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1 Chapter 7 Part 1 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Quantum Theory and the Electronic Structure of Atoms

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2 Properties of Waves Wavelength ( ) is the distance between identical points on successive waves. Amplitude is the vertical distance from the midline of a wave to the peak or trough. Frequency ( ) is the number of waves that pass through a particular point in 1 second (Hz = 1 cycle/s). The speed (u) of the wave = x

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3 Maxwell (1873), proposed that visible light consists of electromagnetic waves. Electromagnetic radiation is the emission and transmission of energy in the form of electromagnetic waves. Speed of light (c) in vacuum = 3.00 x 10 8 m/s All electromagnetic radiation x c

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5 x = c = c/ = 3.00 x 10 8 m/s / 6.0 x 10 4 Hz = 5.0 x 10 3 m A photon has a frequency of 6.0 x 10 4 Hz. Convert this frequency into wavelength (nm). Does this frequency fall in the visible region? = 5.0 x 10 12 nm

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The wavelength of the green light from a traffic signal is centered at 522 nm. What is the frequency of this radiation? 6

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Problem 1 What is the wavelength (in meters) of an electromagnetic wave whose frequency is 3.64 x 10 7 Hz? 7

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8 Mystery #1, “Heated Solids Problem” Solved by Planck in 1900 Energy (light) is emitted or absorbed in discrete units (quantum). E = h x Planck’s constant (h) h = 6.63 x 10 -34 J s When solids are heated, they emit electromagnetic radiation over a wide range of wavelengths. Radiant energy emitted by an object at a certain temperature depends on its wavelength. blackbody-spectrum

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9 E = h x E = 6.63 x 10 -34 (J s) x 3.00 x 10 8 (m/s) / 5.00 x 10 -5 (m) E = 3.98 x 10 -21 J E = h x c / Calculate the energy (in joules) of a photons with a wavelength of 5.00 x 10 4 nm (infrared region). 5.00 x 10 4 (nm) x (1 x 10 -9 (m)/(nm) = 5.00 x 10 -5 (m)

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10 Calculate the energy (in joules) of a photons with a wavelength of 5.00 x 10 -2 nm (x-ray region).

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Problem 2 The energy of a photon is 5.87 x 10 -20 J. What is its wavelength in nanometers? 11

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12 Light has both: 1.wave nature 2.particle nature h = KE + W Mystery #2, “Photoelectric Effect” Solved by Einstein in 1905 Photon is a “particle” of light KE = h - W h KE e - where W is the work function and depends how strongly electrons are held in the metal photoelectric

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13 E = h x E = 6.63 x 10 -34 (J s) x 3.00 x 10 8 (m/s) / 0.154 x 10 -9 (m) E = 1.29 x 10 -15 J E = h x c / When copper is bombarded with high-energy electrons, X rays are emitted. Calculate the energy (in joules) associated with the photons if the wavelength of the X rays is 0.154 nm.

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14 The work function of cesium metal is 3.42 x 10 -19 J. Calculate the minimum frequency of light necessary to eject electrons from the metal.

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15 The work function of cesium metal is 3.42 x 10 -19 J. Calculate the kinetic energy of the ejected electron if light of frequency 1.00 x 10 15 s -1 is used for irradiating the metal.

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Problem 3 The work function of titanium metal is 6.93 x 10 -19 J. Calculate the energy of the ejected electrons if light of frequency 2.50 x 10 15 s -1 is used to irradiate the metal. KE = _____x 10 -19 J 16

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17 Line Emission Spectrum of Hydrogen Atoms Mystery #3, “Emission Spectra”

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19 1.e - can only have specific (quantized) energy values 2.light is emitted as e - moves from one energy level to a lower energy level Bohr’s Model of the Atom (1913) E n = -R H ( ) 1 n2n2 n (principal quantum number) = 1,2,3,… R H (Rydberg constant) = 2.18 x 10 -18 J

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20 E = h

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21 E photon = E = E f - E i E f = -R H ( ) 1 n2n2 f E i = -R H ( ) 1 n2n2 i i f E = R H ( ) 1 n2n2 1 n2n2 n f = 1 n i = 2 n f = 1 n i = 3 n f = 2 n i = 3

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23 E photon = 2.18 x 10 -18 J x (1/25 - 1/9) E photon = E = -1.55 x 10 -19 J = 6.63 x 10 -34 (Js) x 3.00 x 10 8 (m/s)/1.55 x 10 -19 J = 1280 nm Calculate the wavelength (in nm) of a photon emitted by a hydrogen atom when its electron drops from the n = 5 state to the n = 3 state. E photon = h x c / = h x c / E photon i f E = R H ( ) 1 n2n2 1 n2n2 E photon =

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Problem 4 What is the wavelength (in nm) of a photon emitted during a transition from n i =6 to n f =4 in the H atom? 24

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25 Mystery #1, “Heated Solids Problem” Solved by Planck in 1900 Energy (light) is emitted or absorbed in discrete units (quantum). E = h x Planck’s constant (h) h = 6.63 x 10 -34 J s When solids are heated, they emit electromagnetic radiation over a wide range of wavelengths. Radiant energy emitted by an object at a certain temperature depends on its wavelength. blackbody-spectrum

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26 Light has both: 1.wave nature 2.particle nature h = KE + W Mystery #2, “Photoelectric Effect” Solved by Einstein in 1905 Photon is a “particle” of light KE = h - W h KE e - where W is the work function and depends how strongly electrons are held in the metal photoelectric

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27 Line Emission Spectrum of Hydrogen Atoms Mystery #3, “Emission Spectra”

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28 1.e - can only have specific (quantized) energy values 2.light is emitted as e - moves from one energy level to a lower energy level Bohr’s Model of the Atom (1913) E n = -R H ( ) 1 n2n2 n (principal quantum number) = 1,2,3,… R H (Rydberg constant) = 2.18 x 10 -18 J

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29 De Broglie (1924) reasoned that e - is both particle and wave. Why is e - energy quantized? u = velocity of e- m = mass of e- 2 r = n = h mu

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30 = = 6.63 x 10 -34 J s (6.0 x 10 -2 kg x 68 m/s) = 1.6 x 10 -34 m = 1.6 x 10 -25 nm Calculate the wavelength of the ‘particle’ in each of the following two cases: (a) The fastest serve ever recorded in tennis was about 150 miles per hour, or 68 m/s. Calculate the wavelength associated with a 6.0 x 10 -2 kg tennis ball travelling at this speed. Because the wavelength is so small compared to the size of the tennis ball, the wave properties cannot be detected by any existing measuring device. h mu J = kg m 2 s2s2

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31 Calculate the wavelength of the ‘particle’ in each of the following two cases: (b) Calculate the wavelength associated with an electron (9.1094 x 10 -31 kg) travelling at this speed.

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Problem 5 Calculate the wavelength (in nm) of a H atom (mass = 1.674 x 10 -27 kg) moving at 7.00 x 10 2 cm/s. 32

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33 Chemistry in Action: Laser – The Splendid Light Laser light is (1) intense, (2) monoenergetic, and (3) coherent L ight A mplification by S timulated E mission of R adiation

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