Presentation on theme: "Explosion of Hydrocarbon Fuels"— Presentation transcript:
1Explosion of Hydrocarbon Fuels Aviation Fire Dynamics – Spring 2013Final PresentationDerick Endicott
2What is an ‘explosion’? An explosion can be defined as: -“the sudden conversion of potential (chemical in this case) into kinetic energy including the production and release of gases under pressure.”-“the process of the rapid release of energy involving spontaneous and vigorous reactions with rapid production of very large volumes of gases and heat fluxes, having destructive effects on nearby surroundings”
3Why study explosions?Explosions can be caused by accidental or deliberate sources including but not limited to failure of electronic components, fuel supply lines, and fuel storage tanks.Explosions can produce not only extreme temperatures which can comprise structures but devastating pressure waves that can annihilate anything in close proximity.In order to predict these temperature and pressures an explosion may produce and the subsequent damage, one must have a deep multidisciplinary knowledge.
4Important Definitions Combustion/Fire: chemical reaction in which a substance combines with an oxidant and releases energy. Part of the energy released is used to sustain the reaction. Ignition: ignition of a flammable mixture may be caused by the mixture coming in contact with a source of ignition with sufficient energy or the gas reaches a high enough temperature to cause the gas to autoignite.Fire Point: the lowest temperature at which a vapor above a liquid fuel will continue to burn once ignited; higher than the flash point.
5Important Definitions Mechanical Explosion: an explosion resulting from the sudden failure of a vessel containing high-pressure nonreactive gas.Overpressure: the pressure on an object as a result of an impacting shock (or pressure) wave. This pressure is in excess of the ambient value.Peak Overpressure: maximum pressure minus the ambient pressure.
6Types of HC Explosions: Deflagration vs. Detonation The term ‘explosion’ does NOT imply detonation! Type is determined from the pressure wave developed by the explosion:DeflagrationPressure wave (expansion) travels at the speed of sound in unburned gaseous fuel-air mixture, while the reaction front travels slower than the speed of sound.Simple burning chemistry, involving turbulent flame speed (or laminar to simplify).Rapid oxidation5-10 atm pressure riseDetonationPressure wave (now a shock wave) travels faster than the speed of sound in unburned gaseous fuel-air mixtures.More complicated reaction, not just simple HC burning chemistry, sometimes involving highly unstable agents.Usually associated with fuels like TNT. CAN OCCUR in HC/Air mixtures.atm pressure rise (HC Fuel)
7Fire or Explosion?For deflagrations, only depends upon the rate of energy release!No real definition or limit which describes what level of release rate is an explosion and what level is just a fire.An ‘explosion’ must have a sudden enough energy release such that the energy ‘builds up’ at the site of explosion.This energy may be dissipated by pressure waves, projectiles, thermal radiation, acoustic energy, etc. 
8Fire or Explosion?The maximum pressure achieved and the maximum rate of pressure increase are important parameters when characterizing an explosion and what effects it will have, and the possible subsequent damage.
9REFERENCE: Dr. Jeng lecture notes, combustion book 
12Parameters that Determine Explosion Type Ambient temperatureAmbient pressureComposition of explosive materialPhysical properties of explosive materialIgnition sourceUn/Confined fuel-air mixtureTurbulenceAmount of combustible material availableRate at which combustible material is introduced
13Flammability/Explosive Limits It is not always the initial component failure that causes an explosion!Is there exists a source of ignition within an area where the air fuel mixture is within flammability/explosive limits?These fuels will have both Upper and Lower Explosive Limits (UEL and LEL).High temperatures and pressures can expand these limits.
14Focus of Study Fire/Combustion Hydrocarbon Deflagrations Hydrocarbon DetonationsShort Intro to Detonations of high explosivesHow to prevent explosions
15CombustionCombustion is the exothermic oxidation reaction between a fuel (HC) and an oxidizer (AirOxygen).C and H easily break current bonds (when heated) and form new molecules with O + HEAT….this is how a fire thrives.Or more simply:
16CombustionThe previous slide describes the global reaction, or the simplest way to approach the reaction.Reality? long chain of reactions in which many radical intermediate species appear.Fires flammable F/A mixture exposed to a source of heat or ambient temperature at or above the flash/fire point of the mixture.
