2Chocolate Chip Cookies!! 1 cup butter1/2 cup white sugar1 cup packed brown sugar1 teaspoon vanilla extract2 eggs2 1/2 cups all-purpose flour1 teaspoon baking soda1 teaspoon salt2 cups semisweet chocolate chipsMakes 3 dozen2 EggsHow many eggs are needed to make 3 dozen cookies?How much butter is needed for the amount of chocolate chips used?How many eggs would we need to make 9 dozen cookies?1 Cup6 Eggs
3Cookies and Chemistry…Huh!?!? Just like chocolate chip cookies have recipes, chemists have recipes as wellInstead of calling them recipes, we call them chemical equationsFurthermore, instead of using cups and teaspoons, we use moles to measure amountsLastly, instead of eggs, butter, sugar, etc… we use chemical compounds as ingredients
4The Math of Chemical Equations StoichiometryThe Math of Chemical Equations
5Just what is stoichiometry? The word stoichiometry is derived from two Greek words: stoicheion (meaning element) and metron (meaning measure).
6Jeremias Benjamin Richter ( ) was the first to lay down the principles of stoichiometry. In 1792 he wrote: “Stoichiometry is the science of measuring the quantitative proportions or mass ratios in which chemical elements stand to one another.”This was verified by Antoine Lavoisier with the Law of Conservation of Mass
7When do we use stoichiometry? Whenever chemists want to know how much of a desired product will be produced.Chemists always start with a balanced equation.
8How does it work?The chemist uses the balanced equation to guide them in calculating the maximum amount of products.Since stoichiometry is used to predict things in a “perfect world”, we can expect that the reaction in the lab won’t create the maximum amount of product that was calculated.
9How do I use the chemical equation? Looking at a chemical equation tells us how much of something you need to react with something else to get a product (like the cookie recipe)The chemical equation is written like a mathematical expression.When balanced, the coefficients tell how many moles of each reactant or product is needed or expected.
10The important thing is that the equation must be BALANCED!!!!
11Example:2H2 + O2 2H2OOne way to understand the information conveyed by a chemical equation is to convert the equation into an English sentence.
122H2(g) + O2(g) 2H2O(l)2 “parts” hydrogen gas reacts with one “part” oxygen gas to form 2 “parts” liquid water.Now, we can get a bunch of relationships – the “parts” could be: molecules, atoms, moles, or masses(the coefficients tell how many moles, atoms or molecules of each chemical are needed in the “recipe”)The most important relationship for stoichiometry is the MOLE relationship!
13What is a mole ratio? Mole Ratios: The mole ratio is based on the balanced chemical equation.You will use the coefficients to get the mole ratio between two DIFFERENT substancesThese ratios will be used as conversion factors for stoichiometry problems.
14How do you use a mole ratio? The mole ratio is an equivalent which means that you can arrange the ratio in any way needed.The mole ratio is the KEY to calculations based upon a chemical equation.With it, you can calculate the amount of any other reactant in the equation and the maximum amount of product you can obtain.
15Molar RatiosThe expressing the ratio of moles in an equation using the coefficientsEx. 2H2 + O2 2H2OWhat is the mole ratio between H2 and O2?What other mole ratios can we come up with?
16Warning:The coefficients of a reaction only give the ratio in which substances react and form.They DO NOT directly tell you, HOW MUCH MASS is reacting.You will need to convert from moles to mass using molar mass as the conversion factor.
17Example of a mole ratio problem: N2 + 3H2 2NH3Write the mole ratios for N2 and H2Write the mole ratios for NH3 and H2
18Stoichiometry has 5 basic steps: Step 1: Write and balance the equation
19Step 2: Write down all information that you’re given (Make sure to identify what you are trying to find!)
20Step 3: Convert everything given into moles Step 3: Convert everything given into moles. (Use molar mass as the conversion factor if you have to.)
