Presentation on theme: "Hazardous Waste Determination Flowchart"— Presentation transcript:
1Hazardous Waste Determination Flowchart Department of Environmental Health & SafetyHazardous Waste Management
2Master Flowchart START HERE HAZARDOUS WASTE STOP Your waste is NOT aHazardous Waste?PhysicalStateContinue to:Drain DisposalLIQUIDSOLIDDeface containerlabel. Disposein regular trashConsider your wasteHAZARDOUS and have aWaste Determinationcompleted.Contact:Master FlowchartYour waste is:HAZARDOUS WASTEContactfor proper disposalNOYESIs your material a WASTE?Refer to: Waste DefinitionIs your waste a SPECIAL WASTE?Refer to: Special WasteIs your waste IGNITABLE?Refer to: IgnitabilityIs your waste CORROSIVE?Refer to: CorrosivesIs your waste REACTIVE?Refer to: ReactivityIs your waste an OXIDIZER?Refer to: OxidizingIs your waste TOXIC?Refer to: ToxicityStill think your waste might be HAZARDOUS?START HEREIs your waste a Medical Waste?Refer to: Medical WasteSTOP
3Waste Definition Can the material be used by someone else? Is the material:Intended to be discarded ( i.e. the materialis “abandoned,” “recycled” or inherently“waste-like”) EPA views old chemicals thathave not been used in years and which areunlikely to be used in the foreseeable futureas waste.Give the material to anotherauthorized laboratory or user.If your material is not a WASTE,then it is not a Hazardous Waste.Waste DefinitionSTARTYESNOMaterial meets the definition of WASTEContinue on Master Flowchart
4Special Waste START HERE Is your waste RADIOACTIVE? Refer to:Radioactive Waste FlowchartUsed Batteries FlowchartPaint Waste FlowchartAsbestos Waste FlowchartCompressed Gas Cylinders & Aerosols FlowchartEmpty Container FlowchartScrap Metal FlowchartPhotographic Chemicals FlowchartWaste Oil & Antifreeze FlowchartIs your waste RADIOACTIVE?Is your waste a BATTERY? (i.e., NiCd, Lead Acid, etc.)Is your waste PAINT?Does your waste contain ASBESTOS?Is your waste a GAS CYLINDER or AEROSOL CAN?Is your waste an EMPTY CONTAINER?Is your waste a METAL?Is your waste a PHOTOGRAPHIC CHEMICAL?Is your waste an OIL or ANTIFREEZE?START HERESpecial WasteMaterial is NOT a SPECIAL WASTE.Continue on Master Flowchart.YESNOor
5Radioactive Waste START HERE RADIOACTIVE WASTE. Is this symbol (with or without wording):displayed on thewaste or wastecontainer?Does the waste contain any:RADIOACTIVE MATERIAL?Does the waste contain any isotope of anelement that undergoes nucleartransformations emitting a form of radiation?URANIUM or THORIUM COMPOUNDS?(i.e., uranium dicarbide, uranium dioxide, uranium hexafluoride,uranium hydride, uranium monocarbide, uranium tetrafluoride,uranocene, Uranyl acetate, uranyl nitrate or thoriumacetylacetonate, thorium carbide, thorium chloride,thorium dioxide, thorium disulfide, thorium fluoride,thorium nitrate, thorium oxalate, thorium sulfate)Is the waste a:Self-Illuminated Exit Sign? Smoke Detector?Electron Capture Detector (ECD) or Static Eliminator?START HERERadioactive WasteYESNOorYour waste is NOT a RADIOACTIVE WASTE.Continue on Special Wastes Flowchart.If you believe you still have a radioactive waste,contactYour waste MAY BE aRADIOACTIVE WASTE.ContactFor further assistanceYour waste is a
6Paint Solvents & Thinners Type ofPaint RelatedWasteLatex PaintOil Based PaintLacquer Based PaintPaint Solvents & ThinnersNOIs the waste:Paint Related Waste?(including Latex Paint, Oil Based Paint,Lacquer Based Paint, Paint Solvents andThinners)START HEREYESContinue onSpecial Wastes FlowchartPaint WasteYour waste is a:HAZARDOUS WASTEContactto schedule a pickup.Please note that Air Quality Regulations doNOT allow us to dry-out oil based paints orsolvents for the purpose of disposal.There are alternative disposaloptions for latex paint.Please contactfor further information.