17Flame Spread Thermal/molecular diffusion Gravity (buoyancy) causes the heated combustion products (less dense) to rise and surrounding air/fuel to be entrained in.While this is happening the surrounding air/fuel is being heated for reaction.
22DeflagrationsSubsonic combustion propagating through an unburned mixture via thermal/molecular diffusion.Reaction relatively very slow compared to detonation.Most common type of HC explosion*Main danger: heat/thermal damage
23Molecular (Thermal) Diffusion Thermal motion of particles at temperatures above absolute zero.Flame front(serves as concentration gradient)Mass flux acrossconcentration gradient[Reactants]Low[Reactants]HighCombustion Products(Hot)Unburnt F/AMixture(Cold)[Products]High[Products]Low[ ] denotes concentration
24Deflagrations – Flame Speed Flame speed, an important concept in the physics of flames can be understood using a basic 1-D tube assumption.
25δ SL P T α Φ ~ 1 δ P T α Φ ~ 1 SL δ – flame thickness SL – flame speed (laminar)δSLSLPTαΦ ~ 1δPTαΦ ~ 1
29Predicting Laminar Flame Speed Experimental – Case Western Reserve/Univ. of Connecticut 
30Predicting Laminar Flame Speed Experimental – Case Western Reserve/Univ. of Connecticut 
31Reality: Turbulence Turbulent intensity Reality Explosions highly turbulent!High turbulence more surface area (of flame) increased flame speed.Turbulence model developed by Klimov  for a turbulent intensity >> 1
33Flammability Limits (U/L-FL/EL) Upper and lower flammability/explosive limits are critical to predicting an explosion.‘flammability’ and ‘explosive’ are used interchangeably and have the same meaning.Explosive limits widened with increasing temperature.UEL significantly with P, but pressure has little effect on LEL.Important for confinedexplosions
35When will a deflagration be an explosion? High turbulence improves mixing increase flame speedHigh temperatures increase flame speedHigh pressure induce explosion in confined areaStoichiometry close to 1.0 produces greatest flame speedWell mixed F/A mixture rapid propagationFuel is introduced rapidly, while allowing the mixture to stay within explosive limitsLarge volume of mixed F/A for a flame to propagate through
36Fuel introduced at high rate Intense F/A mixing High turbulenceFuel introduced at high rateIntense F/A mixingIf damaged possible ignitionsources existProper EL exists somewhereTemperature/Pressure vary bysituation
41DetonationsStrong pressure wave (shock) compresses the unreacted mixture in front of the reaction front above its autoignition temperature abrupt pressure change in front of the reaction.Shock can travel at 5-7 times speed of sound.A detonation is a shock wave sustained by the energy released by this combustion reaction of the compressed mixture.Main danger: Overpressure!
44Detonation of HC Fuels HC fuels hard to detonate! Direct detonation heavy HC fuels oxygen-enrichment required very high EignFor practical use O2 must be stored on board, or a generation system must be on board.Undesirable method for propulsion purposes because of the added weight and complexity (not to mention danger of storing pure O2).
45Detonation of HC FuelsThe ignition energy to directly detonate at STP for practical HC-air stoichiometric mixtures is on the order of 105 J .The typical spark plug can provide only 100 mJ of ignition energy!
47Detonation of HC Fuels small-tube pre-detonator How to successfully detonate?small-tube pre-detonatorThis also means that a pure detonation of HC fuels is not likely to happen by accident, like a deflagration explosion could. Good for our safety!But there is another means by which a detonation could occur, purposefully or by accident…
48DDT – Deflagration to Detonation Conclusion?...direct detonations in HC fuels NOT LIKELY. Often times a detonation in HC fuels will be produced by the transition of a subsonic flame front from deflagration to detonation (DDT).
