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HangZhou JLS Flame Retardants Chemical Co.,Ltd. Professional Flame Retardants.

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Presentation on theme: "HangZhou JLS Flame Retardants Chemical Co.,Ltd. Professional Flame Retardants."— Presentation transcript:

1 HangZhou JLS Flame Retardants Chemical Co.,Ltd. Professional Flame Retardants

2 Introduction HangZhou JLS Flame Retardants Chemical Co.,Ltd. is a special corporation for exploring and manufacturing non-halogenated flame retardants. We have explored a series of products to meet halogen free requirement. We are world leader in range of ammonium polyphosphate, non- halogenated flame retardants in polyolefine and melamine derivates. Our tenet : QUALITY, INNOVATION, SERVICE

3 Advantages of JLS  Lower smoke,no halogen, environment friendly  Varied series of products,broad Application  Excellent water-proof,aging stability and low migration  Excellent process property  More attractive price/performance

4 JLS Products Catalogue JLS-MC Series JLS-MC Series — Melamine Cyanurate Flame Retardant JLS-PNA JLS-PNA — Non-Halogen Flame Retardant for Polyamide

5 JLS-MC JLS-MC25 JLS-MC15 JLS-MC810 JLS-MC series Melamine Cyanurate JLS-MC50

6 JLS-MC :Melamine Cyanurate CAS No:37640-57-6 EINECS:2535757 MCA content Excess melamine Excess Cyanurate D 50 D 98 Treating method JLS-MC15≥99.5 %≤0.3 %≤0.2 %≈3μm15 μmNo JLS-MC25≥99.5 %≤0.3 %≤0.2 %≈4μm25 μmNo JLS-MC50≥99.5 %≤0.3 %≤0.2 %≈5μm50 μmNo JLS-MC810≥98.5 %≤0.3 %≤0.2 %≈4μm25 μm surface coating JLS-MC Character

7 JLS-MC series Advantages ◆ Higher bulk density to reduce floating dust and increase mix uniformity. ◆ Excellent particle distributing to ensure Nylon with JLS-MC better mechanism and a smoother surface. ◆ Well mixing with Nylon resin,so is easier to disperse during processing. ◆ JLS-MC810 has even higher disperse property,which ensure Nylon a better mechanical property. ◆ JLS-MC15, MC25 and MC50 is different diameter, which can suitable for different need. ◆ The Nylon which contain JLS-MC is better than Br/Sb system in electricity isolation capability , it can be used widely in low piezoelectricity applications.


9 JLS-MC laser diameter distribution Contrast VolumeJLS-MC DSM- MC Ordinary MCA % Particle Diameter , µ m D 10 0.2320.2770.217 D 25 0.7901.1310.614 D 50 3.9813.9761.962 D 75 9.86610.703.308 D 90 17.4719.544.632 Average diameter 2.7713.0831.368

10 JLS-MC series laser diameter Contrast Volume JLS- MC15 JLS- MC25 JLS- MC50 D 10 0.4720.4900.458 D 25 0.9621.2461.477 D 50 2.0833.5065.564 D 75 4.4128.42413.090 D 90 7.31114.66020.860 D 98 11.23120.01032.870 Average diameter 1.8512.9894.031

11 JLS-MC and Melapur MC laser diameter Contrast

12 JLS-MC15 and Melapur MC15 laser diameter Contrast VolumeJLS-MC15 Melapur MC15 D 10 0.4720.429 D 25 0.9620.961 D 50 2.0832.345 D 75 4.4125.106 D 90 7.3118.028 D 98 11.23111.813 Average diameter 1.8512.059

13 JLS-MC series Applications JLS-MC series consists of JLS-MC15, MC25, MC50 and JLS- MC810 based on JLS-MC, which is mostly used in Nylon. The series can also be used in a range of polyesters. PC,thermoplastic polyurethane Thermosets including epoxy resins, unsaturated polyesters and polyurethane foams.

