3Counting Atoms Masses of atoms expressed in grams are extremely small. An atom of O-16 literally weighs gFor most calcs in chemistry it is easier to use a relative atomic mass.for relative masses, an atom was arbitrarily chosen as the standard, by which all other masses are compared
4Counting AtomsThe mass of all the other atoms are then expressed in relation to the standardC-12 atom acts as the standardA single C-12 atom was assigned a mass of 12 atomic mass units (amu)1 amu is exactly 1/12 of the mass of a C-12 atomCarbon has 12 nucleons therefore, the mass of a proton = 1 amu6CARBONC12
5Counting AtomsThe masses of all other atoms are based on the mass of 1 amuHydrogen has 1 proton therefore, it weighs 1 amuHelium has 2 protons and 2 neutrons therefore, it weighs 4 amusMost elements occur naturally as a mixture of isotopes.For instance in the two isotopes of Chlorine (Cl-35 & Cl-37)
6Counting Atoms Cl-35 atoms are naturally more abundant than Cl-37 75% of all of the Cl atoms found in nature are the isotope Cl-3525% of the all of the Cl atoms found in nature are the isotope Cl-37Cl-35 atoms are naturally more abundant than Cl-37Therefore, the average mass of Cl (taking into account isotopic abun-dance) should be closer to 35 than to the median of 36.
7Here’s how the masses were calculated on the Periodic Table: Counting AtomsMasses on the PT are weighted aver-ages of all of the naturally occurring isotopes of an elementThe average atomic mass on the PT is reflective of both the mass numbers of each isotope & the abundance of each isotopeHere’s how the masses were calculated on the Periodic Table:
8Counting Atoms Calculating average atomic masses: Naturally occurring copper consists of 69.17% Cu-63, which has a mass of amu, and 30.83% Cu-65, with a mass of amu.The average atomic mass of Cu is calculated by multiplying the atomic mass of each isotope by its abundance and adding the results.
9Counting Atoms 63.55 amu 63.54564387858 amu Cu-63 The reported average atomic mass of naturally occurring Cu is amu.
10Your Turn:Gallium consists of two isotopes of masses amu and amu with abundances of 60.16% and 39.84%, respectively. What is the average atomic mass of gallium?Naturally occurring element X exists in three isotopic forms: X-28 ( amu, 92.21% abundance), X-29 ( amu, 4.70% abundance), and X-30 ( amu, 3.09% abundance). Calculate the atomic weight of X.
11Counting AtomsIt is impractical to get caught up into working with 1 atom or 1 atom’s mass.It makes more sense to work with a collection of atoms rather than individuallyScientists were challenged to figure out a way to define a collection of particlesAnd which could still be described in terms of a relative mass
12Counting AtomsIf we assume we can relate the relative masses from the PT in the terms of gramsWith the literal masses of an atom (g) for each atom we use we seem to get the same number of atomsOxygen:
14Counting AtomsThe number of atoms that are in the relative masses of elements identical in grams to the atomic masses on the PT is called Avogadro’s NumberAnd is defined as a moleThe mole becomes a counting unit much like the dozen.1 dozen eggs = 12 eggs1 mole of eggs =602,000,000,000,000,000,000,000 eggs
15Counting AtomsThe word “mole” was introduced by Wilhelm Oswald, who derived the term from the word moles meaning a “heap” or “pile.”We are just defining the pile as con-taining 6.02x1023 itemsAny time we are counting how many we have and we want to describe it in terms of moles than…1 mole is always = x 1023 items
16Counting AtomsThe mole, whose abbreviation is “mol”, is the SI base unit for measuring amount of a pure substance.It’s used exclusively for counting atoms, molecules, ions, or other things that are extremely smallIt’s the chemist’s six-pack or dozen. Many objects in our everyday lives come in similar counting units.1 ream = 500 sheets of paper1 pair of socks = 2 socks1 cube = 24 cans
17Counting AtomsWe will learn in the near future that when a chemist reasons through a chemical reaction (recipe) they think in terms of X number of mols of this compound reacts with Y number of mols of this compound.So we need to know how to calculate the number of molecules or atoms are involved in that X number of mols
