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ULTRA BIOCID Technical Presentation. Purpose/Description z Ultra Biocid is used for the lowering of pH in chemical treatment solutions. z Ultra Biocid.

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Presentation on theme: "ULTRA BIOCID Technical Presentation. Purpose/Description z Ultra Biocid is used for the lowering of pH in chemical treatment solutions. z Ultra Biocid."— Presentation transcript:

1 ULTRA BIOCID Technical Presentation

2 Purpose/Description z Ultra Biocid is used for the lowering of pH in chemical treatment solutions. z Ultra Biocid is clear, 100% water soluble product. zUltra Biocid is targeted to replace traditional organic and inorganic acids.

3 Advantages zEnvironmentally smart: Low BOD/COD when compared to acetic and other organic acids. Safe to handle (unlike mineral acids) No-Odor/ No VOC’s Strength of a strong acid without safety concerns. Cost effective vs total cost of using other acids. No heating upon dilution (unlike other strong acids).

4 Technical Specifications Ultra Biocid Normality16.31 Density (g/ml)1.53 pH<1.0 Freezing Point<-10C

5 MSDS Highlights zNFPA: Fire 0; Health 2; Reactivity 2 zHMIS:Fire 0; Health 2; Reactivity 0 Toxicological Information: Eye Irritation: May Be Irritating Skin Irritation: Non Corrosive To Skin DOT Non-Regulated

6 Competitive products: basic acids StrengthCODBODVolatilityOdorDOT Acetic AcidGlacial HighStrongcorrosive/Flammable Acetic Acid Highstrongcorrosive/Flammable Sulfuric Acid9800LowStrongcorrosive Sulfamic Acid *Lownonecorrosive Citric Acid LownoneNot Regulated Phosphoric Acid10000Lownonecorrosive Formic Acid *LowStrongcorrosive Oxalic Acid *LownoneNot Regulated Ultra Biocid NonenoneNot Regulated

7 Strength titration data vs. other acids

8 Titrations

9 Titrations: Ultra Biocid(Adjusted strength to equal 56% acetic acid)

10 Uses zSome examples of Uses are: yPre-treatment bath pH adjustment yAfter-treatment bath pH adjustment yWaste stream pH adjustment yBleach neutralization (souring) yMetals Manufacturing ySubstitution for most Industrial mineral Acids yMany more......

11 Environmental zUltra Biocid does not contain any chemicals currently on the EPA’s Extremely Hazardous Substance List or the Toxic Chemicals List, Sara Title III section 302 or 313. zIt is EPA Section 304,311 and 312 regulated because the pH is less than 2.0.

12 Storage zUltra Biocid can be stored in 316 stainless steel, high density polyethylene or polypropylene containers. zUCI International Inc. has been using the same tanker (316 stainless) and pipelines for over 7 years with Ultra Biocid and have had NO corrosion problems.

13 Shipping z Ultra Biocid is NOT regulated by any of the following Transportation agencies: yD.O.T. yI.A.T.A. yI.M.D.G. yT.D.G zFor Air Transportation: D.O.T. Regulates as ORM-B, NOS; NA1760

14 Conclusion z Ultra Biocid ‘s pH adjustment chemistry can provide a cost effective alternative to traditional organic and mineral acids. While improving overall safety of the workplace, employees and the environment.

15 ULTRA BIOCID-GENERAL CHARACTERISTICS zSAFETY 1- VERY SAFE PRODUCT WHICH HAS NO ODOR, FUMES OR VAPOR PRESSURE 2- NO AFFINITY FOR HUMAN FLESH- WILL CAUSE NO BURNS OR BLISTERING- SEE DERMAL IRRITATION TESTS 3- EASY STORAGE; REQUIRES NO SPECIAL HANDLING OR CONTAINERS 4- NO FUMES MEANS NO CORROSION WHEN USED AT AMBIENT TEMPERATURES- SEE METAL CORROSION TESTS 5- NO MUTAGENICITY- SEE AMES ASSAY 6- NON TOXIC-LD mg/kg(RATS, ORAL) 7- NO HEAT LIBERATION UPON DILUTION