14 JLS-MC FR Mechanisms contrast FR - mechanism Melamine- derivatives Halogen / Sb 2 O 3 ATH/Mg(OH) 2 Inert Gases√√√ Heat sink√√√ Char formation√√√ Intumescence√ Heat Insulation√ Heat transfer(dripping)√

15 JLS-MC FR Mechanism in PA Advantages l Salt Degradation: T > 300 o C l Heat Sink: Endothermic decomposition to M and CA l Inert Gas Source: (M): Dilution of oxygen and fuel gases l Non-burning dripping (CA): Decrease of exposure to flame

16 JLS-MC for Nylon l PA6, 66 un-reinforced: UL 94 V-0 at 6~12 wt%, PA6 need more addition than PA66 l PA6, 66 mineral filled: UL 94 V-0 at 13~15 wt.% l PA6, 66 glass fiber reinforced: 10~15% glass fiber, 15% MC Properties: UL 94 V-2, Glow wire 960 o C, CTI > 500 Volt

17 JLS-MC Properties in Nylon66 ItemUnits Bromine Antimony JLS-MC Ordinary MCA Tensile StrengthMPa758082 Elongation at break% Flexural StrengthMPa100125115 Flexural ModulusGPa33.94.5 Charpy Impact-NotchedKJ/m 2 48-104 Flame test (0.8mm)UL94V0 V2 Smoke Density firing790190 No-firing39080 CTIV350>550

18 JLS-MC used in Nylon contain of Glass fiber Contain: 10% glass fiber, 10%~15%JLS-MC ItemUnit Flame resistance PA6PA6 basis Standard Fire test0.8mm UL 94 V-2 no UL 94-1996 Izod impact strengthJ/m 10.28 8-10 ISO 179-1982 Flexural StrengthMpa 68.4 69 ASTM D790-00 Flexural ModulusMpa 2100 1800 Tensile StrengthMpa 58.46 56.38 ASTM D638-99 Elongation at break% 33.8~51 34.5

19 JLS-MC processing instructions in Nylon Item1234567NOZZLE Temp, ℃ PA66 250260265 270 265255 PA6 230240250245240 235 Vacuum ≥-0.08Mpa ( recommend )

20 JLS-PNA JLS-PNA is a non-halogenated and phosphorus/nitrogen flame retardant. It may be used in Nylon modified glass fiber. It is melamine polyphosphate.

21 JLS-PNA SPECIFICATIONS Phosphorus % ( m/m ) 16-18 Thermal decomposition ℃ ≥350 Water content% ≤0.5 Average particle size µm ≤25 JLS-PNA: Melamine Polyphosphate CAS No:218768-84-4

22 ◆ Non-halogenated, lower smoke density and toxic ◆ Good processing capability , no need especial screw combination and especial specs glass fiber ◆ Excellent thermal stability, thermal decomposition≥350 ℃, very suitable for modified glass fiber Nylon ◆ White color , easy to make all kinds of colors ◆ Excellent electricity capability , CTI>450V , very suitable for E&E applications,no recycle problem JLS-PNA Advantages

23 Mostly used in glass fiber modified PA66 and PA6, which is suitable for processing of sorts,for example extrusion and injection moulding. The compound consisted of JLS-PNA, glass fiber and Nylon provided with excellent flame resistance and mechanical performance JLS -PNA APPLICATIONS

24 JLS-PNA Laser Diameter Volume , % Particle Diameter , µm D 10 0.412 D 25 3.134 D 50 6.758 D 75 11.25 D 90 15.47 Average diameter 4.470

25 JLS-PNA Application in PA66 Item Additive percent ( %wt ) PA66 ( A3K ) 50-55 Glassing fiber 25 JLS-PNA20-25 fire test ( UL 94 ) UL94 : V-0 Mechanical properties Tensile strength , Mpa 95.7 Flexural Strength , Mpa 175.0 Flexural Modulus , Mpa 8400 Notched impact strength , J/m 45.0 Charpy impact Strength,no notched , KJ/m 2 15.4 Heat transition ,℃( 0.45Mpa ) 220 Hardness, Rockwell 120

26 PNA processing instructions in Nylon66 modified glass fiber Item1234567Nozzle Temp ℃ 250260270265 255245270 Vacuum <-0.06Mpa ( recommend ) Screw speed 150-180rpm is suitable

27 Thanks for attention

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