3Development of the Periodic Table History of the Periodic Table – By the end of the 1700’s, scientists had identified only 30 elements (ex. Cu, Ag, Au, H2, N2, O2, C).By the mid 1800’s, about 60 elements had been identified.Sept 1860 – chemists assembled at the First International Congress of Chemists in Germany to settle the controversial issues such as atomic mass. Standard values set for atomic mass and improved communication for research.
4Johann Dobereiner: 1817Organized the elements into sets of three with similar properties.He called these groups triads. The middle element is often the average of the other two.Ex) Cl – 35.5Br – 79.9I – 126.9CaAvg SrBa
6B. John Newlands: 1866Arranged elements in order of increasing atomic mass.Noticed repeating patterns in the elements’ properties every 8th element.Law of Octaves - properties of elements repeated every 8th element.There were 62 known elements at the time.
7C. Dmitri Mendeleev: 1869Arranged elements in order of increasing atomic mass.Similar properties occurred after periods (horizontal rows) of varying lengths.Organized the 1st periodic table according to increasing atomic mass and put elements with similar properties in the same column.Periodic – repeating properties or patternsNoticed inconsistencies in the arrangement.
9He arranged some elements out of atomic mass order to keep them together with other elements with similar properties. (Notice Te and I)He also left several blanks in his table.In 1871, he correctly predicted the existence and properties of 3 unidentified elements – Sc, Ga and GeThese elements were later identified and matched his predictions.
10Mendeleev is known as the 1st Periodic LawProperties of the elements repeat periodically when the elements are arranged in increasing order by atomic massMendeleev is known as theFather of Chemistry#101 honors Mendeleev
11D. Henry Moseley: 1911Studied X-ray spectral lines of 38 metals. Each element had a certain amount of positive charge in the nucleus which are called protons.Analyzed data and found that the elements in the PT fit into patterns better when arranged in increasing nuclear charge, which is the Atomic Number.The Modern Periodic Law: When elements are arranged in order of increasing atomic number, their physical and chemical properties show a periodic pattern.
12Glenn Seaborg “Seaborgium” Sg #106 Born in 1912 in Michigan, Seaborg proposed reorganizing the Periodic Table one last time as a young chemist working on the Manhattan Atomic Bomb Project during WWII.He suggested pulling the “f-block” elements out to the bottom of the table.He was the principle or co-discoverer of 10 transuranium elements.He was awarded the Noble prize in 1951 anddied in 1999.
13Seaborgium is the exception… After some argument between the USA and the rest of the world, element 106 was named Seaborgium shortly before he died. This was a matter of some controversy because the International Union of Pure and Applied Chemistry, IUPAC, the body that deals with naming in chemistry, had previously ruled that elements should not be named after living people.Atomic #104105106107IUPACUnnilquadeumUnqUnnilpentiumUnpUnnilhexiumUnhUnnilseptiumUnsAgreed in 1995Dubnium(Dubna, Russia)Joliotium(Frederic Joliot)Rutherfordium(Earnest Rutherford)Bohrium(Neils Bohr)Agreed in 1996Seaborgium
14Parts of the Periodic Table Horizontal Rows – PERIODSThere are 7 periods in the periodic tableElements in a period do NOT have similar properties.Vertical Columns – GROUPS or FAMILIESLabeled 1-18IA-VIIIA are the Main-group or representative elements.Elements in a group have similar properties.Why?