16 ULTRA BIOCID- GENERAL CHARACTERISTICS zENVIRONMENTAL 1- VERY LOW BOD/COD- MUCH LOWER THAN ACETIC AND CITRIC ACID 2- CONTAINS NO PHOSPHATES, CHLORIDES, ETC. 3- NOT KNOWN TO INCREASE WASTEWATER DISCHARGE LIMITS

17 ULTRA BIOCID- GENERAL CHARACTERISTICS zECONOMY 1- COMPETITIVE AGAINST MOST COMMONLY USED ACIDS 2- NEW US PATENTED TECHNOLOGY

18 NEUTRALIZATION OF CAUSTIC TREATED DENIM DENIM FABRIC SUBJECTED TO HIGH AMOUNTS OF CAUSTIC (NaOH 50%) WILL EXHIBIT FACE AND BATH pH’s OF APPROXIMATELY 12.0 – 13.0 AS THESE GOODS ARE PROCESSED ON A CONTINUOUS WASH RANGE, A WIDE ARRAY OF pH RANGES MAY BE ADJUSTED USING ULTRA BIOCID

19 NEUTRALIZATION OF CAUSTIC TREATED DENIM zPROCEDURE zINTO THE FIRST OR SECOND WASH BOX A CONTINUOUS FEED OF ULTRA BIOCID IS INTRODUCED PLUS WASH WATER WHICH IS ALLOWED TO OVERFLOW. THE AMOUNT OF ULTRA BIOCID ADDED IS DETERMINED BY THE DESIRED FABRIC FINISH pH REQUIRED, THE MACHINE SPEED AND TO A LESSER DEGREE THE FABRIC WEIGHT. AS AN EXAMPLE, MOST DENIM WILL REQUIRE AN ULTRA BIOCID ADJUSTED BATH pH OF APPROXIMATELY 1.5 – A MACHINE SPEED OF 60 – 80 YPM

20 NEUTRALIZATION OF CAUSTIC TREATED DENIM zPROCEDURE CONTINUED UNDER THESE OPERATING CONDITIONS, EXIT FABRIC FACE pH’S WILL EQUAL APPROXIMATELY 8.0 – 9.5 IN-PLANT ADJUSTMENTS OF THE ULTRA BIOCID FLOW RATE WILL ALLOW THE WASHER OPERATOR TO ACHIEVE ANY pH RANGE DESIRED BECAUSE ULTRA BIOCID HAS NO VAPOR PRESSURE, EXTREMELY STEADY AND LEVEL pH RANGES ARE POSSIBLE WHEN COMPARED TO OTHER ACID SOURCES

21 NEUTRALIZATION OF CAUSTIC TREATED DENIM zMAINTENANCE IT IS STRONGLY RECOMMENDED THAT ALL PROCESS EQUIPMENT BE CLEANED AND RINSED FREE OF ANY RESIDUAL ULTRA BIOCID AFTER PROCESS IS COMPLETE SO AS NOT TO ALLOW DRIED SALTS TO REMAIN ON EQUIPMENT. IF DRIED SALTS ARE EXPOSED TO HIGH TEMPERATURES OVER A SUSTAINED PERIOD OF TIME, THE POSSIBILITY OF CORROSION MAY OCCUR. SIMPLE CLEANING WITH WATER WILL ELIMINATE THIS POSSIBLE CONDITION SINCE THESE ACID SALTS WILL READILY DISSOLVE.