21Step 4: Use a mole ratio to solve for what you are trying to find Step 4: Use a mole ratio to solve for what you are trying to find. (Use the coefficients from the balanced chemical equation to get the correct mole ratio.)
22Step 5: Convert, if needed, everything into correct units Step 5: Convert, if needed, everything into correct units. (IF you need to get from moles to mass use the molar mass of the substance as the conversion factor.)
23Mole-to-Mole Stoichiometry One way to change ion ore, Fe2O3, into metallic iron is to heat it together with hydrogen:Fe2O3 + 3H2 2Fe + 3H2OHow many moles of iron are made from 25.0 moles of Fe2O3 reacting with excess hydrogen?
24Mole-to-Mole K: 25 moles Fe2O3 UK: ? moles Fe Use Dimensional Analysis :25 moles Fe2O3= 50. mol Fe
25More examples of mole-to-mole stoichiometry problems: 2H2 + O2 2H2O 1. How many moles of H2O are produced when 5.00 moles of oxygen are burned in excess hydrogen gas?10.0 mol H2O
26Examples of a mole-mole stoichiometric problem continued: 2H2 + O2 2H2O2. If 3.00 moles of H2O are produced, how many moles of oxygen must be consumed in a reaction with excess hydrogen gas?1.50 mol O2
27Examples of a mole-mole stoichiometric problem continued: 2H2 + O2 2H2O3. How many moles of hydrogen gas must be used, when reacting with 0.25 mol oxygen gas to create water.0.50 mol H2
28Mole-to-Mass Stoichiometry Most of the time in chemistry, the amounts are given in grams instead of molesWe STILL go through moles and use the mole ratio, but now we also use molar mass (as a conversion factor) to get to gramsExample: How many grams of chlorine are required to react completely with 5.00 moles of sodium to produce sodium chloride?2 Na + Cl2 2 NaCl5.00 moles Na= 177g Cl2
29PracticeCalculate the mass, in grams, of iodine required to react completely with 0.50 moles of aluminum to make aluminum iodide.2 Al + 3 I2 2 AlI3
30Mass-to-Mole Stoichiometry We can also start with mass and convert to moles of product or another reactantWe use molar mass and the mole ratio to get to moles of the compound of interestEX: Calculate the number of moles of ethane (C2H6) needed to produce 10.0 g of water2 C2H6 + 7 O2 4 CO2 + 6 H2010.0 g H2O 1 mol H2O 2 mol C2H618.0 g H2O 6 mol H20= mol C2H6
31PracticeCalculate how many moles of oxygen are required to make 10.0 g of aluminum oxide4 Al + 3 O2 2 Al2O3
32Mass-to-Mass Stoichiometry Most often we are given a starting mass and want to find out the mass of a product we will get (called theoretical yield) or how much of another reactant we need to completely react with it (no leftover ingredients!)
33We must go from grams to moles by using molar mass of the compound given Go from moles of compound given to moles of compound needed using the mole ratio from the coefficientsGo back to grams of compound we are interested in by using molar mass of the compound you are looking for
34Mass-to-Mass Stoichiometry Problems Ex: Calculate how many grams of ammonia are produced when you react 2.00g of nitrogen with excess hydrogen.N2 + 3 H2 2 NH3
35PracticeHow many grams of calcium nitride are produced when 2.00 g of calcium reacts with an excess of nitrogen?3 Ca + N2 Ca3N2
36Gas Stoichiometry (Volume-to-Volume) @ STP Figure out volume of gas given.Convert to moles using the fact that22.4 L=1 STPChange from moles of compound given to moles of new compound using molar ratio from the coefficients.Change moles of new compound to volume using 22.4 L = 1 mole
37Gases and Stoichiometry 2 H2O2 (g) 2 H2O (g) + O2 (g)3.5 L of H2O2 was decomposed in a flask. What is the volume of O2 made at STP?Bombardier beetle uses decomposition of hydrogen peroxide to defend itself.
