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Feb 2006 SurTec International 关心环保. Feb 2006 SurTec International SURTEC INTERNATIONAL GMBH 赛德克囯际集団 赛德克杭州  東莞亞德 SURFACE TECHNOLOGY 金属表面处理科技专家.

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Presentation on theme: "Feb 2006 SurTec International 关心环保. Feb 2006 SurTec International SURTEC INTERNATIONAL GMBH 赛德克囯际集団 赛德克杭州  東莞亞德 SURFACE TECHNOLOGY 金属表面处理科技专家."— Presentation transcript:

1 Feb 2006 SurTec International 关心环保

2 Feb 2006 SurTec International SURTEC INTERNATIONAL GMBH 赛德克囯际集団 赛德克杭州  東莞亞德 SURFACE TECHNOLOGY 金属表面处理科技专家

3 Feb 2006 SurTec International SurTec products range 経営范圍 Pickling 酸洗 Delaquering 除漆 Corrosion Protection 防蝕 Passivation 鈍化 Phosphating 磷化 Coating 电鍍 Micro Technology 微型 Cleaning 清洗 Colouring 染色 Anodizing 阳极氧化

4 Feb 2006 SurTec International 集团子公司与代理商全球分佈图 Europe SurTec Ges.m.b.H, Austria SurTec France SurTec Adria Roland, Belgium Univar, France SurTec Eurosjaj, Bosnia-Herzegovina SurTec ČR/SurTec SK, Czech/Slovakia SurTec d.o.o. Croatia SurTec Scandinavia, Denmark SurTec Deutschland, Germany GLOMAX, Italy America CST-SurTec, USA SurTec do Brasil, Brasil SurTec Mexico Africa SurTec South Africa Galvachimie Marokko Asia Morimura Bros., Japan Pars Electroplating, Iran PAZ Lubricants, Israel SurTec Korea, South Korea SurTec Chemicals India Electro Chemical/YA THAI, Thailand Viet Nhat, Vietnam Yachung. Taiwan MS Chem, Malaysia Cahaya Chandra, Indonesia SurTec Hangzhou, China SurTec Taipei, Taiwan YST, Guangdong China SurTec Middle East SurTec UK SurTec BENELUX, Netherlands SurTec Polska, Poland SurTec Romania, Romania SurTec Čačak, Serbia/Montenegro COQUINESA, Spain RIAG, Switzerland SurTec Schachen GmbH, Switzerland DEDE a.sþ, Turkey artegalva Portugal HADJIKYPEROS, Greece

5 Feb 2006 SurTec International Application Areas and Customer References 产品应用范圍及囯际知名客戶 Aircraft and Aerospace 航空 EADS Lufthansa Automotive Industry 汽車 and Suppliers ABB Atoma Roltra BMW Borg Warner Bosch Ti Bundy Continental Teves Daimler-Chrysler Kelsey Hayes Knorr Bremse Luk Mahle Mannesmann Sachs Opel Parker Hannifin Rehau Siebe/Cooper TRW Valeo ZF Building and Household 建築 Broetje Gretsch Unitas Krupp-VDM Leitz Linde Vaillant Zwilling J.A. Henkels Electric and Electronics 电子 AEG Braun Buckbee Mears Heraeus Nanjing Electronic Philips Siemens Yantai Electronic Thomson PolKolor Fasteners 緊箍件 Arnold Ejot Hilti Textron Hardware 手工具 FAG Kugelfischer INA IWIS KETTEN Krauss Maffei RUD KETTEN SKF Timken Machine Manufacturers 机械 Grieshaber Guetling Parsys Metal Processing 金属加工 Alcan Langenberg PUT Plating Job Shops 代工廠 Gärtner & Klinger Holder Holzapfel Kronenberger Straehle Vollmerhaus Pipes and Fittings 制管及傢俱 Ceodeux Draeger Kemper Rieber VSH Printing Industry 印刷工业 Axel Springer Burda Maul Belser NDI Steel Industry 鋼鉄业 Hille & Müller Iscor Rasselstein Sollac Thyssen

6 Feb 2006 SurTec International TrivalentChromePassivation For Aluminum 鋁材的三價鉻鈍化

7 Feb 2006 SurTec International SurTec 650 chromitAL TCP Conversion coating for Aluminum, Magnesium 鋁與鎂的轉換層 Patented process – Licensed from US Navy 北美專利製程 – 由美國海軍授權 Contains low concentration of Cr(3) 含低濃度三價鉻 Non Hazardous 無毒無害

