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Carboxylic Anhydrides, Esters and Amides
Naming Anhydrides Drop the word acid and say anhydride
Naming Esters Name the alkyl group bonded to the oxygen Then name the acid part but change the ending from oic acid to oate
Naming Amides Drop the oic acid part and say amide
Formation of Esters
Amides: Preparation Addition of ammonia results in an ammonium salt: ammonium salt Heating will remove a water and give the Amid This is not the most common way
Formation of Amides Anhydride + amine = amide + acid http://www.youtube.com/watch?v=f4I2S0jUoh4 http://www.youtube.com/watch?v=G-k08VVz0Vc Do The YouTube
Reactions Hydrolysis of esters with acid Hydrolysis of esters with base (saponification) Reaction of Anhydrides with Alcohol Reaction of Esters with ammonia
Hydrolysis of Ester with Acid Hydrolysis breaks a carboxyl bond by addition of water, alcohol, or amine
Hydrolysis of Esters Hydrolysis = Reverse of esterification –Acid or base catalyzed –Produces acid and alcohol 1 o alcohol B
Hydrolysis of Esters with Base Base catalyzed hydrolysis (saponification) 1 o alcohol B
Reaction of Anhydrides with Alcohols EsterAcid
Reaction of Esters with Ammonia
Phosphoric Anhydrides Anhydrides of Phosphoric Acid The phosphorus structure is very common in biological systems For example - the phosphate portion of DNA B anhydride form H 3 PO 4
Phosphoric Anhydrides Anhydrides of Phosphoric Acid B
Phosphoric Anhydrides Anhydrides of Phosphoric Acid –Contain HIGH ENERGY bonds (linkages) Release of energy when broken B
Phosphoric Anhydrides Anhydrides of Phosphoric Acid –Esters found in Biochem reactions –ATP, ADP, etc. 1 o alcohol B As these bonds break, energy is released.
Reactions of Carboxylic Acids, Carboxylate Salts, and Carboxylate Esters Susan F. Hornbuckle Associate Professor of Chemistry Clayton State University.
Carboxylic Acids Carboxylic acids contain a carboxyl group: O CH 3 C-O-H ORCH 3 CO 2 H Carboxyl group.
© 2006 Thomson Learning, Inc. All rights reserved General, Organic, and Biochemistry, 8e Bettelheim, Brown, Campbell, & Farrell.
Chemistry 2100 Chapter 19.
Revision of Formation of Esters Formed from:- Formed from:- Carboxylic Acid Carboxylic Acid.
Chapter 19: Carboxyl Derivatives In this chapter, we study three classes of compounds derived from carboxylic acids; anhydrides, esters, and amides. –
Chapter 11 Carboxylic Anhydrides, Esters, and Amides
Carboxyl Derivatives In this chapter, we study three classes of compounds derived from carboxylic acids; anhydrides, esters, and amides. Each is related.
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CHAPTER 15 CONCURRENT ENROLLMENT. CARBOXYLIC ACID CCCCarboxylic acid or carboxyl group - is an organic compound that contains the following functional.
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Chapter 14 Carboxylic Acids and Carboxylic Acid Derivatives Denniston Topping Caret 6 th Edition Copyright The McGraw-Hill Companies, Inc. Permission.
Karboxylsyrer og derivater. Functional groups Acid and esters.
Functional Groups Chemistry 11. Functional Groups There are several different groups that can be added to a hydrocarbon in order to change it into a different.
Copyright © 2000 by John Wiley & Sons, Inc. All rights reserved. Introduction to Organic Chemistry 2 ed William H. Brown.
15-1 Principles and Applications of Inorganic, Organic, and Biological Chemistry Denniston, Topping, and Caret 4 th ed Chapter 15 Copyright © The McGraw-Hill.
In this chapter, we focus on four classes of organic compounds derived from carboxylic acids. Under the general formula of each is a drawing to show how.
© 2003 Thomson Learning, Inc. All rights reserved General, Organic, and Biochemistry, 7e Bettelheim, Brown, and March.
The ammonium salt formation is reversible. Upon heating, a slower but thermodynamically more favorable reaction between the carboxylic acid and the amine.
Formation of the ester ethyl propanoate from a carboxylic acid.
C HAPTER 15: C ARBOXYLIC A CID D ERIVATIVES Nucleophilic Acyl Substitution.
1 Ch. 14: Carboxylic Acids, Esters, Amines and Amides Chem 20 El Camino College.
14.6 Amides Tylenol, an aspirin substitute, contains acetaminophen. Acetaminophen is an amide. It acts to reduce fever and pain; however, it has little.
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Week 4 © Pearson Education Ltd 2009 This document may have been altered from the original Explain the water solubility of carboxylic acids. Describe the.
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