15Family Names write these on your P.T. Transition elements or metals (3-12): d-blockInner transition elements or metals (f-block)Lanthanides or lanthanide seriesActinides or actinide seriesTransuranium elementsHydrogen (1)Alkali metals (1) – most reactive metals; reactivity increases down the groupAlkaline earth metals (2)Boron family (13)Carbon family (14)Nitrogen family (15)Oxygen or Chalcogen family (16)Halogens (17)Noble gases (18) - inert
17E. Metal, Nonmetals and Metalloids (Semimetals): Found on theLEFT side ofthe PT2. NonmetalsLocated on theRIGHT side of3. Metalloids - Properties of both metals & nonmetals- Good conductors of heat & electricity- High melting points most solids at room temperature- High luster (shiny)- Ductile (can be drawn into thin wire)- Malleable (bends without breaking)- High densities- Reacts with acids- Brittle (easy to break)- No luster (dull)- Insulators nonconductors- Neither ductile nor malleable- Nonreactive with acids(Semimetals)
18Review of Early Atomic Theories Dalton Thomson (plum pudding)
20Quantum Mechanical (Schrödinger) Model Bohr – electrons in a particular path have a fixed energy called energy levelsRungs of a ladderQuantum Mechanical (Schrödinger) ModelElectrons better understood as WAVESDoes not tell where the electrons are locatedElectrons have a certain amount of energy - QUANTIZED
22ex) Radio FM 93.3 megahertz (MHz) is 93.3 x 106 Hz (cycles/sec) Light as a WaveCharacteristics of a WaveAmplitude: Height of the wave from the baseline. The higher the wave the greater the intensity.Wavelength: (λ , “lambda”) in nanometers (1 x 10-9 m). Distance between similar points on 2 consecutive waves.Frequency: (ν , “nu”) The number of waves that pass a fixed point per unit of time. Measured in cycles/second (1/s) 1 cycle/second = Hertz (Hz)ex) Radio FM 93.3 megahertz (MHz) is x 106 Hz (cycles/sec)
24D. Electromagnetic Radiation - a form of energy that exhibits wavelike behavior as it travels through space - all forms of EM radiation move at the speed of light
25This is an indirect relationship. Speed of Light (c)E x 108 m/s or 186,000 miles/sec.The relationship between wavelength andfrequency can be shown with the followingequation:This is an indirect relationship.If λ then ν .c = λ ν
29X Quantum Theory Planck’s Hypothesis: (Max Planck 1900) Studied emission of light from hot objectsObserved color of light varied with temperatureSuggested the objects do not continuously emit E, but emit E in small specific amountsLight is absorbed or emitted in a little packet or bundle called a quantum (quanta –plural).Quantum = minimum amount of E that can be lost or gained by an atomEnergies are quantized.(Think steps not a ramp)e-e-Xe-e-
30Incandescent light bulbs give off most of their energy in the form of heat-carrying infrared light photons -- only about 10 percent of the light produced is in the visible spectrum. This wastes a lot of electricity. Cool light sources, such as fluorescent lamps and LEDs, don't waste a lot of energy generating heat -- they give off mostly visible light. For this reason, they are slowly edging out the old reliable light bulb.
31Max Planck’s Energy Equation Proposed that energy is directly proportional to frequency.E = hPlanck’s equation for each quantumh = Plank’s constant = x J.sThis is a direct relationship.As energy increases, frequency increases.
32Albert EinsteinWhile well-known for the equation E=mc2 , Einstein’s work on the photoelectric effect resulted in being awarded the 1921 Nobel Prize in Physics.(1879 – 1955)German Physicist
33Albert Einstein and the Photoelectric Effect Refers to the emission of electrons from a metal when light shines on the metalObservations:Electrons are ejected by light of sufficient energy. Energy minimum is different for different metals.The current (# of electrons emitted/s) increases with brightness of the light.my.hrw.com
34Albert Einstein and the Photoelectric Effect Conclusions:Proposed that light consists of quanta of energy that behaves like particles.Quantum of light = photon = massless particle that carries a quantum of energy.Proposed the Dual Nature of Light: its wave and particle nature.Light travels through space as wavesLight acts as a stream of particles when it interacts with matter.my.hrw.com
36SpectroscopyDefinition: a method of studying substances that are exposed to some sort of continuous exciting energy.A. Emission Line Spectra: contains only certain colors or wavelengths ( ) of light.1. Every element has its own line spectrum (fingerprint).
37Continuous Spectrum – White Light Line Spectrum – Excited Elements
38B. White light gives off a Continuous Spectrum a blending of every possible wavelength
39Gas Discharge TubesElectricity is added to the gas which causes the electrons to jump to a higher or excited state. They immediately fall back to the ground state and give off particular wavelengths of light. We see a blending of wavelengths without the spectroscopes.
40Flame Testsused to test qualitatively for the presence of certain metals in chemical compounds. the heat of the Bunsen flame excites electrons that emit visible light.Copper(II) sulfateLithium chloridePotassium chlorideBarium nitrate
42SpectroscopeUses a diffraction grating to diffract the light into particular wavelengths of light.
43A Line Spectra result from excited elements - as electrons of an element gain energy and rise to an excited state they then fall back to their ground state in the same pattern producing the same energy drop each time which we see as individual wavelengths of light.
44III. Atomic Spectra and the Bohr Model of Hydrogen (1913) Neils Bohr - Danish ScientistExplained the bright-line spectrum of hydrogenStudy:Added E as electricity to H gas at low pressure in a tube.Emitted E as visible light, was observed through a prismResult: Hydrogen emitted 4 distinct bright lines of color, aka bright line spectrum
45Electrons release energy as they fall back to a lower energy level
46Electrons absorb energy to rise to a higher or excited state and emit energy in the form of a photon of light as they fall back to their ground states.
