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**Conversion and Reactor Sizing**

Lec 5 week 6

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**Definition of Conversion for the following reaction**

The reaction can be arranged as follows: Now we ask such questions as "How can we quantify how far the above reaction proceeds to the right?" or “How many moles of C are formed for every mole A consumed? A convenient way to answer these questions is to define a parameter called conversion. The conversion XA is the number of moles of A that have reacted per mole of A fed to the system.

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**Batch Reactor Design Equations in terms of conversion**

In most batch reactors. the longer a reactant stays in the reactor, the more the reactant is converted to product until either equilibrium is reached or the reactant is exhausted, Consequently. in batch systems the conversion X is a function of the time the reactants spend in the reactor. If NAO is the number of moles of A initially in the reactor then the total number of moles of A that have reacted after a time t is [NA0 *X]

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**Batch Reactor Design Equations in terms of conversion**

the mole balance on species A for a batch system is given by the following equation: reactant A is disappearing: therefore, we multiply both sides of Equation by -1 then

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**Batch Reactor Design Equations in terms of conversion**

For batch reactors. we are interested in determining how long to leave the reactants in the reactor to achieve a certain conversion X. To determine this length of time, we write the mole balance. Equation in terms of conversion. NA=NA0(1-XA) by differentiating the above equation with respect to time, remembering that NAo is the number of moles of A initially present and is therefore a constant with respect to time.

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**Batch Reactor Design Equations in terms of conversion**

To determine the time to achieve a specified conversion X This equation is now integrated with the limits that the reaction begins at time equal zero where there is no conversion initially (i.e., t = 0, X = 0).

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**Design Equations for Flow Reactors**

For a batch reactor. we saw that conversion increases with time spent in the reactor. For continuous-flow systems, this time usually increases with reactor volume. E.g. the bigger /longer the reactor, the more time it will take the reactants to flow completely through the reactor and thus, the more time to react. The conversion X is a Function of reactor volume V. If FA0 is the molar flow rate of species A fed to a system operated at steady state. The molar rate at which species A is reacting within the entire system will be FA0X.

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**Design Equations for Flow Reactors**

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**Design Equations for Flow Reactors**

For liquid systems, CA0, is commonly given in terms of molarities, for example, CAO = 2 moll/dm3. For gas systems, CAo can be calculated from the entering temperature and pressure using the Ideal gas law.

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**Design Equations for Flow Reactors**

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Example(1 ) A gas of pure A at 830 kPa (8.2 atm) enters a reactor with a volumetric flow rate,v0 of 2 dm3/s. at 500 K. Calculate the entering concentration of A, CA0, and the entering molar flow rate. FAo.

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solution For flow reactors (CSTR) For gas phase reactor.

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**Tubular Flow Reactor (PFR)**

For a flow system, FA has previously been given in terms of the entering molar flow rare FA0 and the conversion X By differentiate Substitute in the 1st equation to give the differential form of the design equation for a plug-flow reactor (PFR): We now separate the variables and integrate with the limits V = 0 when X = 0 to obtain the plug-flow reactor volume necessary to achieve a specified conversion X:

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Packed-Bed Reactor

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Example Consider the liquid phase reaction which we will write symbolically as A B The first order (-rA = k CA) reaction is carried out in a tubular reactor in which the volumetric flow rate, v, Is constant i.e. v =v0. (a) Derive an equation relating the reactor volume to the, entering and exiting concentrations of A the rate constant k, and the volumetric flow rate v. (b) Determine the reactor volume necessary to reduce the exiting concentration to 10% of the entering concentration when the volumetric flow rate is I0(dm3/min) and the specific reaction rate, k. is 0.23 min-1 .

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Solution

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ERT 316: REACTION ENGINEERING CHAPTER 2 CONVERSION & REACTOR SIZING

ERT 316: REACTION ENGINEERING CHAPTER 2 CONVERSION & REACTOR SIZING

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