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Chapter 6: The States of Matter Suggested Problems:

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States of Matter ______ –Definite volume and shape ______ –Definite volume but not shape Takes the shape of its container _______ –No definite volume or shape Will not only take the shape of its container it will fill it completely

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Solids A __________ state of matter Atoms (or molecules) are “touching” Strongest intermolecular forces –Hold atoms (or molecules or ions, etc.) rigidly in a 3D crystalline lattice

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Liquids Also a __________ state of matter Atoms (or molecules) are “touching” Intermolecular forces hold atoms (or molecules) in contact, but not rigidly in place…molecules can slide past each other

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Gases Virtually ___ intermolecular forces Gaseous molecules (etc.) comprise a very small percent of the sample volume Gaseous molecules are in constant random motion…the velocity is related to temperature Molecules collide with walls of container and with each other and bounce off with no loss of energy

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Properties of Gases Gases are the best understood state of matter, because we ignore intermolecular forces The volume a gas sample occupies is a function of three variables: –___________

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Pressure Pressure is force per unit area Units of pressure: –Pounds per square inch –Torr or mmHg –Atmosphere 1 atm = 760 torr = 760 mmHg = 14.7 psi

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Measuring Pressure: Barometer air pushing down gravity pulling down

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Pressure Conversion Example The gauge on an oxygen gas cylinder reads 1272 psi. Express this in atm and torr. (1 atm=14.7 psi)

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Volume of a Gas Imagine a fixed amount of air at a given temperature and pressure in a balloon What will happen to the volume if we add more air?

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Volume of a Gas Imagine a fixed amount of air at a given temperature and pressure in a balloon What will happen to the volume if we squeeze the balloon (increase pressure)?

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Volume of a Gas Imagine a fixed amount of air at a given temperature and pressure in a balloon What will happen to the volume if we increase the temperature?

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The Combined Gas Law P is pressure V is volume T is ________ temperature n is number of moles

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The Empirical Gas Laws Boyle’s Law –Volume is inversely proportional to pressure (constant n and T) Charles’s Law –Volume is directly proportional to the Kelvin temperature (constant n and P) Avogadro’s Law –The volume of a gas is directly proportional to the number of gas moles (constant T and P)

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Boyle’s Law: Example 15 liters of argon is collected at an initial pressure of 1.05 atm. If the gas is compressed to a new pressure of 1510 torr, what is the new volume?

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Charles’s Law: Example The temperature of 35.6 mL of neon is increased from –35.4ºC to 75.2ºC. What is the new volume?

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Combining Boyle’s and Charles's Laws A bubble of air having a volume of 75.0 mL is released from 35 feet under the sea (where the pressure is 2.07 atm and the temperature is 18 ºC). What will the new volume be at the surface, where P=0.967 atm and T=23 ºC?

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The Ideal Gas Law Combines the elements of the ________ gas laws

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Standard Conditions STP = standard temperature and pressure T = _____ K (_____ ºC) P = _____ atm = ____ torr

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Example What volume will 2.0 grams of helium occupy at a temperature of 290K and a pressure of 800 torr?

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Which Gas Law to Use? Use the combined gas law when the problem describes two sets of conditions –the pressure and/or temperature changes Use the ideal gas law when there are a single set of conditions

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Empty container Oxygen 0.25 atm Nitrogen 0.75 atm Dalton’s Law of Partial Pressures The ______ pressure of a gaseous mixture is the sum of the partial pressures Nitrogen 0.75 atm Oxygen 0.25 atm P total =

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Graham’s Law __________ is net movement of a gas from an area of high concentration (pressure) to an area of lower concentration __________ is the movement of a gas through a pinhole Both Diffusion and Effusion follow Graham’s Law Rate is an amount per time

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Graham’s Law Example Oxygen Molecules weigh 16 times as much as hydrogen molecules. Which molecule will diffuse faster and how much faster?

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Changes of State Gas Liquid Solid freeze melt condense sublime vaporize condense What do all of these changes in state have in common?

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Energy Energy is the ability to do work –Kinetic Energy: energy due to motion –_________ Energy: stored energy –Heat Energy: the sum of the kinetic and potential energies of molecules in a sample

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Energy and Its Units calorie (cal): is the amount of heat needed to raise the temperature of 1 gram of water by 1 degree Celsius at 15 o C kilocalorie = 1000 cal A food Calorie = 1000 cal Joules (J): are the metric unit of energy 1 cal = J

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Energy Conversion Example A candy bar has 350 Calories. How many joules does one candy bar contain?

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Heat and Temperature __________: is a measurement of the average kinetic energy of the molecules in a sample –___ is measured in degrees with a thermometer _______: is the sum of the kinetic (and potential) energies in a sample –_____ is measured in calories with a calorimeter

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Calorimeters Bomb Calorimeter Coffee Cup Calorimeter

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Specific Heat Specific heat (SH) is the amount of heat needed to raise the temperature of 1 gram of material by one degree Celsius

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Specific Heat Example A 10.0 gram sample of copper at 25 ºC has a final temperature of 100 ºC when 289 J of heat are added. What is the specific heat of copper? (SH of liq water = 4.18 J/g o C)

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Distribution of Energy In a sample of material, the kinetic energies of the molecules follow a Boltzman Distribution: Kinetic Energy # Molecules Average KE

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Kinetic Energy Distribution Kinetic Energy # Molecules T high T low

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Changes of State Gas Liquid Solid freeze melt condense sublime vaporize condense

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Vaporization The most energetic molecules in a liquid have sufficient kinetic energy to escape into the ____ phase Once the molecules are free as gases, they exert a pressure –This is called the ______ pressure How does vapor pressure depend on temperature?

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Vapor Pressure of Water and Ethanol

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Boiling Point The boiling point of a liquid is the temperature where the vapor pressure equals the ambient pressure. The _______ boiling point of a liquid is the temperature where the vapor pressure equals 760 torr. How does boiling point depend on pressure?

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Changes of State Gas Liquid Solid freeze melt condense sublime vaporize condense What do all of these changes in state have in common?

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Freezing/Melting Point The melting point of a substance is the temperature at which a crystalline solid changes to a liquid. What is the difference between melting point and freezing point?

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Energy Changes and Changes of State Imagine recording the temperature of an 18 gram (i.e., 1.0 mole) sample of ice at -40ºC as heat is added No T heat added, kJtemperature

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Heating Curve for 1 Mole of Water Water is boiling: Heat of vaporization 40.7 kJ/mol Ice is melting: Heat of fusion 6.02 kJ/mol

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Molar Heat of Fusion Hº fus is the heat required to convert one mole of solid to a liquid at at its normal melting point Hº fus represents the energy needed to break down intermolecular forces and allow molecules to slide around the liquid phase

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Molar Heat of Vaporization H° vap is the heat required to convert one mole of liquid to a gas at at its normal boiling point H° vap represents the energy needed to break intermolecular forces and allow molecules to escape into the gas phase

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Putting it all Together How much heat is required to convert an 18 gram piece of ice at -40 o C to steam at 120 o C?

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Heating Curve for 1 Mole of Water Heat of fusion 6.02 kJ/mol Heat of vaporization 40.7 kJ/mol A B C D E SH ice = 2.1 J/g o C SH liq = 4.18 J/g o C SH gas = 2.0 J/g o C q = m(SH)( T)

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Question Explain why orange growers spray their trees with water when there is a threat of freezing temperatures.

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Question Why does steam at 100ºC cause more severe burns than water at the same temperature?

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