7Continue on Special Wastes Flowchart Does the waste:Contain > 1% Asbestos?Examples of Materials CommonlyContaining Asbestos (but not limited to):• Sheet Rock Taping and Joint Compound• Fire Door Core Material• Roofing Felt• Floor Tile and Mastic• Transite Sheets (Cementious Panels)• Sprayed-on Ceiling Materials• Boiler Insulation• Pipe Insulation• Brake Pads• Clutch Pads• Gaskets• Electrical Wire Insulation• Thermal Insulation on Electrical AppliancesSTART HERENOAsbestos WasteContinue on Special Wastes FlowchartYour waste is a:HAZARDOUS WASTEContactto schedule a pickupYES
8Compressed Gas Cylinders & Aerosols Is the waste:An aerosol container?START HEREIs the container:Completely emptied of the contents to themaximum extent practical under normal use(which is atmospheric pressure) (i.e.,the spray mechanism is not defective)?Did the container:Formerly contain an Hazardous Waste?(refer to P-Listed Wastes)Dispose of in regular trashIs the waste a:Compressed gas cylinder or a single usepropane canister?(including gas cylinders, lecture bottles orrefillable LPG canisters)Compressed Gas Cylinders & AerosolsYESNOYour waste is a:HAZARDOUS WASTEContactto schedule a pickupYour aerosolcontainer even ifcompletely empty is a:ContactContact the Supplier or Manufacturer andarrange to have the compressed gas cylinderreturned to them for proper disposal.If not returned to the Supplier or Manufacturer,your waste is a:Contact to schedule a pickup.Continue on Special Wastes FlowchartOrDon’tKnow
9Empty Containers START HERE Continue on Special Wastes Flowchart Is the waste:An “empty” container that formerly contained ahazardous material?Does the waste:Meet the definition of EMPTY?For containers that held a pourable hazardous material…No further material can be poured or drained from thecontainer when it is held in any orientation.For containers that held a non-pourable hazardous material…No hazardous material remains in the container thatcan be removed by physical methods.Did the empty container:Formerly contain a material that had an oral LD50 < 50 mg/kg?(refer to the Toxicity section on Material Safety Data Sheet)Formerly contain an Extremely Hazardous Waste?(refer to P-Listed Waste)START HERE■ All containers must be triple rinsed before disposal. If the containerheld a strong-smelling material, rinse with an appropriate solvent. Ifthe cleaning solvent is a hazardous material, collect & dispose of asa hazardous waste.■ Deface label and mark “triple rinsed”.■ Recycle glass, bottles and cans where possible.■ Under no circumstances may a container labeled with theinternational radioactive symbol or with the words “HazardousWaste” be disposed of in the regular trash.Empty ContainersYESYES orDON’TKNOWNOContinue on Special Wastes FlowchartYour waste container, even ifcompletely empty, is a:HAZARDOUS WASTEContactto schedule a pickup
10Scrap Metal Is the waste: A solid metal? START HERE Is the metal:Aluminum,Copper,Iron,Lead,Steel, orZinc?START HERENOYour waste can’t be recycled as Scrap Metal.Continue on Special Wastes Flowchart.YESWhen you have accumulatedmore than 5 pounds of material,Contactto schedule a pickup.
11Fixer, Bleach-Fixer (Blix), Color Developer, Photographic ChemicalsSTART HEREIs the waste:A chemical product used for photography?NOContinue on Special Wastes FlowchartYESUnused photographic chemicals may be a:HAZARDOUS WASTE.Refer to the Corrosives Flowchart andToxicity Flowchart orContact for assistance.Has the photographic chemical been used?NOYESIs the waste:Fixer, Bleach-Fixer (Blix), Color Developer,or Color Stabilizer?Your waste should be recycled in thesilver recovery units.Contact for assistance.YESNOYour waste is a:HAZARDOUS WASTEContactto schedule a pickup.Is the waste:Selenium Toner or Sepia Toner?YESNOIs the waste:Stop Bath or Hypo Cleaning Agent?YESContact to discuss disposal.NOContact to assistwith the proper disposal of yourphotographic chemicals.