22 LABORATORY TESTING

23 BIOCID TESTING zDUE TO ULTRA BIOCID’S UNIQUE CHEMISTRY, SOME MINOR DIFFERENCES MAY BE NOTED DURING LAB EVALUATIONS zAS COMPARED TO ACETIC ACID, FOR EXAMPLE, ULTRA BIOCID’S BUFFER POINT IS APPROXIMATELY 2.0 AND ACETIC ACID IS APPROXIMATELY 3.8 zBECAUSE OF THE BUFFER DIFFERENCES, CUSTOMERS USUALLY ATTEMPT TO ADJUST ULTRA BIOCID BY ADDITIONAL STRENGTH CUTS WHICH WILL LEAD TO INCONSISTENT pH READINGS AND ERRONOUS RESULTS

24 BIOCID TESTING- CONTINUED zWE STRONGLY SUGGEST THAT THE AMOUNTS OF ULTRA BIOCID RECOMMENDED BE FOLLOWED IN ALL CASES AS IT WILL SAVE VALUABLE LAB TIME AND MINIMIZE MISTAKES zBIOCID’S LOWER BUFFER POINT WILL REACH EQUILIBRIUM VERY QUICKLY AS IT DISASSOCIATES WHICH WILL EQUATE THE ACID BEING TESTED zSEE CHART AND GRAPHS FOR ADDITIONAL ASSISTANCE zULTRA BIOCID IS EASILY BLENDED WITH WATER TO THE REQUIRED pH STRENGTHS WITH INCREDIBLE SAFETY AND EASE OF HANDLING

25 BIOCID DYEBATH pH ADJUSTMENTS

26 zBIOCID WILL READILY AND SAFELY ADJUST DYEBATH pH RANGES zBIOCID MAY BE USED ON ANY DYEING EQUIPMENT AND FOR ANY FIBER AND FIBER BLENDS zEXAMPLES OF DYE EQUIPMENT INCLUDE JETS, PACKAGE MACHINES, BECKS, BEAMS, HOSIERY MACHINES OF ALL TYPES, CONTINUOUS DYE RANGES, ETC. zBIOCID EXHIBITS NO UNUSUAL SPECTRA SHIFTS WHEN USED AS RECOMMENDED – NO DIFFERENCES IN DYE YIELDS NOTED. zSEE CHARTS FOR STRENGTH COMPARISONS OF VARIOUS ACIDS

27 BIOCID STRENGTH VS VARIOUS ACIDS

28 BIOCID STRENGTH VS VARIOUS ACIDS TABLE #1 z10 ml ACETIC ACID (GLACIAL) z10 ml ACETIC ACID (84%) z10 ml ACETIC ACID (70%) z10 ml ACETIC ACID (56%) z10 ml ACETIC ACID (20%) z10 ml FORMIC ACID z10 ml PHOSPHORIC ACID z10 ml SULFAMIC ACID (15%) z10 ml OXALIC ACID z10 ml CITRIC (50%) z10 ml SULFURIC ACID(70%) z 10 ml BIOCID z 7 ml BIOCID z 5 ml BIOCID z 4 ml BIOCID z 2 ml BIOCID z 10 ml BIOCID z 3 ml BIOCID z 11 ml BIOCID z 5 ml BIOCID z 11 ml BIOCID

29 BIOCID STRENGTH VS VARIOUS ACIDS zALL STRENGTH COMPARISONS ARE TO BE USED AS GENERAL GUIDES ONLY zLABORATORY TESTING IS SUGGESTED TO VERIFY COMPARISONS

30 BIOCID’S USE IN WASTEWATER

31 zULTRA BIOCID IS WIDELY USED TO TREAT PLANT AND MUNICIPAL WASTEWATER WHEN pH ADJUSTMENTS ARE REQUIRED zBECAUSE ULTRA BIOCID HAS VERY LOW BOD/COD REQUIREMENTS, AND CONTAINS NO PHOSPHATES, MANY CUSTOMERS USE BIOCID TO ASSIST IN THEIR WASTEWATER TREATMENT zBIOCID WILL REPLACE SULFURIC ACID AND ALSO CARBON DIOXIDE GAS zBIOCID IS NORMALLY ADDED AT THE LAST WASTEWATER DISCHARGE EXIT TO CONTROL pH AND BOD/COD


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