8 Feb 2006 SurTec International Aluminum Basic Process 基本製程 A drop-in replacement for Cr(6) processes 可替代六價鉻製程 Deoxidize RinsingDrying Used as isPainted chromital TCP - Cr(3) Clean Cr (6) Passivation

9 Feb 2006 SurTec International Process Sequence 製程工序 As is 處理前 Non Etch Clean 非侵蝕型清洗 (SurTec 133) Alkaline Etch 鹼性侵蝕 (SurTec 181) Desmut 除膜 (SurTec 495) ChromitAL TCP 三價鉻鈍化 AlMnCu Si 0.6, Fe 0.7, Cu 0.05 – 0.2 Mn 1.0 – 1.5, Zn 0.1

10 Feb 2006 SurTec International Application methods 應用方式 Immersion 浸沒 Spray – For large surfaces 噴淋 -- 適用於大型面積 Brush-on, touch-up maintenance 用刷塗上, 修整保養

11 Feb 2006 SurTec International Performance Evaluation Evaluated on various alloys 對各種不同的合金作評估 Tested against commercial Cr-free conversion coatings 對各式無鉻型置換層進行比較測試 A standard Cr(6) system was used as standard reference. (Control) 選擇標準六價鉻系統作為參考標準

12 Feb 2006 SurTec International Alloys Evaluated 評估的合金 Alloy 合金編號 Composition 成份 T34.5Cu, 1.5Mg, 0.6 Mn 2219 – T Cu, 0.3 Mn Mg, 0.7Mn 7075 – T65.5Zn, 2.5Mg,1.5Cu, 0.3Cr 6061 – T61.0Mg, 0.6 Si, 0.25Cu, 0.25Cr

13 Feb 2006 SurTec International Systems Compared 比較的系統 Cr(6) – Control 六價 Zirconate Siloxane/Zirconate Organic Acids/Solvents Organic Silane/Titanate Permanganate + Sealer Pyrolidone/Solvents chromitAL TCP, Cr(3) 三價 Non Cr Systems 非鉻型系統

14 Feb 2006 SurTec International Scope of Evaluation 評估的範圍  Bare corrosion resistance - Unpainted surfaces 裸露腐蝕測試 – 鈍化後未塗裝的表面  Painted surfaces 塗裝後的表面  Anodized Aluminum 陽極處理鋁材的封閉

15 Feb 2006 SurTec International Bare Corrosion Testing Unpainted Surfaces 裸露腐蝕測試 – 鈍化後未塗裝的表面 NSS, 168 and 336 hrs 中性塩霧 168 與 336 小時

16 Feb 2006 SurTec International Neutral Salt Fog, 336 hrs 中性塩霧 336 小時 Hexavalent Chrome System 六價鉻系統 T3 Control – Cr(6) T87

17 Feb 2006 SurTec International Neutral Fog Test – 168 hrs 中性塩霧 168 小時 Non – Chrome System 無鉻型系統 2024 T T-87 Zirconate System

18 Feb 2006 SurTec International Neutral Salt Fog, 336 hrs 中性塩霧 336 小時 - 三價鉻系統 chromitAL TCP 三價鉻 TCP T T87

19 Feb 2006 SurTec International System24 hrs48 hrs168 hrs336 hrs Cr(6) 10 Zirconate 983_ Permanganate + Sealer 982- chromitAL TCP 三價鉻 10 Average Rating after Neutral Salt Fog Test Al 2024 T-3 中性塩霧測試後平均評分 Rating

20 Feb 2006 SurTec International System24 hrs48 hrs168 hrs336 hrs Cr(6) Zirconate 0--_ Permanganate + Sealer 980- chromitAL TCP 三價鉻 Average Rating after Neutral Salt Fog Test Al 2219-T87 中性塩霧測試 2219 合金後平均評分 Rating

21 Feb 2006 SurTec International Painted Surfaces 塗裝後的表面 Primer, Paint, Lacquer… 各種底漆, 漆, 清漆  Tests performed: 實行的測試 –Dry tape adhesion 乾膜附著力 –Wet tape adhesion 濕膜附著力 –Neutral salt fog, 3000 hrs 中性塩霧 3000 小時 –SO2 salt fog, 500 hrs 二氧化硫酸霧 500 小時 –GM 9540 Cyclic test, 120 cycles 120 次 GM9540 循環測試 –Filliform corrosion 絲狀腐蝕 –Marine exposure 海洋暴露