47Path of an excited electron as it “falls” back to the Ground State When electrons gain energy, they jump to a higher energy level (excited state).Electrons are not stable at the excited state and will immediately fall back to a lower level or ground state.As they fall, they emit electromagnetic radiation.Depending on how far they fall determines the type of radiation (light) released.
48Bohr Model of HydrogenConclusion:*Unique line spectrum is due to quantized electron energies.*Electrons are in specific orbits related to certain amounts of energy known as stationary states.*Orbits are related to energy levels.*Energy levels are identified as E1, E2, E3, … (n = 1, 2, 3, …)*Lowest energy level = ground state*Electrons absorb certain amounts of energy to move to a higher energy level farther away from the nucleus = excited state*Electrons return to the more stable ground state and release a photon that has energy equal to the difference in energy between the energy levels.from E2 to E1: Ephoton = E2 – E1 (difference in energy)
49The Bohr Atom for Hydrogen - a Model Successful in calculating the wavelength, frequency, & energy of hydrogen’s line spectrum.Successful in calculating the energy needed to remove hydrogen’s electronH(g) + energy H+1(g) e-Calculated ionization E = observed ionization E= kJ/mol
50Lyman, Balmer and Paschen series of the Hydrogen Atom Lyman series: electrons fall to n = 1 and give off UV light.Balmer series: electrons fall to n = 2 and give off visible light.Paschen series: electrons fall to n = 3 and give off infrared light.
51When electrons absorb energy they jump to a higher (excited) state. n=2 n=3 n=4 n=5 n=6 n=7Electrons are not stable. Radiation (light) is emitted when an electron falls back from a higher level to a lower level.
54Atomic SpectraHydrogenAlthough Bohr’s atomic model explained the line spectra of hydrogen, it failed for heavier elements.HeliumLithiumMercury
55Limitations of the Bohr Model Model could not calculate the wavelengths of observed spectra of multi-electron atoms.Model could not explain the chemical behavior of atoms.Bohr used classical mechanics to understand the behaviors of small particles.The Bohr model is also known as the planetary, solar system, or satellite model.
56Quantum Mechanical Model of the Atom Louie De Broglie (1924-5)Took Einstein’s idea that light can exhibit both wave and particle propertiesVery small particles (like electrons) display properties of waves.Behavior of electrons in Bohr’s quantized orbits was similar to behavior of wavesFrench scientistKnown: any wave confined to a space can only have specific frequenciesDe Broglie suggested electrons are waves confined to the space around the atomic nucleus.Electrons could exist only at specific frequencies which correspond to specific energies (E = h quantized E of Bohr)
57Quantum Mechanical Model of the Atom Experimentally proven in 1927 by diffraction of electrons by Davisson & Germer (showed diffraction of electrons by a crystal of Ni)Wave-Particle Duality of NatureLight and electrons (very small particles like electrons, atoms, molecules) have properties of waves and particles QUANTUM MECHANICS (based on WAVE properties)**Large objects obey the laws of classical mechanics**
58C. Werner Heisenberg: (1927) Heisenberg’s Uncertainty Principle: states that it is impossible to determine simultaneously both the position and velocity of an electron or any other particle.You cannot predict future locations of particles.He found a problem with the Bohr Atom - no way to observe or measure the orbit of an electron.
59D. Erwin Schrödinger Wave Equation (1926) Wave nature of an electron is described by a mathematical equation.Four quantum numbers in the equation are used to describe an electron’s behavior – location and energy.Electron is treated as a wave with quantized energy.Describes the probability of the electrons found in certain locations around the nucleus.(1887 – 1961) Austrian Physicist
60Electron Density An orbital is a region in which an electron with a particular energy is likelyto be found.Where the density of anelectron cloud is high thereis a high probability that iswhere the electron islocated. If the electrondensity is low then there isa low probability.
64E. Atomic Orbitals - region around the nucleus where an electron with a particular energy is likely to be found (not the same as Bohr’s orbits!)Orbitals have characteristic shapes, sizes, &energies.2. Orbitals do not describe how the electron moves.3. The drawing of an orbital represents the dimentional surface within which the electron is found 90% of the time.
654. Sublevels can have 4 different shapes s – orbital spherical
661s, 2s & 3s orbitals Superimposed on one another
76Quantum NumbersEach quantum number provides more specific information on the probable location of an electron.Each electron within an atom can be described by a unique set of 4 quantum numbers.