49DDT – Deflagration to Detonation Once flame front speed exceedsThe sonic velocity in theUnburned F/A mixture,a normal shock will develop.1D closed end tube explanation:Build up of temperature and pressureAccelerating the flame frontTP(F/A)unburnedCombustionproducts
50DDT – Deflagration to Detonation Normal Shock RelationsWe know from these relations that as the F/A mixture crosses the shock, it’s pressure is increased (compressed) and the temperature is increased:TxPxMxTyPyMyTP
51DDT – Deflagration to Detonation TxPxMxTyPyMyTPAs the mixture crosses the shock itis compressed, heated andautoignited, fueling the detonation.
53PDE – Pulsed Detonation Engines Pulsed detonation engines operate on the principle of DDT.The ‘pulse’ comes from the detonation chamber having to be cleared, and the F/A mixture renewed, after each detonation.Theoretically can operate from subsonic fight to roughly Mach 5.PDE thermal efficiency > turbofans/turbojets.Compressors/turbines are not necessary, weight
54PDE Schematic Pulsed Detonation Research Facility in the Air Force Research Laboratory at WPAFB Schelkin-type spirals to accelerate flame speed through turbulence and flame mixing  to achieve DDT.
55PDE - FlightThe AFRL developed and flew the Long E-Z aircraft in a low speed (120 mph) low altitude flight ( feet) producing 200 lbf thrust.
56Why not in practical use? - PDE Engine pulses need to operate ≈ 1000 Hz.Requires extremely fast and efficient mixing.Integration of the inlet and nozzle.Bulk of research done with gaseous fuels (C1-C3) which are easier to detonate.
57Focus of Study Fire/Combustion Hydrocarbon Deflagrations Hydrocarbon DetonationsShort Intro to Detonations of High ExplosivesHow to prevent explosions
58Additional Detonation Info High Explosives Most true high explosives contain the oxygen they need for burning.For instance, the chemical formula for nitroglycerin is:C3H5(ONO2)3Dynamite = sawdust + nitroglycerin!Detonation of nitroglycerin can propel a shock at 30 times the speed of sound in air and produce temperatures as high as 9030°F. 
59Additional Detonation Info TNT Equivalence Common method for equating a known energy of a combustible fuel to an equivalent mass of TNT:mTNT = equivalent mass of TNT (mass)η = empirical explosion efficiency (unitless)m = mass of hydrocarbon (mass)ΔHc = energy of explosion of flammable gas (energy/mass)ETNT = energy of explosion of TNT (energy/mass)
60Additional Detonation Info Nuclear (Fission) Bombs  One particular type of nuclear weapon is a nuclear fission bomb.Fission bombs are created by induced fission.These free neutrons are used to set off a massive chain of fission reactions.
61Additional Detonation Info Nuclear (Fission) Bombs ‘Little Boy’, the bomb dropped on Hiroshima, was this type of nuclear weapon. It produced an explosion equivalent to 14,500 tons of TNT, at an efficiency of 1.5%...That means that only 1.5% of the material was fissioned before being carried away by the explosion. 
62Additional Explosion Info Vapor Cloud Explosions (VCE) Vapor cloud explosions usually occur through a series of stepsSudden release of a large quantity of flammable vaporDispersion of mixture throughout building/plant/environment while mixing with air.Ignition of the vapor cloud
63Additional Explosion Info Flixborough, England Disaster (VCE) 
64Additional Explosion Info Flixborough, England Disaster (VCE) On June 1, 1974 a VCE destroyed a chemical plant in Flixborough, England killing 28 people and injuring 36 more.The plant produced caprolactum, a chemical precursor to nylon, through the process of oxidizing cyclohexane with air through a series of 6 reactors.2 months prior to the explosion, a crack was discovered in reactor 5. The company rerouted the the piping with a temporary bypass so that the plant could still produce, until the crack was properly fixed.This bypass pipe ruptured, spewing 40 tons of cyclohexane into the plant creating a vapor cloud, meters in diameter.The VC was likely ignited by a nearby furnace and the explosion leveled the plant, damaging over 1800 buildings within a 1 mile radius.The explosion was estimated to be of 15 ton TNT equivalence.