12Waste Oil & Antifreeze START HERE Continue on Special Wastes Flowchart Is the waste:an Oil or Antifreeze?Is your waste:• Motor Oil• Automatic Transmission Fluid• Power Steering Fluid• Diesel Fuel• Gear Oil• Turbine Engine Oil• Hydraulic Oil• Fuel Oil• Kerosene (#3, #4, & #6)Oils can NOT be disposed down the drain(even if they are not hazardous waste).Is your waste?• Ethylene Glycol based Antifreeze• Coolant from Chillers / HVAC systems• Propylene Glycol based Antifreeze (freeze protection > 0o F)• Any type of oil contaminated with a hazardous chemical• Chlorinated Solvents• Metal working fluids• Degreasing solvents• Freon and Freon contaminated refrigeration oil• Naptha• Transformer Oil• Brake Fluid• Radiator Flush• Deicers• Oily Water• Antifreeze with a freeze protection above 0o FSTART HEREWaste Oil & AntifreezeContinue on Special Wastes FlowchartYour waste should be recycled .Contact for assistanceYour waste is a:HAZARDOUS WASTEContactto schedule a pickupYESNO
13Used Batteries START HERE Continue on Special Wastes Flowchart Is the waste: A Battery?Is your waste (not leaking/damaged)?• Lead Acid Batteries• Ni-Cd Rechargeable Batteries• Lithium Batteries• Mercuric Oxide Batteries• Silver Oxide BatteriesIs your waste (leaking/damaged)?START HEREIs your waste: Alkaline BatteryUsed BatteriesContinue on Special Wastes FlowchartYour batteries should be recycled accordingto the universal waste regulations.Contact for assistance.Your waste is a:HAZARDOUS WASTEContactto schedule a pickupThese are non-hazardous and can beplaced in the regular trash, however, in aneffort to become environmentally friendlyyou may choose to collect these batteries ina 1-gallon container for recycling purposes.Contact to obtaincontainers and schedule pickups.YESNO
14Reactivity START HERE HAZARDOUS CLASS Continue on Master Flowchart Does the waste:React violently with water, or form potentiallyexplosive mixtures with water?Create toxic gases when in contact with water?React violently when exposed to air or formpotentially explosive mixtures with air?Create toxic gases when exposed to air?Is the waste:Unstable (readily undergoes violent change with orwithout detonating or exploding?A potential peroxide former that has either exceededits open or shelf time limits or is stored in anundated containerSTART HEREReactivityHAZARDOUS CLASSREACTIVEContactfor assistance.Material does NOT meet the definition of REACTIVE.Continue on Master FlowchartNOYES
15Corrosives START HERE Non-Aqueous or Non-Liquid Waste Aqueous Physical StateofWasteWaste has:A pH greaterthan or equalto 12.5(pH ≥ 12.5)A pH less thanor equal to 2(pH ≤ 2)When mixed with an equivalentweight of water, the waste:Produces a solution havinga pH greater than or equal to12.5 (pH ≥ 12.5)a pH less than or equal to 2Non-Aqueous orNon-Liquid WasteAqueousLiquid WasteThe ability to cause destruction of livingtissue or steel surfaces by chemical actionHAZARD CLASSCORROSIVE ACIDContactfor assistanceCORROSIVE BASECORROSIVEMaterial does NOT meet the definition of CORROSIVEContinue on Master FlowchartYESNO
16Ignitability SOLID LIQUID START HERE HAZARD CLASS IGNITABLE Physical StateofWasteIs the waste:An aqueous solutioncontaining ≥24%alcohol?Is the flash point ofthe waste(or any single phase ifmulti-phase)≤140oF (≤60oC)?Capable of causing firethrough friction, moistureabsorption, or spontaneouschemical change?SOLIDLIQUIDIgnitabilityHAZARD CLASSIGNITABLEContactfor assistanceMaterial does NOT meet the definition of IGNITABLE.Continue on Master FlowchartYESNO