22 Feb 2006 SurTec International Dry Tape Adhesion Testing Cross hatch and scribed method 乾膜附著力測試, 交叉刻劃法 Testing adhesion of primers applied to passivated panels per ASTM D 3359 依據 ASTM D-3359 標準對鈍化後 的試片進行底漆的附著力測試

23 Feb 2006 SurTec International SystemRating Cr(6)5.0 NC 15.0 NC 24.5 NC 35.0 NC 45.0 NC 54.5 NC 64.5 TCP 三價鉻 5.0 Dry Tape Adhesion Test - 6 Primers Cross Hatched and Scribed Methods 乾膜附著力試驗, 交叉刻劃法 Rating 0 - 5

24 Feb 2006 SurTec International Wet tape Adhesion Testing 濕膜附著力測試 Tape adhesion test after immersion in DI water for: 24 hrs, RT 浸泡至去離子水後 96 hrs, 50 C 做濕膜附著力測試 168 Hrs, 65C Measures adhesion of organic coatings submerged under water. 測量有機塗層在浸泡水後的附著力 Measures ability to resist penetration of water. 測量防水能力 Testing per FED – STD 141, ASTM 3359 依據 FED – STD 141, ASTM 3359 測試

25 Feb 2006 SurTec International SystemRating Cr(6)4.9 NC 14.9 NC 23.9 NC 34.0 NC 43.7 NC 53.9 NC 64.6 TCP 三價鉻 4.9 Wet Tape Adhesion Test - 6 Primers Cross Hatched and scribed Methods 濕膜附著力試驗, 交叉刻劃法 Rating 0 – 5

26 Feb 2006 SurTec International Neutral Salt Fog, 3000 hrs Scribed Painted Surfaces 刻劃於塗漆表面後進行中性塩霧三千小時 Test evaluates ability to prevent corrosion in scribed areas and adhesion of paint. 測試評估刮痕處的防蝕能力與對漆的附著力

27 Feb 2006 SurTec International SystemRating Cr(6)7.2 NC 17.3 NC 26.0 NC 33.0 NC 44.8 NC 52.7 NC 63.8 chromitAL TCP 三價鉻 7.2 Rating Summary – All Primers and Alloys Tested Neutral Salt Fog, 3000 hrs 所有底漆與合金組合測試中性塩霧三千小時 Rating

28 Feb 2006 SurTec International SO 2 Salt Fog Test 二氧化硫酸霧測試 Modified Salt Spray with SO 2 從中性塩霧變更為二氧化硫酸霧 Measures paint adhesion in acidified corrosive environment. 測量漆層在酸化腐蝕環境中的附著力 e.g. Industrial environment; Exhaust from engines… 例如 : 工業區環境 ; 引擎排放廢氣 …

29 Feb 2006 SurTec International Al SO 2 Salt Fog Test, 500 hrs 2219 合金於二氧化硫酸霧測試 500 小時 Cr (6) 六價 chromitAL TCP 三價鉻 Zr 無鉻型

30 Feb 2006 SurTec International System Combined Rating Cr(6)6.8 NC 16.2 NC 26.4 NC 33.3 NC 43.9 NC 52.5 NC 63.7 chromitAL TCP 三價鉻 6.8 Rating Summary – All Primers and Alloys Tested 500 hrs SO 2 Salt Fog Test 所有底漆與合金測試二氧化硫酸霧 500 小時 Rating

31 Feb 2006 SurTec International Filiform Test 絲狀腐蝕測試  Critical test for painted surfaces 對塗漆表面的嚴格測試  Evaluates under paint corrosion 評估漆層下的腐蝕狀況

32 Feb 2006 SurTec International Filiform Test 絲狀腐蝕測試 Test method 測試方式 : –Painted panel scribed X 在塗漆的試片上做 X 形刻劃 –Exposed to 12N HCL fumes for 1 hr, 24 C 暴露於溫度 24 度的 12N 鹽酸酸霧中 1 小時 –Exposed to Humidity, 80%, 40 C, 1000 hrs 暴露於溫度 40 度,80% 溼度中 1000 小時 –Corrosion filaments grow from scribed areas and penetrate laterally under paint 絲狀的腐蝕從刻劃處開始, 然後向漆層底下滲透

33 Feb 2006 SurTec International Filiform Test 絲狀腐蝕測試 Half the panel is stripped 剝去試片一半的漆層 Under paint corrosion exposed 暴露出漆層底下的腐蝕狀態 A template with 60 squares placed on both legs of X measures extent of corrosion 將六十格樣板放置於 X 的下面兩端以測量腐蝕狀態 Best rate: 120 clear squares – No corrosion 兩片六十格樣板共一百二十格無腐蝕即為滿分

34 Feb 2006 SurTec International Filiform Corrosion Test - Al T3 Waterborne Epoxy Primer 絲狀腐蝕測試 2024 合金塗裝水性環氧樹脂底漆 Zr 無鉻型 chromitAL TCP 三價鉻 Permanganate 無鉻型

35 Feb 2006 SurTec International Filiform CorrosionTest - Al 2024 – T3 Solvent-borne Epoxy Primer 絲狀腐蝕測試 2024 合金塗裝溶劑型環氧樹脂底漆 Cr (6) 六價 chromitAL TCP 三價鉻

36 Feb 2006 SurTec International Filiform Test 絲狀腐蝕測試 Template - 60 Squares 六十格樣板測試

37 Feb 2006 SurTec International Permanganate 無鉻型 Primer – Water Base 水性環氧樹脂底漆

38 Feb 2006 SurTec International Cr(6) 六價 Primer – Base solvent 溶劑型環氧樹脂底漆

39 Feb 2006 SurTec International chromitAL TCP 三價鉻 Primer – Water base 水性環氧樹脂底漆

40 Feb 2006 SurTec International chromitAL TCP 三價鉻 Primer – Solvent Base 溶劑型環氧樹脂底漆

41 Feb 2006 SurTec International System Combined Rating Cr(6)39.2 NC NC NC NC NC NC chromitAL TCP 三價鉻 71.9 Rating Summary – All Primers 2024 T3 Filiform Corrosion Rating 120 – 0 Template Method 以一百二十格樣板評估 2024 合金的絲狀腐蝕測試

42 Feb 2006 SurTec International Marine Exposure Test 海邊暴露測試 Scribed panels exposed to marine environment at beach site. 暴露刻記的試片於海灘邊的環境 Coating evaluated after 4, 8, 12 months 在 4,8,12 個月後評估塗層 Rated for creepage from scribe 就刻記部分底層的蠕變腐蝕情形進行評比

43 Feb 2006 SurTec International Coupon Exposure racks 暴露材料於架上

44 Feb 2006 SurTec International System Combined Rating Cr(6)9.1 NC 19.0 NC 27.2 NC 36.2 NC 47.9 NC 55.6 NC 66.5 chromitAL TCP 三價鉻 9.1 Rating Summary – All Primers and Al Alloys tested Marine Exposure – 12 Months 測試所有底漆與鋁合金組合, 暴露於海邊 12 個月 Rating

45 Feb 2006 SurTec International

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48 Al Phosphoric Acid Anodize NSS, 500 hrs chromitAL TCP 40 min, 25 C 10 min 45 C

49 Feb 2006 SurTec International chromitAL TCP Fields of Application TCP 的應用 Architectural 建築 Aerospace – Aircraft 航太飛機 Automotive wheels – Paint applications. 輪圈, 塗裝應用 Bicycles – Paint applications 腳踏車, 塗裝應用 Electrical, electronic components - Paint applications, low contact resistance 電機電子零件塗裝應用之低電阻要求 Waveguide 波導 Marine industry 航海業

50 Feb 2006 SurTec International Meeting Requirements 符合以下需求 Qualicoat approved QPL Listed MIL DTL B MIL C-5541-E - Class 1, 3 ELV RoHS

51 Feb 2006 SurTec International Conclusions chromitAL TCP 是獨特的非六價鉻的 鋁置換層 可替代六價鉻鈍化製程且符合其所有特性 它提供無塗裝情況下的優異的裸露防蝕功 能, 以及對有機塗層的優秀附著力 可有效應用於一般鋁材、陽極鋁材、各式 鋁合金及鎂合金


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