65Focus of Study Fire/Combustion Hydrocarbon Deflagrations Hydrocarbon DetonationsShort Intro to Detonations of High ExplosivesHow to prevent explosions
66Methods for Preventing Explosions – Inerting Reducing the oxygen concentration is an effective way to prevent explosions.Below the described oxygen concentration, the reaction cannot generate enough energy to heat the unburned gases adequately.Concentration of fuel doesn’t matter when [O2] too low!Strongly dependent upon the inert gas species (nitrogen in this case)
67Limiting Oxygen Concentration (LOC) Depends on inert speciesLOC for each fuel
68Methods for Preventing Explosions – Inerting Inerting begins initial purge of the empty vessel with inert gas to safe [O2] level:Generally ‘safe’ is considered 4% below the LOC (for example 6% if the LOC is 10% for a particular fuel).Then the flammable material is added to the vessel.
69Methods for Preventing Explosions – Inerting An inerting system is required to maintain the safe oxygen concentration once the fuel is under use.
70Methods for Preventing Explosions – Static Electricity A static charge is the result of physically separating a poor conductor from a good conductor or another poor conductor.When different materials come into contact, electrons move across the interface from one surface to another.
71Methods for Preventing Explosions – Static Electricity Physically separating two good conductors?Physically separating good/poor or poor/poor conductors?Electrostatic build-up!
72Methods for Preventing Explosions – Static Electricity Common producers of static electricity:Pumping nonconductive fluid through a pipe, mixing immiscible liquids, pneumatically conveying solids, and leaking steam that contacts an ungrounded conductor, etc.A charge on the order of 0.1 mJ is considered dangerous.Static build up of walking across a carpet averages roughly 20 mJ.
73Methods for Preventing Explosions – Static Electricity An electrostatic discharge occurs when two materials at different potentials come close enough to produce a charge transfer.This transfer can be energetic enough to be an ignition source.
74How charge accumulates Contact and frictional charging: two materials, one being an insulator, are brought into contact and a charge separation occurs at the interface. If the two objects are then separated, some of the charges are separated, giving the two materials equal but opposite charges.
75How charge accumulates Double-layer charging: charge separation occurs on a microscopic scale in a liquid at any interface (solid-liquid, gas-liquid, or liquid-liquid)… As the liquid flows, it carries a charge and it leaves a charge of opposite sign on the other surface, for example a pipe wall.
76How charge accumulates 3. Induction: electrons migrate towards the opposite charge on opposing side of a vessel, thus accumulating an equal quantity of charge on the opposite side of the body. This leaves the other part of the vessel charged by induction.
77How charge accumulates 4.Charging by transport: when charged liquid droplets or solid particles settle on an isolated object, the object is charged. The transferred charge is a function of the objects capacitance and of the conductivities of the droplet or particle and interface.
78How electricity discharges A charged object can discharge to a ground or an oppositely charged object when the field intensity between the two exceeds 3 MV/m (breakdown voltage of air), or when the surface reaches a maximum charge density of 2.7 x 10-5 C/m2.
79How electricity discharges Electricity may discharge by any one of these methods, each of which produce enough energy to ignite common HC fuels:SparkPropagating brushConical pile (Maurer discharge)BrushLightning-likeCorona discharges
80Preventing discharges by type Sparks – prevented by grounding and bonding. Prevents two metallic objects from having different potentials. Conical Pile Discharges – prevented by keeping nonconductive surfaces or coatings thin enough or conductive enough such that it has a breakdown voltage below 4 kV. Lightning-like Discharges – prevented by keeping the vessel volume less than 60 m3 or the vessel diameter less than 3 m.
81Preventing electrostatic ignitions Prevent charges from accumulating to dangerous levelsInclude charge reductions by means of low energy dischargesWhen dangerous discharges cannot be eliminated, then an inertant must be used to prevent explosions.
