/1783) Dibenzothiophene (28/76) Red/Green (799/1187) Pyrene (18/158) suzuki coupling(29/315) Molecular charge transfer(53/1135) donor-acceptor(46/381) single crystal(44/1086) monodisperse(18/190) Blue (375/1540) Carbazole (253/642) Red/Green (402/1354) ~2006 (2154) 2007 (545) 2008 (387) 2009 (612) 2010 (488) 2011 (348) 2012 (366) 2013 (364) Total 5344 OLED Kirimura, K. 2002, Liu, H. 2008, Yang, F., 2008, Li, Y. Y. 2009, Xia, C. Y. 2009, Grisorio, R.2010, Nayak, P. K. 2010, Zafra, J. L. 2011, Hsu, C. Y Chen, J. P. 2003, Lee, T. H. 2005, Seo, J. H. 2005, Guan, M. 2006, Kawakami, A. 2008, Tsuzuki, T. 2009, Cho, I. 2012, Li, Y.2012, Hsu, C. Y (640)(948)(1560)(1509) (1325)(1376)(1204) (3072) OLED MAP OLED (5344/11638) Purity (526/683) Electron transfer layer (1253/1744) Emitter layer (1038/2315) Electrode (3381/2600) Phos- phorescence (458/2139) Hole transfer layer (1265/1453) 22.7%↑ 23.4%↑ 21.1%↑ 22.1%↑ 25.8%↑ 16.9%↑ 17.5%↑ Update ︰ 1010/

18 T HERMAL EVAPORATOR PURIFICATION SYSTEM 11

19 C RYSTAL S TRUCTURE (T HIOPHENE - X ) 12 DBTO-MPDBTO-MFDBTO-PP Along a-axis Along b-axis Along c-axis DBTO-MPDBTO-MFDBTO-PP Inter-molecular distance 3D profile conformation intermolecular charge transfer DBTO- MP DBTO- MF DBTO- PP along a-axis electron conjugation goodexcellentpoor along b-axis sequence of Intermolecular arrangement excellent poor intermolecular distance (Å) π-π stacking interactions negligiblelittleleast along c-axis symmetry of Intermolecular conformation good excellent 3D profile conformation z-shapespiralbrick superimposition of intermolecular interactions poorexcellentgood intramolecular charge transfer DBTO- MP DBTO- MF DBTO- PP dihedral angles 28 o 30 o 33 o quantum efficiency donor and accepter effect moreaverage quantum yield (%)

20 I DENTIFY WITH FINGERPRINT (T HIOPHENE - X ) DBTO-MPDBTO-MFDBTO-PP Along a-axis Along b-axis Along c-axis 13

21 I DENTIFY WITH FINGERPRINT (T HIOPHENE - X ) DBTO-MPDBTO-MFDBTO-PP Inter-molecular distance 3D profile conformation 14

22 I DENTIFY WITH FINGERPRINT (T HIOPHENE - X ) intermolecular charge transfer DBTO- MP DBTO- MF DBTO- PP along a-axis electron conjugation goodexcellentpoor along b-axis sequence of Intermolecular arrangement excellent poor intermolecular distance (Å) π-π stacking interactions negligiblelittleleast along c-axis symmetry of Intermolecular conformation good excellent 3D profile conformation z-shapespiralbrick superimposition of intermolecular interactions poorexcellentgood intramolecular charge transfer DBTO- MP DBTO- MF DBTO- PP dihedral angles 28 o 30 o 33 o quantum efficiency donor and accepter effect moreaverage quantum yield (%)