18How many moles of Magnesium Counting AtomsUsing the mole in calculations #1How many moles of Magnesiumis 1.25 x 1023 atoms of Magnesium?unit equality:1 mol Mg = 6.02 x 1023 atoms Mg
20How many atoms of Gold do we have if we have .0327 moles of Gold? Counting AtomsUsing the mole in calculations #2How many atoms of Gold do we have if we have moles of Gold?unit equality:1 mol Au = 6.02 x 1023 atoms Au
21Counting Atoms = 2.23x1022 atoms Au The desired conversion is: moles atoms6.02x1023atoms Au.0327 mole Au1 mole Au= 2.23x1022 atoms Au
22Your Turn:Fill in the missing information in the following table, be sure to show your work.MolesAtoms or moleculesmols Al(OH)32.017 x 1012 molecules H2O6.017 x 1042 atoms W.2116 mols Al+3
23Counting AtomsNow suppose you want to determine how many atoms are in a mol of a compound or moleculeTo do this you must know how many atoms are involved in the molecule.To determine the number of atoms represented in a molecule requires knowing the chemical formulaEg, each molecule of Carbon Dioxide (CO2) is composed of 3 atoms
24How many atoms of Carbon are in 2.12 mols of Propane (C3H8)? Counting AtomsUsing the mole in calculations #3How many atoms of Carbon are in 2.12 mols of Propane (C3H8)?unit equalities:1 mol C3H8 = 6.02x1023 molecules C3H81 molecule C3H8 = 3 atoms C
26Your Turn:Fill in the missing information in the following table, be sure to show your work.MolesAtoms or molecules# of ____ atomsmols Al(OH)37.2511x1024 molecules# of O atoms3.350x10-12 mols H2O2.017 x 1012 molecules H2O# of total atoms9.995x1018 mols W6.017 x 1042 atoms W.2116 mols Al+31.274x1023 ions Al+3
27Counting AtomsWe can’t literally count the number of atoms in a sample, but we can count them by massSo, there needs to be a connection between the mass of a sample and the number of moles in that sampleIf we weigh out a particular mass of a substance, that can represent a particular number of molsIf we weighed out g of CarbonIt will represent 1 mole of Carbon and/or 6.02x1023 Carbon atoms
2818.99g F atoms=1 mol F atoms=6.02x10 F atoms Counting AtomsThis allows us to use the mass off of the periodic table to represent the mass of 1 mole (or 6.02x1023 atoms) of that element1 mol of C atoms weighs g1 mol of H atoms weighs g1 mol of W atoms weigh g18.99g F atoms=1 mol F atoms=6.02x10 F atoms23
29Counting AtomsThis new understanding of mass from the periodic table is known as the gram molar mass, or molar mass.Molar Mass = mass of 1 mole of atoms in gramsWe have a list of every possible molar mass for any given element on the periodic tableThis mass can be used as a conversion factor…1 mole = g H, etc.
30Counting Atoms So what if we have a compound instead of an element? How do we figure out the mass of a mole of a compound?This would be called a molecular mass, formula mass, or still can be called a molar massAll we need is the formula for a representative particle of the compound and the periodic table.
31Counting AtomsFor instance how do we calculate the mass of 1 mole of Ca(OH)2?You can calculate the mass of a mol- ecule of Ca(OH)2 by breaking it up into individual piecesWe can start with Calcium, then oxygens, then 2 hydrogens… until we run out of pieces74.09 g/molCa: (1)(40.09 g/mol) =40.09O: (2)(15.99 g/mol) =H: (2)(1.008 g/mol) =
326.02x1023 molecules of the compound –weighs 180.1 grams Counting AtomsWhat is the MM of glucose (C6H12O6)?(6C’S)(12.011g/mol) =72.066g/mol(12H’S)(1.008 g/mol) =12.096g/mol(6O’S)(15.99 g/mol) =95.94g/mol180.1g/mol1 mole of C6H12O6 or6.02x1023 molecules of the compound –weighs grams
33Practice Time: Molar Mass Moles Atoms or molecules # of ____ atoms mols Al(OH)37.2511x1024 molecules# of O atoms2.1753x1025 atoms O3.350x10-12 mols H2O2.017 x 1012 molecules H2O# of total atoms6.051x1012 atoms9.995x1018 mols W6.017 x 1042 atoms W.2116 mols Al+31.274x1023 ions Al+3
34How many grams are in 9.45 mol of Dinitrogen Trioxide (N2O3) Counting AtomsUsing the molar mass in calculations:How many grams are in 9.45 mol of Dinitrogen Trioxide (N2O3)The only connection to N2O3 and its mass is how much 1 mol of the compound weighs. But, using it as a comparison we can calculate the mass of 9.45 mol.
