Presentation on theme: "How Scientists Determine Formulas"— Presentation transcript:
1 How Scientists Determine Formulas You have learnedhow atoms form bondshow to write formulashow to name compoundshow to count the atom in compounds.Don’t you wonder how scientists figure out the formulas in the first place?
2 Atomic Masses: Counting Atoms by Weighing Let’s REVIEW a bit:Atoms have very tiny masses so scientists made a unit to avoid using very small numbers.1 atomic mass unit (amu) = 1.66 10–24 gTOO TINY TO WORK WITH IN A LAB!
3 The Mole brings measurements to a scale we can work with! One mole of anything contains × 1023 units of that substance.Avogadro’s number is × 1023A sample of an element with a mass equal to that element’s average atomic mass (expressed in g) contains one mole of atoms.
5 It is found on the periodic table. The average atomic mass for an element is the weighted average of the masses of all the isotopes of an element.It is found on the periodic table.Use digits to the hundredths place for all problems in this class.EX] Oxygen g/mol Hydrogen 1.01 g/mol*Sometimes, in demo problems, I will round the values. I do this so you see the concept more easily and don’t get bogged down in numbers.
7 Understand the definition of molar mass Calculate molar mass ObjectivesUnderstand the definition of molar massCalculate molar massLearn to convert between moles and massLearn to calculate the mass percent of an element in a compound
8 Molar Mass A compound is a collection of atoms bound together. The molar mass of a compound is obtained by summing the masses of the component atoms.
14 Remember how to “count atoms” Mass in grams of one mole of the substance:Molar Mass of N = g/molMolar Mass of N2 = g/mol(2 × g/mol)Molar Mass of H2O = g/mol(2 × 1.01 g/mol) g/molMolar Mass of Ba(NO3)2 = g/molg/mol + (2 × g/mol) + (6 × g/mol)Remember how to “count atoms”1 Ba, 2 N, 6 O…because the subscript 2 applies to everything in the parentheses that precedes it
15 Percent Composition of Compounds Percent composition consists of the mass percent of each element in a compound:Mass percent =
16 For iron in iron(III) oxide,(Fe2O3): Mass % O?You can do it 2 ways:3(16.00 g) = g = %2(55.85 g) + 3(16.00 g) g gOR100% %= 30.06%...percent should add up to 100%Note: You can check your work. Total percent should always be very close to 100%, although it may be slightly off due to rounding.
17 Calculate % composition from masses of each element Scientists also do this calculation from actual masses obtained from experiments. This is actually a very important research tool!EX] A new compound is extracted from a plant root. It breaks down as shown below. What is its % composition?Total sample mass = gC = g/ g x 100% = 40.00%O = g/ g x 100% = 53.33%H = g/ g x 100% = %_______100.00%
19 ExerciseConsider separate gram samples of each of the following: H2O, N2O, C3H6O2, CO2Rank them from highest to lowest percent oxygen by mass.H2O, CO2, C3H6O2, N2OH2O, CO2, C3H6O2, N2O; The percent oxygen by mass in each is:H2O = 88.81%CO2 = 72.71%C3H6O2 = 43.20%N2O = 36.35%
23 SO WHAT! Why do we care?Because, from this information, we can figure out the actual chemical formula!This is how scientists determine the chemical formulas for substances!Discovery, research…SCIENCE!
24 Understand the meaning of empirical formula ObjectivesUnderstand the meaning of empirical formulaLearn to calculate empirical formulasLearn to calculate the molecular formula of a compound
25 Empirical Formulas The word “empirical” means it is based on observations, experiments, or experience…not theory or logic only Scientists collect data in experiments and use it to determine empirical formulasThe empirical formula of a compound is the simplest whole number ratio of the atoms present in the compound.The empirical formula can be found from the percent composition of the compound.The empirical formula can be found from masses of each element also.
27 Refresher Course!You need to remember how to calculate moles of an element from grams of the elementDivide the given mass by the molar massEXAMPLE:How many moles in36.03 g C|1mol C = mol C|12.01 g C
31 Grams or percent…It doesn’t matter! If you are given grams, calculate number of moles by dividing by the molar massIf you are given %composition, change units from percent to grams and calculate moles by dividing by the molar mass. (You assume a sample size of 100 g to do this.)Why do we do it 2 ways?Because sometimes experiments yield results measured in grams, and sometimes the results are measured as percentages of the whole sample.
34 Subscripts must be WHOLE numbers Sometimes when you divide all mole values by the smallest, you don’t get whole numbers!Multiply by the smallest whole number that will convert them all to whole numbers. See hint belowLook for common decimal equivalents of fractions.25=1/ =1/ =1/ =3/4.67=2/ =1/ =1/6Multiply all values by the denominator to get whole numbers
39 Calculation of Molecular Formulas The molecular formula is the exact formula of the molecules present in a substance.Remember, only IONIC compounds are simplified to the lowest whole number ratioThis is because molecular compounds actually form molecules (!!groups of atoms held together by bonds formed from shared electrons!!)Molecules can be multiples of the simplest formula (empirical)The molecular formula is always an integer multiple of the empirical formula.Molecular formula = (empirical formula)nwhere n is a whole number
40 Molecular formulasHow do you know when you need to calculate a molecular formula?You must be given the actual molar mass of the compound.What do you do to calculate the molecular formula?Divide the given molar mass by the mass of the empirical formulaMultiply each SUBSCRIPT by this value
41 C6H12O6 Given molar mass of substance = 180 g/mol Given mass = 180 = 6 EXAMPLE: GlucoseGiven molar mass of substance= 180 g/molMolar mass of empirical formula =30 g/molGiven mass = 180 = 6Emp massMultiply each subscript by the calculated integerMOLECULAR FORMULA:C6H12O6
45 ExerciseThe composition of adipic acid is 49.3% C, 6.9% H, and 43.8% O (by mass). The molar mass of the compound is about 146 g/mol.What is the empirical formula?C3H5O2What is the molecular formula?C6H10O4Assume 100.0g g of carbon is mol C (49.3/12.01) g of hydrogen is mol H (6.9/1.008) g of oxygen is mol O (43.8/16.00). The ratio of C:H:O is 1.5:2.5:1 (C: 4.105/ = 1.5; H: 6.845/ = 2.5). Multiplying each by 2 to get a whole number becomes a ratio of 3:5:2. The empirical formula is therefore C3H5O2. The molar mass of the empirical formula is g/mol, which goes into the molar mass of the molecular formula 2 times (146/73.07). The molecular formula is therefore C6H10O4.