23 S UBMIT PAPER TO T ETRAHEDRON (1) (2)(3) (4) (5) 16

24 T ITLE : "F LUORESCENT O LIGOMERS OF D IBENZOTHIOPHENE S,S- DIOXIDE D ERIVATIVES : T HE I NTERPLAY OF C RYSTAL C ONFORMATIONS AND P HOTOPHYSICAL P ROPERTIES " Submitted original paper to Chemistry of Materials Submitted original paper to Organic Electronics Submitted original paper to Journal of Materials Chemistry Submitted original paper to Tetrahedron Ref. TET-D The interplay of crystal conformation and photophysical properties in dibenzothiophene-S,S-dioxide fluorescent oligomers Dear Dr. Whang, Thank you for submitting your work to Tetrahedron. Before ……… We regret to inform you that your manuscript does not meet the Journal's required standard. Please make changes/corrections as detailed in the comments below…….. Yours sincerely, D. Jones; Administrative Support Agent [24-Feb-11], Tetrahedron …………………………… Ms. Ref. No.: TET-D R2 Title: Fluorescent Oligomers of Dibenzothiophene S,S-dioxide Derivatives: The Interplay of Crystal Conformations and Photophysical Properties Tetrahedron Dear Dr. Thou-Jen Whang, I am pleased to confirm that your paper "Fluorescent Oligomers of Dibenzothiophene S,S-dioxide Derivatives: The Interplay of Crystal Conformations and Photophysical Properties" has been accepted for publication in Tetrahedron and sent to the publisher. You should be receiving galley proofs within several weeks. Thank you for submitting your work to this journal.; With kind regards, Kiyoshi Tomioka, PhD, Editor, Tetrahedron 17

25 MIP VS OLED 18

26 C O -A UTHORS 19

27 F IRST A UTHOR - H SU C. Y. 20

28 C ONCEPTION - MIP Thermometric calorimeter Molecularly imprinted polymers imitate preparation Functional monomer Cross-linkers titrated to Protein (hydrophilic, hydrophobic etc.) EVAL Ploy (vinyl alcohol-co- ethylene) Fe 3 O 4 (magnetite nanoparticles) Amino acid (Tyrosine, Phenylalanine etc.) 21

29 2277 Thermal Activity Monitor, Thermometric AB and Scitech Software AB, Sweden Model Slover P47H- PRO, NT-MDT, Moscow, Russia Luminescence spectrophotometer (Hitachi−F4500) Particle sizer (90Plus, Brookhaven Instruments Co., NY) NOVA 1000e (Quantachrome Instruments, FL), Brunauer Emmett Teller ( Quantachrome Instruments, Florida) MPMS XL-7 system (Quantum Design, San Diego, CA) NTEGRA Spectra - AFM / Confocal Raman Imaging spectrometer Minimize Energy command in the MM2 menu (from software of Chem3D) MIP Analyzer Map 22

30 S UMMARIZE MIP (1) (2) (3) Update : 4,057on 1014/

31 A NALYZE RESULTS - MIP 學校名稱 國家別名 來源期刊 作者貢獻 國別指引 領域趨勢 24

32 S UB - KEYWORDS FOR MIP Amino acidIsothermal titrationMicrocontract Cross-linkingMagnetic nanoparticleProtein 25

33 Seong, H Lin, H. Y El Kirat, K Li, L., A Gao, R. X Kryscio, D. R Lin, J. M Vidyasankar, S Peng, H Weber, A Zhang, L. Y. 2002~2003 Lakshmi, D Tang, S. W.2006 Lin, Y. C Mirmohseni, A Casey, C. N Lin, H. Y Hsu, C. Y Zhou, X Kan, X. W Su, W. X Lee, M. H Gao, R. X ~2006 (96) 2007 (17) 2008 (24) 2009 (21) 2010 (20) 2011 (17) 2012 (15) 2013 (11) Total 229 MIP Lin, H. Y. 2006, Lee, M. H ~2010 (6), Li, L., 2009, Su, W. X. 2009, Qu, P. 2010, Khadro, B Kirchner, R.2002, Weber, A Cliff, M. J. 2003, Weber, A Wollner, K. 2007, Gue, A. M Dvorakova, G (521) (525)(432) (342) (355) (254) (268) (1274) MIP MAP Update ︰ 0902/2013 Update :

34 M AIN A UTHOR OF S TUDIED THE MIP (T AIWAN ) 27 (1) (2)

35 期許:吃得下飯、睡得著覺、笑得出來! 伙伴協助者: 徐 崇 益 現在進行 著; 1. 科普計畫執行與推動、規劃繕擬與申請 2. 產學計劃案籌備與規劃、協助廠商申請 SBIR ; Skype: hsuyi888 Thank you for your attention ! 28 HSUYI


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