35Counting Atoms Step 1: Determine the mass of 1 mol of N2O3 (2N’s)(14.01g) =28.02g(3O’s)(15.99g) =47.97g75.99gIf 1 mole of N2O3 weighs 75.99g than how much will 9.45 mols of N2O3 weigh?
36Counting Atoms 75.99 g N2O3 9.45 mol N2O3 1 mol N2O3 =718 g N2O3 Step 2: Convert the given moles to grams using the Molar mass equality.75.99 g N2O39.45 mol N2O31 mol N2O3=718 g N2O3
37Counting Atoms Find the number of moles of 92.2g of Iron (III) Oxide (Fe2O3)The only connection to the mass of Fe2O and how that corresponds to mols is how that 1 mol of the compound weighs a certain # of grams. Using that we can figure out how many moles weigh 92.2 g
38Counting Atoms (2Fe’s)(55.85g) = 111.7g (3O’s)(15.99g) = 47.97g Step 1: Determine the mass of 1 mol of Fe2O3(2Fe’s)(55.85g) =111.7g(3O’s)(15.99g) =47.97g159.67gIf 1 mole of Fe2O3 weighs g than how many mols will weigh 92.2 g of Fe2O3?
39Counting Atoms 1 mol Fe2O3 92.2 g Fe2O3 159.67 g Fe2O3 =.577mol Fe2O3 Step 2: Convert the given mass to mols using the Molar mass equality1 mol Fe2O392.2 g Fe2O3g Fe2O3=.577mol Fe2O3
40Practice Time:Vitamin C (C6H8O6), cannot be stored by the body and therefore, must be present in the diet. If an orange contains 70 mg of Vit C how many oranges are necessary to consume 2.5 mols of Vit C?
41Counting AtomsAnother generality about the mole is that with matter in the gas phase we can develop another equality.Under the same conditions, equal volumes of gases contain equal numbers of particles.1 mol of a gas will occupy the same volume as 1 mol of any other gas under the same conditions.
42Molar Volume of a Gas22.4 L22.4 L1 mole of any gas under the specific conditions of 0°C and 1 atm (STP) will occupy a volume of 22.4 L.6.02x1023molecules of O26.02x1023molecules of CO2
43What volume, in Liters, does 0.60 mol of SO2 gas occupy at STP? Counting AtomsWhat volume, in Liters, does 0.60 mol of SO2 gas occupy at STP?The only connection to the volume of any gas and how that corresponds to mols is that 1 mol of a gas occupies 22.4 Liters of space. Using that we can figure out the volume of 0.60 mols of a gas at STP.
44Counting Atoms 22.4 L SO2 0.60 moles SO2 1 mole SO2 = 13 L SO2 Step 1: Use the equality 1 mol = 22.4 L to do the conversion22.4 L SO20.60 moles SO21 mole SO2= 13 L SO2
45Practice Time:The Snoopy balloon featured at the Macy’s Thanksgiving Day Parade has a volume of ft3. How many moles of Helium are required to fill it STP?
47Counting AtomsAspartame is an artificial sweetener that is 160 times sweeter than sugar when dissolved in water. It is marketed as Nutra-Sweet (C14H18N2O5).What number of molecules are in 5.0 mg of aspartame?What number of atoms of nitrogen are in 1.2 g of aspartame?What is the mass in g of 1 molecule of aspartame?
52Your Turn:What is the mass of 7.21x1021 molecules of silver acetate (AgC2H3O2)?How many grams of neon gas will fill a room with a volume of 4000L at STP?How many molecules are there in g of Cu(NO3)2?Which has the greater mass?a. 9.5x1024 atoms of Cb. 2.1 mol Br2c. 1.86x1022 molecules of CCl4d. 59.5g Hg