Presentation on theme: "Advances in Understanding Pollutant Mass Loadings Lester McKee Jon Konnan, Richard Looker, Nicole David, Jay Davis Article on Page 77 of the Pulse."— Presentation transcript:
Advances in Understanding Pollutant Mass Loadings Lester McKee Jon Konnan, Richard Looker, Nicole David, Jay Davis Article on Page 77 of the Pulse
Why Measure Loadings? Fish consumption advisories since 1993 –San Francisco Bay is listed as impaired for a range of contaminants Initially loadings information was generated to develop TMDL project reports written by the Water Board –More loadings information –Measurement of progress towards targets
What are the priority contaminants? SubstancePriority Mercury and PCBsTop Polybrominated diphenylethers (PBDEs)High Current use pesticides (pyrethroids), dioxins, selenium, OC pesticides, copper, nickel, PAHsMedium Silver, arsenic, cadmium, chromium, lead, zinc, organophosphate pesticides, nutrientsLow
What are the Main Sources and Pathways? Guadalupe River Urban StormwaterIn-Bay contaminated sites Focus is on the larger pathways that are deemed potentially controllable
Sacramento River Guadalupe River Zone 4 Line A What Stormwater Loading Studies are ongoing?
Sacramento River at Mallard Island near Pittsburg
Loadings normalized per unit area per year Area (km 2 ) Suspended Sediment (t/km 2 ) Total Mercury ( g/m 2 ) Methyl- Mercury ( g/m 2 ) Sum of PCBs ( g/m 2 ) Sum of PBDEs ( g/m 2 ) DDT ( g/m 2 ) Z4LA (WY 2007)4.5245.60.163.29.03.7 Guadalupe River (WY 2004)23636640.08126.96.36.199 Statistically different?Yes No
Mercury Which watersheds are most contaminated? What are the loadings from specific watersheds and the region as a whole –Currently based on sediment Hg concentrations and out-dated estimates of regional sediment loads Little information on mercury speciation –Methylmercury –Reactive mercury Remaining Questions and Progress
PCBs Little information on loadings from small heavily industrialized watersheds –Mainly near the Bay margin –Focus on “old industrial” Which watersheds are most contaminated? What are the sources and processes of release? Remaining Questions and Progress
PBDEs and OC pesticides –One box model paper published in Environment International (Oram et al 2008) –Penta and Octa banned – when will the loads go down - will the Bay recover? Dioxins and pyrethroid pesticides –No information on urban loadings –Little to no information on other pathways Selenium, Copper, Nickel, PAHs –Not recently discussed
All contaminants Are there “high leverage” areas or processes on the Bay margin where contaminants impact the base of the food web What is the linkage between watershed loadings and “hotspots” or “high leverage” areas on the Bay margin What are the remaining questions?
Small Tributaries Loadings Strategy –Being developed now Mercury Strategy (page 4 of the Pulse) –First strategy to be developed Dioxin Strategy –Priorities vary by stakeholder – very expensive so still debate over funding Modeling Strategy –Being developed now Planning efforts to prioritize and address data gaps
1) Impairment Which are the “high-leverage” small tributaries that contribute most to Bay impairment? 2) Loading What are the concentrations and average annual loads of pollutants of concern from small tributaries? 3) Trends How are concentrations or loads of pollutants of concern from small tributaries changing on a decadal scale? 4) Support for Management Actions What are the projected impacts of management actions and where should management actions be implemented? Small Tributaries Loading Strategy A three page document that includes: Key questions and priorities Guiding principles A timeline Recommended methods
Summary Our understanding of pollutant mass loads has changed considerably –We now have accurate measurements of loads in three watersheds But there are still many questions Through time the needs for information are becoming more explicit and the RMP is adapting to new needs –Constant re-evaluation of the management questions –5-year plans for the workgroups and the program as a whole –Focus strategy documents (contaminant or issue specific)