82Preventing electrostatic ignitions Relaxation: pumping fluid through a pipe into a vessel, the separation process produces a streaming current, which is the basis for charge buildup in this situation. Add in enlarged section of pipe before expansion into vessel.
83Preventing electrostatic ignitions Bonding and Grounding: the voltage difference between two conductive materials is reduced to zero by bonding them together. Eliminate all voltage difference between sets of bonded materials by bonding all to ground!
84Methods for Preventing Explosions – Sprinklers Can help absorb heat, preventing explosion from growing/gaining energy.Can help ‘knock down’ gas clouds.Many different types of systems
85Summary Deflagration Detonation Subsonic combustion, driven by thermal diffusion of heat and mass.Speeds typically well below 100 m/sMain danger comes from thermal damage.Standard combustion reaction, travelling at accelerated rate.Can transition to detonation under certain conditions. Often times this is how a HC fuel will detonate.DetonationSupersonic combustion, led by a shock wave.Speeds can be in excess of 2000 m/s (5-7 times speed of sound).Main danger from overpressureShock compresses F/A mixture. prior to reaction zone, causing it to autoignite as it crosses the shock wave, vigorously fueling the reaction.Strength quickly dies down as distance from the blast is increased.Type of explosion produced from high explosives and nuclear weapons.
86Resources Lilley, D., Some Fundamentals of Explosions. 51st AIAA Aerospace Sciences Meeting including the New Horizons Forum and Aerospace Exposition. AIAA  Eidelman, S., Burcat, A., Evolution of a Detonation Wave in a Cloud of Fuel Droplets: Part I. Influence of Ignition Explosion. AIAA Journal. Vol. 18 No. 9 September  McIntosh, A., Influence of Pressure Waves on the Initial Development of An Explosion Kernel. AIAA Journal. Vol. 33 No. 9 September  Kogarko, S., Adushkin, V., Lyamin, A., Investigation of Spherical Detonation of Gas Mixtures. Combustion, Explosions, and Shock Waves. Vol. 1 No  Fletcher, R., Liquid-Propellant Explosions. AIAA Journal of Spacecraft and Rockets. October 1968,  Jeng, S.M. Gas Turbine Combustion Lecture Notes, Spring  Turns, S An Introduction to Combustion: Concepts and Applications. 3rd Edition. McGraw-Hill 
87Resources Cont. Crowl, D., Louvar, J., Chemical Process Safety Fundamentals and Applications. 3rd Edition. Prentice-Hall.  National Fire Protection Association, Guide for Venting of Deflagrations. Quincy, Mass. American National Standards Institute.  Clancey, V.J., Flammability Limits and Burning Velocities of Ammonia/Nitric Oxide Mixtures.  2/20/13.  2/20/13.  2/20/13.  Cheetham, B. W. Speed of Vertical Pre-mixed Laminar Flame in Varying Propane-air Mixture.  Kumar, K., Sung, C.J, Combustion Data for Jet-A, its Constituent Components, and Surrogate Mixtures. Multi-Agency Coordination Committee for Combustion Research – 2009 Fuels Summit. Sept. 17, 2009.
88Resources Cont. Klimov, A. M., “Premixed Turbulent Flames – Interplay of Hydrodynamic and Chemical Phenomena”, in Flames, Lasers, and Reactive Systems (J. R. Bowen, N. Manson, A. K. Oppenheim, and R. I. Soloukhin, eds.), Progress in Astronautics and Aeronautics. Vol. 88, American Institute of Aeronautics and Astronautics, New York, pp. 133 –  Disimile, P., Aviation Fire Dynamics, Lecture Notes C3, Feb    Disimile, P., Aviation Fire Dynamics, Lecture Notes 4B, Feb   
89Resources Cont.     Schauer, F.R., Miser, C.L., Tucker, K.C., Bradley, R.P., Hoke, J.L., Detonation Initiation of Hydrocarbon-Air Mixtures in a Pulse Detonated Engine. 43rd AIAA Aerospace Sciences Meeting, Jan ,    Shapiro, A.H., The Dynamics and Thermodynamics of Compressible Fluid Flow. Volume 1.