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Fiber Analysis Hair and Fiber 3.

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Presentation on theme: "Fiber Analysis Hair and Fiber 3."— Presentation transcript:

1 Fiber Analysis Hair and Fiber 3

2 Fiber Evidence Fiber Can be natural (plant or animal) or man-made
The smallest unit of a textile material that has a length many times greater than its diameter Can be spun with other fibers to form a yarn (rope) that can be woven or knitted to form a fabric Can be natural (plant or animal) or man-made Man-made fibers now account for over ½ of all textile production

3 Forensic Value Are considered class evidence
Are common trace evidence at a crime scene Can be characterized based on comparison of both physical and chemical properties

4 Fiber Classification Natural fibers are classified according to their origin Vegetable or cellulose Animal or protein Mineral Some natural fibers can be altered into artificial ones Cotton and rayon Rayon is chemically-altered cellulose

5 Chemical Alteration Note the differences between the cotton fiber (left) and rayon (right). Can you detect what happens in the chemical transformation process?

6 Fiber Evidence Important characteristics
Type and length of fiber Spinning method Fabric construction Above characteristics can greatly affect transfer of fibers and significance as evidence Can originate from more than clothing Furniture, upholstery, etc.

7 Fiber Evidence Significance
Based upon clear relationships between objects associated with crime Relative value of evidence can be based upon several factors Type of fiber Number of fibers Color or variation of color Location of fibers Number of different fibers Likelihood of transfer based on fiber construction

8 Fiber Evidence Useful in similar crimes to hairs
Since DNA is not found, often limited to class characteristics due to mass production Transfer usually found through physical contact Routinely found in vehicle accidents or on glass/screens

9 Animal Fibers Silk Technically a protein secretion
No longer found in nature Among the most expensive fibers Fibers are altered by changing diet of silkworm Does not resemble typical non-human hair Highly light reflective

10 Mineral Fibers Fiberglass Asbestos Artificially produced fiber
Natural fiber from the mineral serpentine

11 Plant Fibers Cotton Most common plant fiber
Virtually worthless as evidence if white If dyed, the dye is more valuable than the cotton Distinctive twisted, ribbon-like shape

12 Plant Fibers Flax Used to make linen
Distinctive lateral structures through fiber Can be expensive

13 Plant Fibers Ramie fiber, common in SE Asia Hemp fiber, the strongest natural fiber Plant fibers are based on the polymer cellulose, the chemical that forms the cell wall of plant cells Jute fiber, also common in Asia

14 Synthetic Fibers First introduced in 1911 (rayon) followed by nylon in 1939 Hundreds of names currently used for essentially the same artificial fibers Generally grouped into generic names Example: Polyester - Sold under 28 different names

15 Synthetic Fiber Chemistry
Based on polymers Long chain molecules Come in natural and man-made varieties Synthetic polymers were first produced in 1909 Originally discovered by accident When a glass rod was removed from contact with polymer, it stretched and stuck to the rod. It hardened when cooled and would stretch into long filaments

16 Synthetic Fiber Chemistry
Polymers Well known natural polymers Starch Cellulose - nature of polymer provided structure to plants Proteins - form animal hairs Well known man-made polymers Nylon Teflon Silicone Vulcanized rubber

17 Synthetic Fiber Chemistry
Man-made polymers Basic chemical substance of all artificial fibers Also include most paints, plastics, adhesives, rubbers Polymers are routinely formed from thousands of individual atoms Composed of repeating units called monomers that link like chains

18 Synthetic Fiber Chemistry
“Classic” polymer structure of the synthetic fiber nylon. Note the long chain of repeating atoms.

19 Synthetic Fibers In spite of common names, practically no two of the same type of fiber are manufactured the same way all the way through the production process Positive ID almost always involves microscopy and chemical analysis Three different scanning electron microscope images of nylon carpet fibers. Note clear structural differences at this magnification.

20 Synthetic Fiber Analysis
Identification and Comparison Color Based on introduced combinations of dyes Different dyes may identify manufacturer Diameter Typically very little variation due to precise machinery Cross section usually helpful as well Production characteristics Striations - almost always lengthwise “Pitting” - occurs from particles added to fiber to reduce shine Typical cross section of synthetic carpet fibers.

21 Synthetic Fiber Analysis
Production method can be single largest identifier Cross sections are exceptionally important Synthetic fibers are forced out of a nozzle when they are hot Holes of the nozzle are not always round

22 Synthetic Fiber Analysis
Burning Chemistry of fibers can cause fiber to burn in different ways Odor, color of flame, smoke and the appearance of the residue can also be an indicator Thermal decomposition Gently heating can break down polymers to basic monomers Chemical testing Solubility and decomposition

23 Synthetic Fiber Analysis
Chemical composition Most companies have different “formulas” for product Product “fingerprint” can be determined if chemicals are identified Require spectroscopy Fibers can also be melted down into crystals and then identified Light reflectance will be different for unique crystals Known as crystallography Common nylon (above) and rayon (below) fibers under polarized light

24 Synthetic Fiber Analysis
Spectroscopic analysis of two apparently identical red, cotton fibers. Note the clear chemical differences between the two dyes.

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