38What if we are not just looking for a volume to volume calculation? See what the question is asking us and use appropriate conversion factors.For example, going back to:2 H2O2 (g) 2 H2O (g) + O2 (g)What if you wanted to know how many moles of water were formed from the decomposition of 0.25 L of H2O2 at STP?
39Another ExampleFind the number of grams of oxygen necessary for the combustion of 6.7 L of magnesium, assuming the reaction occurs at STP.2 Mg + O2 2 MgOAnswer: 4.8 g O2
41Limiting Reactant: Cookies 1 cup butter1/2 cup white sugar1 cup packed brown sugar1 teaspoon vanilla extract2 eggs2 1/2 cups all-purpose flour1 teaspoon baking soda1 teaspoon salt2 cups semisweet chocolate chipsMakes 3 dozenIf we had the specified amount of ingredients listed, could we make 4 dozen cookies?What if we had 6 eggs and twice as much of everything else, could we make 9 dozen cookies?What if we only had one egg, could we make 3 dozen cookies?
42Limiting ReactantMost of the time in chemistry we have more of one reactant than we need to completely use up other reactant.That reactant is said to be in excess (there is too much).The other reactant limits how much product we get. Once it runs out, the reaction s. This is called the limiting reactant.
43Limiting ReactantTo find the correct answer, we have to try all of the reactants. We have to calculate how much of a product we can get from each of the reactants to determine which reactant is the limiting one.The lower amount of a product is the correct answer.The reactant that makes the least amount of product is the limiting reactant. Once you determine the limiting reactant, you should ALWAYS start with it!Be sure to pick a product! You can’t compare to see which is greater and which is lower unless the product is the same!
44Limiting Reactant: Example 10.0g of aluminum reacts with 35.0 grams of chlorine gas to produce aluminum chloride. Which reactant is limiting, which is in excess, and how much product, in grams, is produced? 2 Al + 3 Cl2 2 AlCl3Start with Al:Now Cl2:10.0 g Al 1 mol Al mol AlCl g AlCl327.0 g Al mol Al mol AlCl3= 49.4g AlCl335.0g Cl mol Cl mol AlCl g AlCl371.0 g Cl mol Cl mol AlCl3= 43.9g AlCl3
45LR Example ContinuedWe get 49.4g of aluminum chloride from the given amount of aluminum, but only 43.9g of aluminum chloride from the given amount of chlorine. Therefore, chlorine is the limiting reactant. Once the 35.0g of chlorine is used up, the reaction comes to a complete
46Limiting Reactant Practice 15.0 g of potassium reacts with 15.0 g of iodine. Calculate which reactant is limiting and how much product is made.2K + I2 2KI
47From the previous question, how much of the excess reactant is left over?
48Percentage Yield = Actual Yield Percent YieldTheoretical Yield: The maximum quantity of product that can be obtained, according to the reaction stoichiometry, from a given quantity of reactantActual Yield: The quantity of product actually obtained from experimentationPercentage Yield = Actual YieldTheoretical yieldX100%
49What if I get an answer over 100%? Percent yield can NEVER be over 100%This would conflict with the Law of Conservation of MatterIf you obtain a yield over 100% you either:A. Did your calculation incorrectly by putting theoretical yield over percent yield ORB. Made a mistake in the experiment
50Percent yield problems: We calculated that 19.6g of KI forms from 15.0g K and 15.0g of I2.If we ran the experiment and only obtained 18.5g of KI what is the percent yield?
51Limiting Reactant & Percent Yield: Recap You can recognize a limiting reactant problem because there is MORE THAN ONE GIVEN AMOUNT.Convert ALL of the reactants to the SAME product (pick any product you choose.)The lowest answer is the correct answer.The reactant that gave you the lowest answer is the LIMITING REACTANT.The other reactant(s) are in EXCESS.To find the percent yield, divide the mass of what you get from the experiment from mass of the product from the limiting reactant and multiply by 100%.