17An aqueous solution of any of the common categories listed below Does the waste:Release oxygen when reacting with another chemical?React with organic materials (i.e., oils, greases, solvents, paper,cloth, wood, etc.) resulting in fire or the generation of heat?Is the waste:A member of one of the common oxidizer categories listed below?orAn aqueous solution of any of the common categories listed belowwhich exhibits any of the oxidizing properties stated above?START HEREOxidizingMaterial does NOT meet the definition of OXIDIZERContinue on Master FlowchartHAZARD CLASSOXIDIZERContactfor assistanceYESNO* Oxidizing mixtures having a pH £ 2 are classified as corrosive.• Sulfuric acid (pH > 2)*• Perchloric acid (pH > 2)*• Hydrogen peroxide• Nitric acid (pH > 2)*• Bromine• Chromic acid (pH > 2)*LIQUIDS• Periodic acid• Permanganates• Permangic acid• Peroxides• Persulfates• Iodates• Iodine• Manganese dioxide• Nitrates• Perborates• Perchlorates• Dichromates• Ferric sulfate• Ferric chloride• Ferric trioxide• Ferriccyanides• Hypochlorites• Bismuthates• Bromates• Chlorates• Chlorites• Chromates• Chromium trioxideSOLIDSExamples:
18Toxicity START HERE Toxic Hazardous Waste Continue on Master Flowchart ■Waste displays the toxicity characteristic if it exceeds certainconcentration levels using specified test methods.■The toxicity characteristic leaching procedure (TCLP) is thespecified test method for determining if a waste is a toxichazardous waste.The TCLP simulates the conditions in a landfill and thenanalyzes the concentrations of specifically listed chemicalsand heavy metals that could potentially leach into thegroundwater.Examples of the most common toxic materials, theirregulatory limits, and their corresponding waste codes arelisted right.START HEREMaterial does NOT meet the definition of TOXICITY.Continue on Master FlowchartD004D005D018D006D022D007D008D009D035D010D011D039D040D0435.0 ppm100 ppm0.5 ppm1.0 ppm6.0 ppm0.2 ppm200 ppm0.7 ppmArsenicBariumBenzeneCadmiumChloroformChromiumLeadMercuryMethyl Ethyl Ketone (MEK)SeleniumSilverTetrachloroethyleneTrichloroethyleneVinyl ChlorideToxic Hazardous WasteNOTE: The 8 compounds that appear in boldfaceare referred to as the “RCRA 8 metals” and areamong the most common toxic wastes generatedat Stony Brook.
19Medical Waste START HERE Regulated Medical Waste. Is the waste:A fluid blood or blood product?A culture of an agent infectious to humans?Generated from the treatment or immunization of animals or humans?Generated by research involving live or attenuated pathogenic organisms?Used or unused sharps (i.e. hypodermic needle, scalpel, razor blades, pasteurpipettes), or any glass or plastic) contacted with infectious materials?Generated from work involving recombinant DNA?Blood, tissue samples, organs, cadavers from infected experimental animals?START HEREMedical WasteYour waste is NOT a MEDIACL WASTE.Continue on MASTER FLOWCHARTYour Waste is aRegulated Medical Waste.Contactfor further assistanceYESNOA cerebrospinal fluid, synovial fluid, pleural fluid, pericardial fluid, peritoneal fluid,amniotic fluid, saliva in dental procedures, any body fluid visibly contaminated withblood, biological materials in labs (etiologic), unfixed human tissue or organ?Chemotherapy Wastes (Wastes with a trace (<15cc) of chemo-waste oranti-neoplastic agents?
20Drain Disposal START HERE Is the waste: A Liquid? Waste CANNOT go down the drain.NOYESDoes the waste:Contain any Radioactive Material?Waste CANNOT go down the drain.Waste is a RADIOACTIVE wasteYESNOIs the waste:Aqueous with only one phase?Waste CANNOT go down the drain.Waste is probably a Hazardous WasteYESNODoes the waste:Contain significant toxics? (alcohols >24%, metals, or other toxics?Waste CANNOT go down the drain.YESNOWaste CANNOT go down the drain.Waste is a Hazardous Waste.Cannot neutralize, unless documentedpart of experimental procedure.Contact for approval.Does the waste have a:pH ≤ 5 or pH ≥ 12.5 ?YESNODoes the waste have a:pH ≥ 5 and pH ≤ 12.5?(a strong acid or base more dilute than 0.01N)Lab may be able to drain dispose as long as thereare no heavy metals or other hazardousconstituents.Not sure contact for confirmation.YESGo back to MASTER FLOWCHART
21THE ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT QUESTIONS?COMMENTS?CONCERNS?CALLTHE ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT@