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AL Chemistry Write an essay on factors which affect the rate of reactions and discuss the uses of kinetic studies. p. 1.

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Presentation on theme: "AL Chemistry Write an essay on factors which affect the rate of reactions and discuss the uses of kinetic studies. p. 1."— Presentation transcript:

1 AL Chemistry Write an essay on factors which affect the rate of reactions and discuss the uses of kinetic studies. p. 1

2 AL Chemistry Write an essay on factors which affect the rate of reactions and discuss the uses of kinetic studies. p. 1

3 AL Chemistry # Guidelines # 0. Introduction: Kinetics is influenced by many experimental conditions (factors) Part A: Factors affecting Rate of Reaction Part B: Uses of Kinetic Studies p. 2

4 (a) Collision Theory [velocity, K.E. of molecules]
AL Chemistry A1. Temperature (a) Collision Theory [velocity, K.E. of molecules] EA (b) M. B. Distribution (c) Arrhenius eqn. (EA) p. 3

5 chance of effective collisions 
AL Chemistry A2. Concentration concentration  freq. of collisions  chance of effective collisions  p. 4

6 for reactions involving gases only
AL Chemistry A3. Pressure for reactions involving gases only (solid & liquid are not compressible) pressure , no. of eff. collisions  p. 5

7 (b) new pathway with lower EA
AL Chemistry A4. Catalyst (a) definition (b) new pathway with lower EA (c) M. B. Distribution p. 6

8  e.g. marble chips VS powdered CaCO3
AL Chemistry A5. Other Factors (a) surface area  state of subdivision  e.g. marble chips VS powdered CaCO3 (b) light  photosynthesis  silver salt & photographic film p. 7

9 B1. Industry maximum yield minimum raw materials minimal fuel
AL Chemistry B1. Industry Optimization of Industrial Production of Chemicals maximum yield minimum raw materials minimal fuel shortest time p. 8

10 (a) deterioration of food
AL Chemistry B2. Society Slow down unwanted reactions (a) deterioration of food (b) rusting p. 9

11 B3. Archaeological Investigation
AL Chemistry B3. Archaeological Investigation Carbon-14 dating of Fossil and Prehistorical Remains (radioactive decay: first order reaction) p. 10

12 B4. Studying Reaction Mechanism
AL Chemistry B4. Studying Reaction Mechanism rate equation  deduce the species involved in r.d.s.  species involved in formation of T.S.  molecularity of reaction  e.g. SN1 or SN2 p. 11


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