77Quantum Numbers - Finding an address for each electron: “state” Principle Quantum Number (n) or the energy level;Describes the relative size of the electron cloud.Positive integer values (n = 1 to n = 7)“city” Sublevel (l)Describes the shape of the electron cloud.The maximum number of sublevels within a level = nShapes are s, p, d,or f.Lowest energy = s Highest energy = f
78Quantum numbers cont. “street” Orbital (ml) odd # of orbitals Describes the orientation or direction in spaces – 1 orbitalp – 3 orbitals (x, y, z)d – 5 orbitals (xy, yz, xz, x2 – y2, z2)f – 7 orbitals (y3 – 3yx2, 5yz2-yr2, x3-3xy2,zx2-zy2, xyz, 5xz2-3xr2, 5z3-3zr2)Orbitals within the same sublevel have the same energy are called degenerate orbitalsAn orbital can hold a maximum of 2 electrons
79Quantum numbers cont. “house” Spin (ms) Describes the direction of electron spin in an orbital.The clockwise or counterclockwise motion of electrons.Only electrons with opposite spins can occupy the same orbital.The opposite spin is written as+1/2 or -1/2 or or
80E. Electron Configurations: Shorthand notation for indicating the number of electrons in each level, sublevel, and orbital.1s2Shows the distribution of electrons among the orbitals. Describes where the electrons are found & what energy they possess.
81Electron Configuration Rules The Aufbau Principle: electrons are added one at a time to the lowest energy orbital available.
82Pauli Exclusion Principle: 1. Each orbital can only hold 2 electrons.2. The electrons must have opposite spins.s-sublevel = max 2 electronsp-sublevel = max 6 electronsd-sublevel = max 10 electronsf-sublevel = max 14 electronsincorrect: ↑↑↑ incorrect: ↑↑ correct: ↑↓
83Hund’s Rule:Electrons will remain unpaired in degenerate orbitals before they pair up.incorrect ↑↓ ↑ __correct ↑ ↑ ↑
87Increasing energy 7p 6d 5f 7s 6p 5d 6s 4f 5p 4d 5s 4p 3d 4s 3p 3s 2p Pauli Exclusion Principle: No more than 2 e- are put in each orbital and they must have opposite spin.Hund’s Rule: electrons spread out among equal energy orbitals in a sublevel (like charges repel)Aufbau Principle: Electrons fill lowest energy levels first (n=1)
88Electron Configuration Examples: Ex) electron configuration for Na:1s2 2s2 2p6 3s1Ex) orbital filling box diagram for Na:
89Electron Dot Diagrams: Write the symbol for the element.Place dots around the symbol to represent thevalence s & p electrons only.Do NOT include d & f orbitals in diagram.p orbital electrons s orbital electrons
90Electron Configuration Orbital Box Diagram Electron-dot Diagram 1s22s22p41s22s22p63s23p51s22s22p63s23p64s23d104p65s24d105p4What does the Tellurium electron-dot resemble???
92Unpaired vs. Paired Electrons Filled and Half-filled orbitals Atoms with unpaired electrons are said to be paramagnetic. These are weakly attracted to a magnetic field.Atoms with all paired electrons are said to be diamagnetic. These are weakly repelled from a magnetic field.½ filled and filled orbitals have special stability
93Noble Gas or Shorthand Electron Configurations RbSeAtDraw the Dot Diagrams for these elements
94Exceptions to the Rules Max stability - ½ filled and filled orbitalsCrMoCuAgAu
95Exceptions to the Rules Max stability - ½ filled and filled orbitalsCrMoCuAgAu
96Electron Configuration for Ions KPAlSeK+1P-3Al+3Se-2
97Excited vs. Ground State If an electron absorbs energy, it is in an EXCITED stateNe: 1s22s22p53s1How is this different from the ground state configuration?Ne: 1s22s22p6
98C. Electron Configuration & Families Valence electrons – outermost electrons (s and p); responsible for bonding and chemical behavior.Elements in the same group have the same number of valence electrons.Carbon has 4 valence electrons
100Electron Configurations Stable Octet: 8 electrons in the outer level is very stable (includes He)Ions – gain/lose electrons to achieve a stable octetIsoelectronic – same electron configurationExamples: N, O, F, Na, Mg, Al are isoelectronic with Ne – this is called an isoelectronic seriesPseudoisoelectronic – same electron configuration but includes the d orbitalsFe+2 is pseudoisoelectronic with Ar